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Materials Data on Ga(CuN)3 by Materials Project

Ga(CuN)3 crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Cu2+ is bonded in a square co-planar geometry to four equivalent N3- atoms. All Cu–N bond lengths are 2.07 Å. Ga3+ is bonded to six equivalent N3- atoms to form corner-sharing GaN6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ga–N bond lengths are 2.07 Å. N3- is bonded to four equivalent Cu2+ and two equivalent Ga3+ atoms to form a mixture of edge and corner-sharing NGa2Cu4 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗