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Results for “Fluorescence thermometry”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Laser-induced fluorescence thermometry of supercritical CO 2 flows inside a micro-channel

This work demonstrates a thermometric technique using laser-induced fluorescence (LIF) in supercritical carbon dioxide flows in a micro-channel. Rhodamine 6G was used as a temperature-sensitive fluorescent dye. The flow conditions were at a pressure of 7.9 MPa and temperature in the range of 23°–90°C. 2D spatial distributions and time-resolved temperature profiles were obtained at this high pressure. Measured LIF signals showed close relations to the temperatures obtained from resistance temperature detectors.

Park, Suhyeon↗
NASA NTRS2020

Nitric Oxide Laser-Induced Fluorescence Rotational Thermometry in a Hypersonic Non-Equilibrium Flow

Spatially-resolved nitric oxide (NO) planar laser-induced fluorescence (PLIF) rotational thermometry was performed on a Mach 5 non-equilibrium flow around a blunt-body specimen in the Hypersonic Materials Environmental Test System (HyMETS) arc-heat wind tunnel at the NASA Langley Research Center. Transitions within the (0,0) band in the A(exp⁡ 2)∑(sup⁡ +) - X(exp⁡ 2)Π system of NO were excited with a 10 Hz pulsed ultra-violet laser. A multi-line fitting algorithm was applied to the PLIF spectra and transitions were filtered based on an iterative method that maximizes thermometry accuracy. NO PLIF thermometry results are compared to non-equilibrium computational fluid dynamics (CFD) simulations reported in the literature. Differences between the experiment and CFD are quantified for the free-stream, post-shock, shear-layer, and expansion-fan regions of the flow. Potential sources of error, applicable to both the CFD and experiment, are discussed.

Connor C McDougall↗
NASA NTRSDate not supplied

Nitric Oxide Planar Laser Induced Fluorescence Rotational Thermometry Characterization of A Hypersonic Boundary Layer

Nitric oxide (NO) planar laser-induced fluorescence (PLIF) was performed to determine rotational temperature profiles and fluctuations within a hypersonic boundary layer above the surface of a 2.75° half-angle wedge. The experiments were performed in the Texas A&M University Actively Controlled Expansion (ACE) hypersonic blow-down wind tunnel at Mach = 5.7 and 𝑅𝑒 = 6 × 10 6 /m. The NO was introduced to the flow in the settling chamber of the ACE tunnel and probed using two laser sheets near 226 nm. The resulting NO PLIF fluorescence signal was acquired using in-house software, which simultaneously recorded tunnel conditions. After a Fast Fourier Transform (FFT) blurring and statistical treatment was performed, the preshock temperature was evaluated to be 58 ± 2 K (3.5%), while the turbulent boundary layer temperature near the wall was found to be 350 K with fluctuations on the order of ±25 K (7%). The relative temperature fluctuations were determined to be 3 − 5% in the freestream and peaked at 33% in the turbulent boundary layer. The advantages and disadvantages of seeding NO in the tunnel settling chamber for thermometric PLIF measurements are discussed.

Hypersonics↗
DOE OSTI2012

Bright upconversion luminescence and increased Tc in CaBi{sub 2}Ta{sub 2}O{sub 9}:Er high temperature piezoelectric ceramics

Er{sup 3+} doped CaBi{sub 2}Ta{sub 2}O{sub 9} (CBT) bismuth layered-structure high temperature piezoelectric ceramics were synthesized by the traditional solid state method. The upconversion (UC) emission properties of Er{sup 3+} doped CBT ceramics were investigated as a function of Er{sup 3+} concentration and incident pump power. A bright green upconverted emission was obtained under excitation 980 nm at room temperature. The observed strong green and weak red emission bands corresponded to the transitions from {sup 4}S{sub 3/2} and {sup 4}F{sub 9/2} to {sup 4}I{sub 15/2}, respectively. The dependence of UC emission intensity on pumping power indicated that a three-photon process was involved in UC emissions. Studies of dielectric with temperature have also been carried out. Introduction of Er increased the Curie temperature of CBT, thus, making this ceramic suitable for sensor applications at higher temperatures. Because of its strong up-converted emission and increased Tc, the multifunctional high temperature piezoelectric ceramic may be useful in high temperature sensor, fluorescence thermometry, and optical-electro integration applications.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Atomic fluorescence study of high temperature aerodynamic levitation

Ultraviolet laser induced atomic fluorescence has been used to characterize supersonic jet aerodynamic levitation experiments. The levitated specimen was a 0.4 cm sapphire sphere that was separately heated at temperatures up to 2327 K by an infrared laser. The supersonic jet expansion and thermal gradients in the specimen wake were studied by measuring spatial variations in the concentration of atomic Hg added to the levitating argon gas stream. Further applications of atomic fluorescence in containerless experiments, such as ideal gas fluorescence thermometry and containerless process control are discussed.

Nordine, P. C.↗
NASA NTRS1990

Fluorescence spectroscopy and thermometry for hypersonic flight research

The present study, which has demonstrated the feasibility of using time-resolved laser-induced fluorescence methods to ascertain boundary layer temperature distributions in real time for hypersonic vehicles in atmospheric flight, employs conventional optics in combination with novel time-resolved spectroscopy. The radiative lifetime and signal intensity involved, both of which are reduced by quenching, are adequate for measurement with state-of-the-art time-resolved fluorescence techniques, except for certain conditions associated with both the highest speeds and the lowest altitudes.

Thompson, B. E.↗
NASA NTRS1990

Laser-induced fluorescence of phosphors for remote cryogenic thermometry

Remote cryogenic temperature measurements can be made by inducing fluorescence in phosphors with temperature-dependent emissions and measuring the emission lifetimes. The thermographic phosphor technique can be used for making precision, noncontact, cryogenic-temperature measurements in electrically hostile environments, such as high dc electric or magnetic fields. The National Aeronautics and Space Administration is interested in using these thermographic phosphors for mapping hot spots on cryogenic tank walls. Europium-doped lanthanum oxysulfide (La2O2S:Eu) and magnesium fluorogermanate doped with manganese (Mg4FGeO6:Mn) are suitable for low-temperature surface thermometry. Several emission lines, excited by a 337-nm ultraviolet laser, provide fluorescence lifetimes having logarithmic dependence with temperature from 4 to above 125 K. A calibration curve for both La2O2S:Eu and Mg4FGeO6:Mn is presented, as well as emission spectra taken at room temperature and 11 K.

Beshears, D. L.↗
NASA NTRS1990

Laser-induced fluorescence of phosphors for remote cryogenic thermometry

Remote cryogenic temperature measurements can be made by inducing fluorescence in phosphors with temperature-dependent emissions and measuring the emission lifetimes. The thermographic phosphor technique can be used for making precision, noncontact, cryogenic-temperature measurements in electrically hostile environments, such as high dc electric or magnetic fields. The National Aeronautics and Space Administration is interested in using these thermographic phosphors for mapping hot spots on cryogenic tank walls. Europium-doped lanthanum oxysulfide (La2O2S:Eu) and magnesium fluorogermanate doped with manganese (Mg4FGeO6:Mn) are suitable for low-temperature surface thermometry. Several emission lines, excited by a 337-nm ultraviolet laser, provide fluorescence lifetimes having logarithmic dependence with temperature from 4 to above 125 K. A calibration curve for both La2O2S:Eu and Mg4FGeO6:Mn is presented, as well as emission spectra taken at room temperature and 11 K.

Beshears, D. L.↗
DOE OSTI2016

CdSe/ZnS quantum dot fluorescence spectra shape-based thermometry via neural network reconstruction

As a system of interest gets small, due to the influence of the sensor mass and heat leaks through the sensor contacts, thermal characterization by means of contact temperature measurements becomes cumbersome. Non-contact temperature measurement offers a suitable alternative, provided a reliable relationship between the temperature and the detected signal is available. In this work, exploiting the temperature dependence of their fluorescence spectrum, the use of quantum dots as thermomarkers on the surface of a fiber of interest is demonstrated. The performance is assessed of a series of neural networks that use different spectral shape characteristics as inputs (peak-based—peak intensity, peak wavelength; shape-based—integrated intensity, their ratio, full-width half maximum, peak normalized intensity at certain wavelengths, and summation of intensity over several spectral bands) and that yield at their output the fiber temperature in the optically probed area on a spider silk fiber. Starting from neural networks trained on fluorescence spectra acquired in steady state temperature conditions, numerical simulations are performed to assess the quality of the reconstruction of dynamical temperature changes that are photothermally induced by illuminating the fiber with periodically intensity-modulated light. Comparison of the five neural networks investigated to multiple types of curve fits showed that using neural networks trained on a combination of the spectral characteristics improves the accuracy over use of a single independent input, with the greatest accuracy observed for inputs that included both intensity-based measurements (peak intensity) and shape-based measurements (normalized intensity at multiple wavelengths), with an ultimate accuracy of 0.29 K via numerical simulation based on experimental observations. The implications are that quantum dots can be used as a more stable and accurate fluorescence thermometer for solid materials and that use of neural networks for temperature reconstruction improves the accuracy of the measurement.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Non-intrusive temperature measurements in the vicinity of a thermocouple using synchrotron x-ray fluorescence

A highly spatially resolved synchrotron x-ray fluorescence (XRF) thermometry technique has been used to map temperature fields around a 125 mu m type R thermocouple immersed in a stoichiometric premixed methane flame. The high spatial resolution of the XRF technique allowed temperatures to be measured close to the thermocouple and the impact of the thermocouple on the flame to be assessed. This paper discusses some of the nontrivial challenges of these measurements including the recovery of spectral features from the krypton fluorescent agent that are overlapped by those from the thermocouple metals at locations near the bead surface. The calculated temperatures from 1D premixed flame simulations are in excellent agreement with measurements along the centerline. The results show that the 125 mu m thermocouple induces minimal disturbances to the gas flow and any catalytic effects originating from the bare wires are also inconsequential. Here, the methodology has advanced to a stage where it enables comparisons between the gas temperature in the vicinity of the thermocouple and the actual thermocouple reading.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

Phosphor Thermometry Signal Analysis and Interpretation

Since the last International Temperature Symposium, phosphor thermometry has continued to mature with considerable attention given to combustion and turbine engine applications. More recently the utility to problems on the micro- and nano-scales has appreciated, particularly in regard to biological and biomedical situations. The method is therefore used for a wide range of situations. Signal interpretation is important and experience teaches that without sufficient care phosphor signals can be misleading. In order to advance the method, signal analysis investigations should prove fruitful. The specific aspect addressed here is the question of waveform sampling. A simple phenomenological approach is described that explores how the number of points digitized per waveform affects the measurement repeatability and accuracy. This is demonstrated for single shot signals and the average of 512 sequential waveforms. A bright temperature-independent luminescence signal from YVO4:Eu is sampled every 800 ps for a highly sampled condition and every 8 microseconds for a low sampled condition. When the average of 512 waveforms are compared for the two sampling conditions, they differ by only 0.4%. For the highly sampled case, a noisy single shot waveform compared to the averaged waveform differed by 1.8%. Future efforts on this subject will address intermediate and lower sampling rates. Also, variable window techniques should be explored that are especially important for non-log-linear signals. Investigations, such as this, give the developer the requisite information for designing analysis systems appropriate for the intended application in terms of precision, accuracy, and response time.

Fluorescence thermometry↗
DOE OSTI2012

Design of Phosphor Thermometry System for Transient High Heat Flux Surface Thermometry

Abstract: A transformative calibration methodology is presented for predicting transient surface temperatures in a thermally conducting medium from in-depth, time-varying temperature measurements. The surface temperature is resolved using two experimental runs and a newly devised first-kind Volterra integral equation. The first experimental run involves calibration with known surface temperature while the second run involves resolving the surface temperature of interest through the ill-posed integral equation. This paper presents the concept genesis and numerically demonstrates the concept for feasibility, robustness, stability and accuracy. From this demonstration, we propose to implement surface placed thermographic phosphors in the calibration stage of the inverse method for estimating the required surface temperature. As a preliminary study, we consider transient, constant property, onedimensional heat conduction in a semi-infinite medium. It is mathematically demonstrated that a Volterra integral equation of the first kind is developed for estimating the surface temperature using a calibrated system (host material and sensor). Sensor characterization, explicit sensor positioning and thermophysical properties are implicitly contained in the new calibration integral equation. The calibration integral equation displays only four terms; namely, the measured front surface temperature and corresponding measured in-depth temperature response associated with the calibration run; and, the unknown surface temperature and its measured in-depth temperature response associated with the second run. Preliminary numerical results indicate the merit of the concept. This paper suggests using thermographic phosphors for estimating the surface temperature in the calibration portion of the process owing to their rapid thermal response, good surface thermal contact characteristics and lack of capacitance for assuring minimal delay. Though the present paper describes the theoretical basis for resolving such problems, it is intended for near-term application using the UTK s high-heat flux laser facility which is presently under development

Fluorescence thermometry↗
DOE OSTI2012

Progress Toward Luminescence-Based VAATE Turbine Blade And Vane Temperature Measurement

Progress towards fielding luminescence-based temperature measurements for the Versatile Affordable Advanced Turbine Engine (VAATE) program is described. The near term programmatic objective is to monitor turbine vane temperatures and health by luminescence from a rare-earth doped thermal barrier coating (TBC), or from a thermographic phosphor layer coated onto a TBC. The first goal is to establish the temperature measurement capability to 1300 C with 1 percent uncertainty in a test engine. An eventual goal is to address rotating turbine blades in an F135 engine. The project consists of four phases, of which the first two have been completed and are described in this paper. The first phase involved laser heating of a 2.54-cm-diameter test sample, coated with a TBC and a thermographic phosphor layer, to produce a thermal gradient across the TBC layer similar to that expected in a turbine engine. Phosphor temperatures correlated well with those measured by long wavelength pyrometry. In the second phase, 10x10- cm coupons were exposed to a jet fuel flame at a burner rig facility. The thermographic phosphor/TBC combination survived the aggressive flame and high exhaust gas velocity, even though the metal substrate melted. Reliable temperature measurements were made up to about 1400 C using YAG:Dy as the thermographic phosphor. In addition, temperature measurements using YAG:Tm showed very desirable background radiation suppression.

Fluorescence thermometry↗
NASA NTRSDate not supplied

10-kHz PLIF Thermometry for Turbulent Jet Flame using Single Burst-mode OPO

Two-color Planar Laser-Induced Fluorescence (TC-PLIF) thermometry techniques that employ two laser systems and two cameras face challenges when implemented in practical combustion facilities because of experimental complexity and multiple laser and camera requirements, particularly for high-speed TC-PLIF. To circumvent those problems, we developed a fast, dual-wavelength switching, burst-mode OPO technology to significantly reduce the experimental complexity of high-speed TC-PLIF thermometry and simplify its implementation in harsh combustion and flow test facilities. A fast, dual-wavelength switched seed laser enabled a high-energy, high-repetition-rate burst-mode laser to generate two 10-kHz pulse trains at wavelengths of ~354.8 nm. The injection-seeded OPO efficiently converts the burst-mode laser output to 285.62 nm and 285.67 nm to excite the Q2(12) andP1(8) OH transitions. PLIF images were collected from each of the two excitation transitions with a single camera and an UV intensifier, and intensity ratios from the images were used to determine local temperatures. Ten kHz hydroxyl radical (OH) TC-PLIF for premixedCH4/Air/H2 jet flame was demonstrated.

thermometry↗
NASA NTRSDate not supplied

10-kHz PLIF Thermometry for a Turbulent Jet Flame using Single Burst-mode OPO

Two-color Planar laser-induced fluorescence (TC-PLIF) thermometry techniques that employ two laser systems and two cameras face challenges when implemented in practical combustion facilities because of experimental complexity and multiple laser and camera requirements, particularly for high-speed TC-PLIF. To circumvent those problems, we developed a fast, dual-wavelength switching, burst-mode OPO technology to significantly reduce the experimental complexity of high-speed TC-PLIF thermometry and simplify its implementation in harsh combustion and flow test facilities. A fast, dual-wavelength switched seed laser enabled a high-energy, high-repetition-rate burst-mode laser to generate two 10-kHz pulse trains at wavelengths of ~354.8 nm. The injection-seeded OPO efficiently converts the burst-mode laser output to285.62 nm and 285.67 nm to excite the Q2(12) and P1(8) OH transitions. PLIF images were collected from each of the two excitation transitions with a single camera and an UV intensifier, and intensity ratios from the images were used to determine local temperatures. Ten kHz hydroxyl radical (OH) TC-PLIF for premixedCH4/Air/H2 jet flame was demonstrated.

thermometry↗
DOE OSTI2022

One-dimensional air temperature measurements by air resonance enhanced multiphoton Ionization thermometry (ART)

In this work, a detailed calibration study is performed to establish non-intrusive one-dimensional (1D) rovibrational temperature measurements in unseeded air, based on air resonance enhanced multiphoton ionization thermometry (ART). ART is generated by REMPI (resonance enhanced multi-photon ionization) of molecular oxygen and subsequent avalanche ionization of molecular nitrogen in a single laser pulse. ART signal, the fluorescence from the first negative band of molecular nitrogen, is directly proportional to the 2-photon transition of molecular oxygen C 3 Π (v = 2) ← X 3 Σ (v’=0), which is used to determine temperature. Experimentally, hyperfine structures of the O 2 rotational branches with high temperature sensitivity are selectively excited through a frequency-doubled dye laser. Electron-avalanche ionization of N 2 results in the fluorescence emissions from the first negative bands of N 2 + near 390, 425, and 430nm, which are captured as a 1D line by a gated intensified camera. Post processing of the N 2 + fluorescence yields a 1D thermometry line that is representative of the air temperature. It is demonstrated that the technique provides ART fluorescence of ∼5cm in length in the unseeded air, presenting an attractive thermometry solution for high-speed wind tunnels and other ground test facilities.

42 ENGINEERING↗
DOE OSTI2017

Facile synthesis and temperature-dependent luminescence of single-phase dual-emitting CdTe@NaNO{sub 3} composite

Graphical abstract: Single-phase dual-emitting CdTe@NaNO{sub 3} composite was prepared by a facile and efficient aqueous ethanol phase assisted coprecipitation method. Its use in self-referencing luminescent thermometry was tested, by exploiting the temperature-dependence of fluorescence intensity ratio (green/red) in range of 273–473 K. - Highlights: • Single-phase green and red dual-emitting CdTe@NaNO{sub 3} composite was prepared. • CdTe QDs embedded in NaNO{sub 3} matrices exhibit photoluminescence quantum yields of 35%. • Temperature-dependent luminescent properties of CdTe@NaNO{sub 3} composite were studied. • It could be a good candidate for ratiometric temperature sensing with a high relative sensitivity. - Abstract: Single-phase dual-emitting CdTe@NaNO{sub 3} composite was prepared by a facile and efficient aqueous ethanol phase assisted coprecipitation method, providing a new type of solid-state luminescent material with processability, robustness and high luminescence. Cubic-shape Green + Red (G + R) CdTe@NaNO{sub 3} composite particles display single-excitation, dual-emission with two well-resolved, intensity-comparable fluorescence peaks. Its application potential in ratiometric luminescent thermometry was tested, by exploiting the temperature-dependence of fluorescence intensity ratio (green/red) in range of 273–473 K, and the maximum sensitivity is found to be 0.6183% K{sup −1} at 473 K. The results indicate that dual-emitting G + R CdTe@NaNO{sub 3} composite could be considered as potential candidates for ratiometric temperature sensing.

36 MATERIALS SCIENCE↗