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Summary of Expansions and Updates in R&D GREET® 2025

The research and development (R&D) version of Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET®) model, or R&D GREET, is developed by Argonne National Laboratory (Argonne) with the support of the U.S. Department of Energy (DOE) and other federal agencies. R&D GREET is a life cycle analysis (LCA) model, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in all transportation sub-sectors (i.e., road, air, marine, and rail) and other end-use sectors, and energy technology systems. Argonne has expanded and updated the model in many areas in R&D GREET 2025. This report provides a summary of the expansions and updates. R&D GREET is designed as an attributional LCA model, but specific consequential effects for certain pathways are included by default when they are scientifically important and/or highly policy relevant. For example, two major consequential elements – induced land use change (ILUC) for biofuels and avoided emissions for certain RNG-based pathways – are implemented by default in R&D GREET because they are highly relevant to our user base and crucial for a comprehensive evaluation of the environmental effects of these technologies. In a future version of R&D GREET, these consequential elements for biofuels and RNG could be more clearly distinguished from core attributional results. We will consider adding a highly visible toggle that would allow users to turn off or adjust these consequential impacts.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Summary of Expansions and Updates in GREET ® 2021

The GREET® (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model has been developed by Argonne National Laboratory (Argonne) with the support of the U.S. Department of Energy (DOE). GREET is a life-cycle analysis (LCA) tool, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in major transportation sectors (i.e., road, air, marine, and rail) and other end-use sectors, and energy systems. Within the transportation sector, GREET covers road, air, water, and rail transportation sub-sectors. Recently, GREET was expanded to cover the building sector. Historically, GREET includes LCA of various materials such as steel, aluminum, cement, and different plastic types. Argonne has expanded and updated the model in various sectors in GREET 2021, and this report provides a summary of the release.

09 BIOMASS FUELS↗

Building Life-Cycle Analysis with the GREET Building Module: Methodology, Data, and Case Studies

To holistically address building sustainability, Argonne National Laboratory has expanded its Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET) life-cycle model with a new GREET Building Module. This report documents life-cycle analysis (LCA) methodology and foreground data that Argonne National Laboratory compiles and develops to address embodied greenhouse gas (GHG) emissions and energy impacts of a wide range of envelope and structural building materials for new construction and retrofits. The methodology and data form the backbone of the GREET Building Module. This research effort focuses on developing consistent LCA methodology that conforms to building LCA standards such as the EN 15978 to address embodied GHG emissions and energy impacts of building materials/technologies. We document detailed foreground data for selected building materials and building components that are common for building construction. To test the LCA methodology and the GREET Building Module, this report includes case studies of insulation materials and wall panels for residential building retrofit. We have developed a separate document as a User Guide for understanding and applying the GREET Building Module to conduct detailed, process-level LCA of embodied carbon and energy impacts of emerging building materials and technology solutions that of interest to the Building Technologies Office (BTO) of the US Department of Energy, researchers, and industry stakeholders.

42 ENGINEERING↗

Life Cycle Analysis of Greenhouse Gas Emissions of Clean Fuels with the R&D GREET 2024 Model

This document summarizes research on the life cycle greenhouse gas (GHG) emissions rates from the production and use of clean fuels to support a new version of the Research and Development Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (R&D GREET) model, R&D GREET 2024 In this effort, Argonne National Laboratory (ANL) focuses on clean fuel pathways that are readily available in the market or are emerging in the near term. The selected pathways represent clean fuel technologies that convert biomass- and/or waste-based feedstocks to liquid and/or gaseous fuels for the transportation sector and other potential uses. The pathways are configured in R&D GREET 2024 with up-to-date feedstock-to-fuel life cycle inventory (LCI) data. Additionally, a new tab has been added to R&D GREET 2024 called “Clean Fuels” which allows the user to easily change inputs and access LCA results. Argonne does not warrant that the results presented in this report are consistent with the requirements of any particular regulatory or incentive program. Users interested in specific programs that reference GREET are encouraged to review guidance specific to those programs if and when it is available to determine appropriate means of compliance and contact the relevant responsible agencies for those specific policies or programs.

09 BIOMASS FUELS↗

Development of the Well-to-Wake Life Cycle Assessment Model for Marine Fuels in R&D GREET 2025

The Marine analysis capabilities in the 2025 Research and Development Greenhouse gases, Regulated Emissions, and Energy use in Technologies (R&D GREET) have been updated to incorporate the latest findings from the Fourth International Maritime Organization (IMO) GHG Study.1 To support these updates and enhance user flexibility, the former single marine module used in previous R&D GREET versions has been split into two workbook tabs: The Marine_Fuel tab, which covers the fuel-cycle, and the Marine_Trip tab, which covers the trip-cycle. In the Marine_Fuel tab, fuel cycle results for 39 marine fuels are available—assuming a slow speed diesel engine—and can be seen in Appendix A. However, there are options for changing feedstocks for multiple fuels, ability to view results with or without pilot fuels for fuels such as methanol and ammonia, and carbon capture options. All these combinations make the number of total possible pathways over one hundred. For each pathway, life cycle emission results are divided into feedstock, conversion, and combustion categories, along with pilot fuel supply chain emissions for fuels used in dual fuel engines. In the newly created Marine_Trip tab, users can view the life cycle emissions of using these fuels from a trip perspective. Compared to R&D GREET 2024, 16 new types of vessels are added in R&D GREET 2025. Examples of results assuming the default size for each vessel type are available in Appendix A. Additional information categories on vessels are included such as vessel size, main propulsion type, engine power rating, combustion cycle, etc. based on the Fourth IMO GHG Study. Operational mode of the trip, fuel consumption, and load calculation were updated based on the report. The fuel consumption calculation also incorporates low-load adjustment, speed–power correction, weather correction, and fouling correction factors. Furthermore, fuel consumption in boilers or steam turbines is also added for the first time, besides fuel use in main propulsion engines and auxiliary engines. This effort makes the R&D GREET Marine capabilities more robust than before. Users will be able to estimate fuel consumption more accurately for more diverse choices of vessel categories, vessel sizes, and energy converters.

09 BIOMASS FUELS↗

Updated Production Inventory for Lithium-Ion Battery Anodes for the GREET® Model, and Review of Advanced Battery Chemistries

The Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET®) model considers lithium-ion batteries with multiple anode materials. Synthetic graphite is the primary anode material used in the previous GREET versions, even as the model offered options to choose a lithium anode and/or a blended anode (blend of synthetic graphite and silicon). Yet, the inventory (material and energy flows) considered for these anodes is dated, and the anode options do not consider natural graphite, which is another important anode material for lithium-ion batteries. This report documents the material and energy flows for natural graphite anode production from raw material extraction to anode production – as incorporated in the updated GREET model. We also present a brief literature review on the current state of inventory for the other three anodes (synthetic graphite, silicon, and lithium), as well as updates made in the recent GREET model on material and energy flows associated with their respective production. Finally, this study provides a summary of advanced battery systems that may be alternatives to LIBs for use in future electric vehicles.

25 ENERGY STORAGE↗

Summary of Expansions and Updates in R&D GREET ® 2024

The research and development (R&D) version of Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET ® ) model, or R&D GREET, is developed by Argonne National Laboratory (Argonne) with the support of the U.S. Department of Energy (DOE) and other federal agencies. R&D GREET is a life cycle analysis (LCA) model, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in major transportation sectors (i.e., road, air, marine, and rail) and other end-use sectors, and energy technology systems. Argonne has expanded and updated the model in various areas in R&D GREET 2024.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Summary of Expansions and Updates in R&D GREET® 2024 Rev.1

The research and development (R&D) version of Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET®) model, or R&D GREET, is developed by Argonne National Laboratory (Argonne) with the support of the U.S. Department of Energy (DOE) and other federal agencies. R&D GREET is a life cycle analysis (LCA) model, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in major transportation sectors (i.e., road, air, marine, and rail) and other end-use sectors, and energy technology systems. Argonne has expanded and updated the model in several areas in R&D GREET 2024 Rev.1. This report provides a summary of the expansions and updates.

54 ENVIRONMENTAL SCIENCES↗

Whole-building life-cycle analysis with a new GREET® tool: Embodied greenhouse gas emissions and payback period of a LEED-Certified library

Embodied greenhouse gas (GHG) emissions of building components and buildings operations need to be quantified to holistically address building sustainability. To evaluate embodied GHG emissions of buildings and to provide insights on building materials and building design decisions toward decarbonization, we have recently created a building life-cycle assessment (LCA) module in the widely used Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET (R)) LCA model. We applied the GREET building LCA module to examine embodied GHG impacts and the payback period of a LEED (Leadership in Energy and Environmental Design) certified public library in Chicago, USA. We developed localized, detailed life-cycle inventories to address individual building materials used in the library. We expanded the LCA system boundary to include the mechanical, electrical, and plumbing system, as well as refrigerant impacts, which are often ignored in previous studies. Results show that the total embodied GHG emissions are approximately 817 metric tons, or approximately 538 kg/m 2 . Sensitivity analysis highlights the positive role of increasing the use of recycled materials for reducing embodied GHG emissions. Sensitivity analysis on embodied GHG emissions payback periods shows the need to benchmark the embodied and operational carbon performance of buildings for comparison to alternative building designs and sustainability practices. Furthermore, this analysis demonstrates that building LCA models, such as the GREET building LCA module, which addresses embodied and operational GHG emission impacts of whole buildings holistically, could empower building architects, technology developers, manufacturers, and general contractors to address embodied and operational impacts holistically for building sustainability.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Summary of Expansions and Updates in GREET® 2020

The GREET® (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model has been developed by Argonne National Laboratory with the support of the U.S. Department of Energy (DOE). GREET is a life-cycle analysis (LCA) tool, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in major transportation sectors (i.e., road, air, marine, and rail) and other end-use sectors, and energy systems. Argonne has expanded and updated the model in various sectors in GREET 2020, and this report provides a summary of the release.

33 ADVANCED PROPULSION SYSTEMS↗

Summary of Expansions and Updates in GREET ® 2022

The GREET ® (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model has been developed by Argonne National Laboratory (Argonne) with the support of the U.S. Department of Energy (DOE) and other federal agencies. GREET is a life cycle analysis (LCA) tool, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in major transportation sectors (i.e., road, air, marine, and rail) and other end-use sectors, and energy systems. Argonne has expanded and updated the model in various sectors in GREET 2022, and this report provides a summary of the release.

25 ENERGY STORAGE↗

Summary of Expansions and Updates in R&D GREET ® 2023

The Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET®) model was developed by Argonne National Laboratory (Argonne) with the support of the U.S. Department of Energy (DOE) and other federal agencies. R&D GREET is a life cycle analysis (LCA) model, structured to systematically examine the energy and environmental effects of a wide variety of transportation fuels and vehicle technologies in major transportation sectors (i.e., road, air, marine, and rail), other end-use sectors, and energy systems. Argonne has expanded and updated the model in various areas in R&D GREET 2023. This report provides a summary of the expansions and updates.

33 ADVANCED PROPULSION SYSTEMS↗

Development of R&D GREET 2023 Rev1 to Estimate Greenhouse Gas Emissions of Sustainable Aviation Fuels for 40B Provision of the Inflation Reduction Act

The federal Interagency Working Group on sustainable aviation fuels (SAF) tasked Argonne National Laboratory with developing a modified version of the Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (GREET) model based on R&D GREET 2023. The goal of the new GREET version is to simulate the life-cycle greenhouse gas (GHG) emissions associated with seven sustainable aviation fuel (SAF) pathways for consideration under the 40B Provision of the Inflation Reduction Act – Sustainable aviation fuel credit. The Provision includes a new GHG-based tax credit to incentivize SAF production and reduce the costs of these fuels.

02 PETROLEUM↗

R&D GREET Battery Carbon Footprint Calculator

The Battery Carbon Footprint (CF) Calculator was developed to help U.S. battery manufacturers meet the carbon footprint reporting requirements of the EU Battery Regulation (EU) 2023/1542. The calculator incorporates several major battery carbon footprint frameworks, including the Joint Research Centre's Rules for the Calculation of the Carbon Footprint of Electric Vehicle Batteries (CFB-EV), RECHARGE's Product Environmental Footprint Category Rules for High Specific Energy Rechargeable Batteries for Mobile Applications (PEFCR), the Catena-X Product Carbon Footprint Rulebook (CX-PCF Rules), Battery Pass's Battery Carbon Footprint: Rules for Calculating the Carbon Footprint of the "Distribution" and "End-of-Life and Recycling" Life Cycle Stages, the Global Battery Alliance's Greenhouse Gas Rulebook: Generic Rules, Version 2.1, and the Ministry of Economy, Trade and Industry's draft Carbon Footprint Calculation Method for Automotive Batteries. The tool pairs these frameworks with foreground data from Argonne's R&D GREET models and integrates user-supplied background data covering battery manufacturing and supply chain activities. By bringing multiple international methodologies together in a single platform, the calculator enables manufacturers to evaluate product carbon footprints, improve data consistency, and prepare for evolving regulatory compliance and global market reporting requirements.

Zhang, Jingyi↗

GREET-Based Interactive Life-Cycle Assessment of Biofuel Pathways: User Manual

An interactive, web-based tool was developed to streamline the process design for biofuel pathways that the Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) is developing. The tool utilizes the latest life-cycle analysis (LCA) data in the Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET) model developed by Argonne National Laboratory (Argonne National Laboratory, 2021). It provides techno-economic analysis (TEA) modelers with a interative interface that generates real-time LCA results based on life-cycle inventory (LCI) data and generates useful insights into key emissions drivers. Economic implications of the LCA results are also included in the tool. Overall, the tool aims to assist TEA researchers with the development of economically viable and environmentally beneficial biofuel technologies. This manual introduces the interface and analysis capabilities of the tool.

09 BIOMASS FUELS↗

Life-cycle Analysis of Conversion of Post-Use Plastic via Pyrolysis with the GREET Model

In this report, we present an updated LCA of the PTF pathway developed at Argonne. Benavides et al. (2017) analyzed the environmental impact of producing ultra-low sulfur (ULS) diesel fuel from PUP via pyrolysis (the most common PTF technology). We used the Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET®) model and collected data from eight PTF companies to assess the potential energy and environmental benefits associated with this technology (Argonne, 2020). We conducted a survey and aggregated the dataset based on the different responses, which included plant capacity, process yields, feedstock composition, material and energy inputs, and outputs, and other parameters. We calculated the energy, greenhouse gas (GHG) emissions, and water consumption of its intermediate product pyrolysis oil and final product PUP-derived ULS diesel and compared the results to those metrics for their conventional counterparts (crude naphtha and petroleum ULS diesel fuel).

10 SYNTHETIC FUELS↗

Expansion and Update of the R&D Feedstock Carbon Intensity Calculator (FD-CIC) for R&D GREET 2025

The R&D Feedstock Carbon Intensity Calculator (R&D FD-CIC) is a transparent and easy-touse tool to estimate feedstock-specific carbon intensity (CI) of biofuel feedstocks, and to examine potential CI variations of different farming practices to grow agricultural feedstocks for biofuel production. The objective of the tool is to assess potential effects of different farming practices with underlined factors to reduce uncertainties in such assessment and help R&D activities. The original work and early versions of R&D FD-CIC were supported by Advanced Research Projects Agency–Energy (ARPA-E) of the Department of Energy, with recent support by the Bioenergy Technologies Office of the Department of Energy. The tool uses life cycle inventory (LCI) data of key farming inputs from the R&D Greenhouse gases, Regulated Emissions, and Energy use in Technologies (R&D GREET) model. The system boundary of R&D FD-CIC covers the cradle-to-farm-gate activities, including upstream emissions related to farming input manufacturing and feedstock production.

09 BIOMASS FUELS↗

Updates to Anaerobic Digestion Pathways for Animal Manure in R&D GREET 2025 Rev.1

Renewable natural gas (RNG) produced from animal manure can significantly reduce greenhouse gas (GHG) emissions from the transportation sector, but accurate life cycle assessment (LCA) of this fuel depends on precise modeling of emissions from business-as-usual (BAU) manure manage ment. This report documents updates to the Research & Development version of the Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (R&D GREET) model that attempt to improve that precision.

09 BIOMASS FUELS↗