Materials Data on Fe(BrN)2 by Materials Project
FeN2(Br)2 crystallizes in the orthorhombic Pbam space group. The structure is zero-dimensional and consists of four hydrobromic acid molecules and two FeN2 clusters. In each FeN2 cluster, Fe2+ is bonded in a linear geometry to two equivalent N3- atoms. Both Fe–N bond lengths are 1.70 Å. N3- is bonded in a single-bond geometry to one Fe2+ atom.
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