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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

On the fundamental frequency of rectangular simply-supported symmetric laminated plates

A new closed-form approximate solution for the fundamental frequency of symmetric rectangular laminates which are simply supported on all four edges is derived. The solution, obtained from eigensensitivity analysis, is expressed as a truncated Maclaurin series in the coupling stiffnesses D16 and D26. Results show that the predicted fundamental frequency is remarkably accurate. A comparison of the fundamental frequencies of four-ply symmetric angle-ply laminates calculated from the new formula with those determined from a Rayleigh-Ritz procedure yielded a maximum differential of 0.6 percent over a wide range of principal stiffness ratios, plate aspect ratios, and design angles.

Reiss, Robert↗
NASA NTRS2002

An Accurate Quartic Force Field, Fundamental Frequencies, and Binding Energy for the High Energy Density Material T(d)N4

The CCSD(T) method has been used to compute a highly accurate quartic force field and fundamental frequencies for all N-14 and N-15 isotopomers of the high energy density material T(sub d)N(sub 4). The computed fundamental frequencies show beyond doubt that the bands observed in a matrix isolation experiment by Radziszewski and coworkers are not due to different isotopomers of T(sub d)N(sub 4). The most sophisticated thermochemical calculations to date yield a N(sub 4) -> 2N(sub 2) heat of reaction of 182.22 +/- 0.5 kcal/mol at 0 K (180.64 +/- 0.5 at 298 K). It is hoped that the data reported herein will aid in the ultimate detection of T(sub d)N(sub 4).

Lee, Timothy J.↗
NASA NTRS1992

Limitations on squeezing and formation of the superposition of two macroscopically distinguishable states at fundamental frequency in the process of second harmonic generation

The results of numerical simulations of quantum state evolution in the process of second harmonic generation (SHG) are discussed. It is shown that at a particular moment of time in the fundamental mode initially coherent state turns into a superposition of two macroscopically distinguished states. The question of whether this superposition exhibits quantum interference is analyzed.

Nikitin, S. P.↗
NASA NTRS2005

The Effect of Approximating Some Molecular Integrals in Coupled-Cluster Calculations: Fundamental Frequencies and Rovibrational Spectroscopic Constants of Cyclopropenylidene

The singles and doubles coupled-cluster method that includes a perturbational estimate of connected triple excitations, denoted CCSD(T), has been used, in conjunction with approximate integral techniques, to compute highly accurate rovibrational spectroscopic constants of cyclopropenylidene, C3H2. The approximate integral technique was proposed in 1994 by Rendell and Lee in order to avoid disk storage and input/output bottlenecks, and today it will also significantly aid in the development of algorithms for distributed memory, massively parallel computer architectures. It is shown in this study that use of approximate integrals does not impact the accuracy of CCSD(T) calculations. In addition, the most accurate spectroscopic data yet for C3H2 is presented based on a CCSD(T)/cc-pVQZ quartic force field that is modified to include the effects of core-valence electron correlation. Cyclopropenylidene is of great astronomical and astrobiological interest because it is the smallest aromatic ringed compound to be positively identified in the interstellar medium, and is thus involved in the prebiotic processing of carbon and hydrogen. The singles and doubles coupled-cluster method that includes a perturbational estimate of

Lee, Timothy J.↗
NASA NTRS1995

Accurate ab Initio Quartic Force Fields, Vibrational Frequencies, and Heats of Formation for FCN, FNC, ClCN, and ClNC

The XCN and XNC (X = F, Cl) isomers have been investigated using the CCSD(T) method in conjunction with correlation consistent basis sets. Equilibrium geometries, harmonic frequencies, anharmonic constants, fundamental frequencies, and heats of formation have been evaluated. Agreement with experiment for the fundamental frequencies is very good, even for nu(sub 2), for CICN, which is subject to a strong Fermi resonance with 2nu(sub 3). It is also shown that a second-order perturbation theory approach to solving the nuclear Schroedinger equation gives results in excellent agreement with essentially exact variational calculations. This is true even for nu(sub 2) of ClCN, provided that near-singular terms are eliminated from the perturbation theory formulas and the appropriate Fermi interaction energy matrix is then diagonalized. A band at 615/cm, tentatively assigned as the Cl-N stretch in ClNC in matrix isolation experiments, is shown not to be due to ClNC. Accurate atomization energies are determined and are used to evaluate accurate heats of formation (3.1 +/- 1.5, 33.2 +/- 1.5, 72.6 +/- 1.5, and 75.9 +/- 1.5 kcal/mol for FCN, ClCN, FNC, and ClNC, respectively). It is expected that the theoretical heats of formation for FCN, FNC, and ClNC are the most accurate available.

Lee, Timothy J.↗
NASA NTRS2013

Rovibrational Spectroscopic Constants and Fundamental Vibrational Frequencies for Isotopologues of Cyclic and Bent Singlet HC2N isomers

Through established, highly-accurate ab initio quartic force fields (QFFs), a complete set of fundamental vibrational frequencies, rotational constants, and rovibrational coupling and centrifugal distortion constants have been determined for both the cyclic 1(sup 1) 1A' and bent 2(sup 1)A' DCCN, H(C13)CCN, HC(C-13)N, and HCC(N-15) isotopologues of HCCN. Spectroscopic constants are computed for all isotopologues using second-order vibrational perturbation theory (VPT2), and the fundamental vibrational frequencies are computed with VPT2 and vibrational configuration interaction (VCI) theory. Agreement between VPT2 and VCI results is quite good with the fundamental vibrational frequencies of the bent isomer isotopologues in accord to within a 0.1 to 3.2 / cm range. Similar accuracies are present for the cyclic isomer isotopologues. The data generated here serve as a reference for astronomical observations of these closed-shell, highly-dipolar molecules using new, high-resolution telescopes and as reference for laboratory studies where isotopic labeling may lead to elucidation of the formation mechanism for the known interstellar molecule: X 3A0 HCCN.

molecular data↗
NASA NTRS2002

Remote magneto-elastic analyte, viscosity and temperature sensing apparatus and associated methods of sensing

An analyte, viscosity, or temperature sensing apparatus for operative arrangement within a time-varying magnetic field, including a sensor with an outer surface that is chemically, frictionally, or thermally responsive and adhered to a base magnetostrictive element, and a receiver to measure a first and second value for magneto-elastic emission intensity of the sensor taken at, respectively, a first and second interrogation frequency. A change in mass or a change in material stiffness of the sensor due to the responsiveness, the viscosity and mass density of a fluid therearound, or the temperature, can be identified. The receiver, alternatively, measures a plurality of successive values for magneto-elastic emission intensity of the sensor taken over an operating range of successive interrogation frequencies to identify a value for the sensor's magneto-elastic resonant frequency (a fundamental frequency or harmonic thereof). Several sensors in an ordered array will provide a package of information.

Grimes, Craig A.↗
NASA NTRS2013

Protonated Nitrous Oxide, NNOH(+): Fundamental Vibrational Frequencies and Spectroscopic Constants from Quartic Force Fields

The interstellar presence of protonated nitrous oxide has been suspected for some time. Using established high-accuracy quantum chemical techniques, spectroscopic constants and fundamental vibrational frequencies are provided for the lower energy O-protonated isomer of this cation and its deuterated isotopologue. The vibrationally-averaged B0 and C0 rotational constants are within 6 MHz of their experimental values and the D(subJ) quartic distortion constants agree with experiment to within 3%. The known gas phase O−H stretch of NNOH(+) is 3330.91 cm(exp−1), and the vibrational configuration interaction computed result is 3330.9 cm(exp−1). Other spectroscopic constants are also provided, as are the rest of the fundamental vibrational frequencies for NNOH(+) and its deuterated isotopologue. This high-accuracy data should serve to better inform future observational or experimental studies of the rovibrational bands of protonated nitrous oxide in the ISM and the laboratory.

fundamental vibrational frequencies↗
NASA NTRS1995

A FFT Method for the Quasiclassical Selection of Initial Ro-Vibrational States of Triatomic Molecules

This paper describes the use of an exact fast Fourier transform (FFT) method to prepare specified vibrational-rotational states of triatomic molecules. The method determines the Fourier coefficients needed to describe the coordinates and momenta of a vibrating-rotating triatomic molecule. Once the Fourier coefficients of a particular state are determined, it is possible to easily generate as many random sets of initial cartesian coordinates and momenta as desired. All the members of each set will correspond to the particular vibrational-rotational state selected. For example, in the case of the ground vibrational state of a non-rotating water molecule, the calculated actions of 100 sets of initial conditions produced actions within 0.001 h(bar) of the specified quantization values and energies within 5 cm(sup -1) of the semiclassical eigenvalue. The numerical procedure is straightforward for states in which all the fundamental frequencies are independent. However for states for which the fundamental frequencies become commensurate (resonance states), there are additional complications. In these cases it is necessary to determine a new set of "fundamental" frequencies and to modify the quantization conditions. Once these adjustments are made, good results are obtained for resonance states. The major problems are in labelling the large number of Fourier coefficients and the presence of regions of chaotic motion. Results are presented for the vibrational states of H2O and HCN and the ro-vibrational states of H2O.

Eaker, Charles W.↗
NASA NTRS1977

Shuttle Experimental Radar for Geological Exploration (SERGE); antenna and integration concept definition study

The baseline configuration defined has the SERGE antenna panel array mounted on the OFT-2 pallet sufficiently high in the bay that negligible amounts of radiation from the beam are reflected from orbiter surfaces into the shuttle payload bay. The array is symmetrically mounted to the pallet along the array long dimension with the pallet at the center. It utilizes a graphite epoxy trusswork support structure. The antenna panels are of SEASAT engineering model design and construction. The antenna array has 7 panels and a 7-way naturally tapered coax corporate feed system. The performance of the system is predicted to exceed 33 db gain, have -15 db sidelobes in the E-plane and even lower in the H-plane, and have and E-plane beamwidth less than 2.2 deg, all within performance specification. The primary support structure is predicted to exceed the specified greater than 25 hertz fundamental frequency, although individual panels will have hertz fundamental frequency.

Kierein, J. W.↗
NASA NTRS1989

Unstable vortices in the near region of an internal flow cavity

This paper presents experimental data taken in the forward region of a separated internal free-shear layer produced in an internal cavity flowfield. It has been found that in the region very near the forward restrictor, experimental velocity profiles agree closely with the exact Stuart instability velocity profile with various values of a steepness parameter. Reynolds shear-stress profiles suggest the presence of counter-rotating longitudinal vortices. Spectral analysis by the maximum entropy method of the time samples within the vortices indicates subharmonic and harmonic components of the fundamental frequency, with a weak indication of the fundamental frequency itself.

Isaacson, L. K.↗
NASA NTRS1984

Quantification of advanced turboprop aircraft flyover noise annoyance

A laboratory experiment was conducted to quantify the annoyance to advanced turboprop (propfan) aircraft flyover noise. A computer synthesis system was used to generate 45 realistic, time varying simulations of propeller aircraft flyover noise in which the tonal content was systematically varied to represent the factorial combinations of five fundamental frequencies, three frequency envelope shapes, and three tone-to-broadband noise ratios. In the experiment, 64 subjects judged the annoyance of recordings of the 45 synthesized flyover noises presented at three sound levels in a test facility which simulates the outdoor acoustic environment. Analyses of the judgements showed that frequency envelope shape did not significantly affect annoyance. The interaction of fundamental frequency with tone-to-broadband noise ratio did have a large and complex effect on annoyance. Duration corrected A-weighted sound pressure level with a modified tone correction predicted annoyance better than any other measurement procedure.

Mccurdy, D. A.↗
NASA NTRS1988

Annoyance caused by advanced turboprop aircraft flyover noise: Single-rotating propeller configuration

Two experiments were conducted to quantify the annoyance of people to advanced turboprop (propfan) aircraft flyover noise. The objectives were to: (1) determine the effects on annoyance of various tonal characteristics; and (2) compare annoyance to advanced turboprops with annoyance to conventional turboprops and jets. A computer was used to produce realistic, time-varying simulations of advanced turboprop aircraft takeoff noise. In the first experiment, subjects judged the annoyance of 45 advanced turboprop noises in which the tonal content was systematically varied to represent the factorial combinations of five fundamental frequencies, three frequency envelope shapes, and three tone-to-broadband noise ratios. Each noise was presented at three sound levels. In the second experiment, 18 advanced turboprop takeoffs, 5 conventional turboprop takeoffs, and 5 conventional jet takeoffs were presented at three sound pressure levels to subjects. Analysis indicated that frequency envelope shape did not significantly affect annoyance. The interaction of fundamental frequency with tone-to-broadband noise ratio did have a large and complex effect on annoyance. The advanced turboprop stimuli were slightly less annoying than the conventional stimuli.

Mccurdy, David A.↗
NASA NTRS1988

Advanced turboprop aircraft flyover noise: Annoyance to counter-rotating-propeller configurations with a different number of blades on each rotor: Preliminary results

A laboratory experiment was conducted to quantify the annoyance of people to the flyover noise of advanced turboprop aircraft with counter-rotating propellers (CRP) having a different number of blades on each rotor (nxm, e.g., 10 x 8, 12 x 11). The objectives were: (1) compare annoyance to nxm CRP advanced turboprop aircraft with annoyance to conventional turboprop and jet aircraft; (2) determine the effects of tonal content on annoyance; and (3) determine the ability of aircraft noise measurement procedures and corrections to predict annoyance for this new class of aircraft. A computer synthesis system was used to generate 35 realistic, time-varying simulations of advanced turboprop takeoff noise in which the tonal content was systematically varied to represent combinations of 15 fundamental frequency (blade passage frequency) combinations and three tone-to-broadband noise ratios. The fundamental frequencies, which represented blade number combinations from 6 x 5 to 13 x 12 and 7 x 5 to 13 x 11, ranged from 112.5 to 292.5 Hz. The three tone-to-broadband noise ratios were 0, 15, and 30 dB. These advanced turboprop simulations along with recordings of five conventional turboprop takeoffs and five conventional jet takeoffs were presented at D-weighted sound pressure levels of 70, 80, and 90 dB to 64 subjects in an anechoic chamber. Analyses of the subjects' annoyance judgments compare the three categories of aircraft and examine the effects of the differences in tonal content among the advanced turboprop noises. The annoyance prediction ability of various noise measurement procedures and corrections is also examined.

Mccurdy, David A.↗
NASA NTRS1989

Crystal oscillators using negative voltage gain, single pole response amplifiers

A simple and inexpensive crystal oscillator is provided which employs negative voltage gain, single pole response amplifiers. The amplifiers may include such configurations as gate inverters, operational amplifiers and conventional bipolar transistor amplifiers, all of which operate at a frequency which is on the roll-off portion of their gain versus frequency curve. Several amplifier feedback circuit variations are employed to set desired bias levels and to allow the oscillator to operate at the crystal's fundamental frequency or at an overtone of the fundamental frequency. The oscillator is made less expensive than comparable oscillators by employing relatively low frequency amplifiers and operating them at roll-off, at frequencies beyond which they are customarily used. Simplicity is provided because operation at roll-off eliminates components ordinarily required in similar circuits to provide sufficient phase-shift in the feedback circuitry for oscillation to occur.

Kleinberg, Leonard L.↗
NASA NTRS1992

Spectral analysis of unsteady surface pressure on a pusher propeller

A propeller of an advanced turboprop testbed aircraft in pusher configuration is instrumented with 22 miniature blade-mounted transducers (BMTs) at two radii. Upstream pylon wake interaction with the propeller is the source of a one-per-cycle excitation for the blades in flight. The time history of fluctuating pressure signals over 26 flight conditions is statistically analyzed in the frequency domain. The rms amplitude of fluctuating pressure signals measured by suction surface BMTs indicates a very strong presence of the fundamental frequency over most of the upper surface. The pylon wake pressure signature on the propeller trailing edge, i.e., x/c not less than 0.80, shows predominantly random turbulence; hence, the amplitude of the fundamental frequency wave is fairly small. The resurgence of a large amplitude fundamental harmonic with coherent pylon wake signature further downstream, say at 90 percent chord, is unexpected behavior. The appearance of a dominating second propeller shaft order in the spectra of the rms pressure in transonic flight conditions identifies the presence of a two-per-cycle excitation source in the azimuthal direction. This is due to the presence of a shock wave, as evidenced by the pressure-time history plots.

Farokhi, Saeed↗
NASA NTRS1998

Control System and Flexible Satellite Interaction During Orbit Transfer Maneuver

In this paper the interaction between the attitude control system and the flexible structure of an artificial satellite during orbit transfer maneuver has been investigated. The satellite was modeled by a rigid central body with one or more flexible appendages. The dynamics equations were obtained by Lagrangean approach. The flexible appendages were treated as clamped-free beam and its displacement was discretized by assumed- mode method. In order to transfer the satellite, a typical Hohmann transfer and a burn-coast-burn strategy were used and the attitude was controlled by an on-off controller. During transfer procedure a global analysis of satellite has been done, such as: performance of control system, influence of elastic response in control system, thruster firing frequency, fuel consumption and variation of orbital elements. In order to avoid the interaction with structure motion, a control system with bandwidth of one decade bellow the fundamental frequency was used. In the simulations the firing frequency was evaluated in an approximately way but kept below the fundamental frequency of the structure. The control system has kept the attitude below the specifications. As a result, the orbit transfer maneuvering has been done correctly without excessive excitation of flexible appendage.

Adenilson Roberto da Silva↗