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At least 19 records

Baseline Postirradiation Examination of the FUTURIX-FTA Experiments

Postirradiation Examination (PIE) results from the baseline examination of the FUTURIX-FTA irradiation experiment are presented in this report. The FUTURIX-FTA irradiation was designed to study the fuel performance of candidate transmutation fuels. The FUTURIX-FTA experiment was conducted in the true fast neutron spectrum conditions of the Phénix sodium fast test reactor in France. FUTURIX-FTA contained several compositions that were also irradiated as part of the AFC-1 test in cadmium filtered positions in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR) that approximate the neutron spectrum of a fast reactor. This experiment was a joint collaboration between the Department of Energy (DOE) in the U.S. and the Commissariat á l'Energie Atomique et aux Energies Alternatives (CEA) in France. A joint agreement between DOE and CEA was established in 2004 to conduct an irradiation experiment of metallic and nitride fuels in the Phénix reactor at CEA. Both the FUTURIX-FTA tests and the AFC-1 tests were conducted for the DOE Advanced Fuels Campaign (AFC) that is part of Fuel Cycle Research & Development (FCRD) program. These programs seek to develop and demonstrate the technologies needed to transmute long-lived transuranic actinide isotopes contained in spent nuclear fuel via fast reactor technology. The long term goal of this work is to reduce the radiotoxicity of future high level waste repositories. Post-irradiation examination of irradiated fuels experiments provides data related to in reactor fuel performance and input into future fuel design choices. The compositions of the FUTURIX-FTA pins were designed to test if minor actinides could be incorporated into the fuel of a fast reactor without significantly changing fuel performance observed for previously well studied fuels. The fuel performance of metallic fuel in fast reactors has been well documented. Likewise the irradiation performance of nitride fuels in fast reactors has also been documented. However the existing database for nitride fuels is much smaller than the database for metal fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fault Tolerance Assistant (FTA): An Exception Handling Programming Model for MPI Applications

Future high-performance computing systems may face frequent failures with their rapid increase in scale and complexity. Resilience to faults has become a major challenge for large-scale applications running on supercomputers, which demands fault tolerance support for prevalent MPI applications. Among failure scenarios, process failures are one of the most severe issues as they usually lead to termination of applications. However, the widely used MPI implementations do not provide mechanisms for fault tolerance. We propose FTA-MPI (Fault Tolerance Assistant MPI), a programming model that provides support for failure detection, failure notification and recovery. Specifically, FTA-MPI exploits a try/catch model that enables failure localization and transparent recovery of process failures in MPI applications. We demonstrate FTA-MPI with synthetic applications and a molecular dynamics code CoMD, and show that FTA-MPI provides high programmability for users and enables convenient and flexible recovery of process failures.

97 MATHEMATICS AND COMPUTING↗

Postirradiation Examination of FUTURIX-FTA metallic alloy experiments

Two different metallic nuclear fuel alloys intended for transmutation applications in fast neutron spectrum nuclear reactors have been irradiated, and their performance has been evaluated after irradiation. These alloys contained elevated levels of plutonium and other minor actinides (Am, Np) compared to historically irradiated fast reactor fuel to ascertain the impact of these isotopes on fuel performance. The irradiation of these alloys was performed at the Phénix fast reactor in France to facilitate comparisons between true fast spectrum irradiations and pseudo-fast spectrum irradiations performed at the thermal neutron spectrum Idaho National Laboratory Advanced Test Reactor. The irradiation tests were designated FUTURIX-FTA DOE1 which contained a low-fertile alloy and FUTURIX-FTA DOE2 which contained a non-fertile alloy. The DOE1 fuel was irradiated to a measured burnup of 9.5 % fissions per initial heavy metal atom (FIMA), and the DOE2 fuel was irradiated to a measured burnup of 12.7 % fissions per initial heavy metal atom. This work reports baseline Postirradiation Examination (PIE) results for DOE1 and DOE2. Fuel swelling, fission product distribution, cladding strain, fission gas release, fuel microstructure, fuel cladding chemical interaction and minor actinide transmutation were all evaluated. Cladding strain was negligible and fission gas release was 52% for DOE1 and 69% for DOE2. The exams show the 2 pins behaved very similar to EBR-II metallic fuel experience. Minor actinides seem to not affect the performance of this candidate transmutation fuel. As a result, performance data from these irradiations can be used to inform the feasibility of minor actinide transmutation in future reactor systems.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Overview of the FUTURIX-FTA Irradiation Experiment in the Phénix Reactor

The Advanced Fuels Campaign utilizes the Advanced Test Reactor (ATR) for most of its irradiation testing. Cadmium-shrouded baskets are used in ATR to modify the neutron spectrum to simulate a fast reactor environment for the fuel. FUTURIX-FTA is an irradiation experiment conducted in the Phenix fast reactor in France. Results from FUTURIX-FTA and irradiation tests in ATR using identical fuel compositions will be compared to identify and evaluate any differences in fuel behavior due to differences in the irradiation source.

fast reactor↗

Summary of FUTURIX-FTA Non-destructive Examination

A summary of results from the non-destructive examination of the FUTURIX-FTA irradiation are presented. This irradiation was conducted under true fast spectrum conditions in the Phenix reactor. Baseline non-destructive examinations of these tests have been completed at this time. Results from visual examination, neutron radiography, gamma spectrometry, and dimensional inspection have been collected. The data collected from this irradiation will be compared to sister irradiations performed in pseudo-fast spectrum conditions at the INL Advanced Test Reactor helping to confirm fuel performance behavior observed in Advanced Test Reactor irradiations is representative of fast reactor conditions. All indications from the non-destructive examinations performed on the FUTURIX-FTA elements indicate a successful irradiation with fuel performance in line with expectations. The intact state of the nitride fuel is especially notable as these pellets were fragile after fabrication, but they appear to have survived the irradiation and extensive shipping well. These rodlets will undergo further examination to include gamma tomography to investigate the radial fission product distribution, fission gas release analysis, optical metallography, microhardness testing, and chemical burnup analysis. If possible, cross sections from optical metallography may also be examined by more advanced techniques such as scanning electron microscopy and transmission electron microscopy of specific sites through the use of focused ion beam lift outs. The results of all these examinations will be compared with the results from the AFC-1B, AFC-I1D, AFC-IF, AFC-1G, AFC-1H and AFC-LAE irradiations. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Reliability Prediction using FMEA, FTA, and Related Techniques [Slides]

Summary: We presented a reliability analysis framework. We made point estimates of reliability using reliability block diagrams, fault trees, success trees and estimates with uncertainty using expert elicitation, Monte Carlo simulation, Bayesian analysis. Expert elicitation of failure modes and probabilities is labor-intensive, but critical. Bayesian analysis updates information from expert elicitation with data from reliability and aging tests (aging/compatibility data are needed to estimate lower-bound reliabilities at end of life). Estimation by more than one method helps insure consistency and accuracy.

97 MATHEMATICS AND COMPUTING↗

Preparations, structures and properties of heterobimetallic complexes based on tetrahydrofuran-2,3,4,5-tetracarboxylate

Transition heterobimetallic metal-organic frameworks based on tetrahydrofuran-2,3,4,5-tetracarboxylicate (FTA), namely [M(H₂O)₆][Cu₂M(FTA)₂(H₂O)₂]·4H₂O [M=Mn (1), Co (2)], and [CuZn(FTA)(H₂O)₅]·H₂O (3) have been synthesized and characterized. Single-crystal X-ray diffraction indicates that complexes 1 and 2 are isomorphic. In 1 and 2, FTA ligand links the metal ions to a 2-D wave-like negative-charged layer with a topology of (4;6²)₂(4;6³;8²)₂(6). They possess 1-D channels with [M(H₂O)₆]²⁺ and lattice water molecules enclathrated. While in the complex 3, Cu²⁺ and Zn²⁺ ions are bridged by FTA to a 2-D neutral layer structure with a (8)₂(8⁴;12²) topology. Magnetic properties of 1–3 were analyzed in connection with their structures, which show that there exist weak antiferromagnetic interactions between metal ions. - Graphical abstract: Three heterobimetallic MOFs were constructed through the size-selectivity of TFA coordination sites for different transition metal ions based on the concept of “Hard and Soft Acids and Bases”. Highlights: • Complexes 1 and 3 contain 2-D wave-like negative-charged layers. • Complex 2 is a 2-D neutral layer structure with a (8)₂(8⁴;12²) topology. • Complexes 1–3 are the first example of heterobimetallic MOFs based on FTA. • The coordination sites of FTA show size-selectivity to metal ions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Zero-Emission Bus Evaluation Results: County Connection Battery Electric Buses

The U.S. Department of Transportation's (DOT's) Federal Transit Administration (FTA) supports the research, development, and demonstration of low- and zero-emission technology for transit buses. FTA funds research projects with a goal of facilitating commercialization of advanced technologies for transit buses that will increase efficiency and improve transit operations. DOT's Research, Development, and Technology Office (OST-R) also has an interest in zero-emission bus (ZEB) technology deployment and commercialization. OST-R is coordinating and collaborating with FTA on the evaluation process and results by providing funding to cover additional evaluations. FTA and OST-R are collaborating with the U.S. Department of Energy (DOE) and DOE's National Renewable Energy Laboratory (NREL) to conduct in-service evaluations of advanced technology buses developed under its programs. NREL uses a standard evaluation protocol for evaluating the advanced technologies deployed under the FTA programs. FTA seeks to provide results from new technologies being adopted by transit agencies. The eight evaluations selected to date include battery electric buses (BEBs) and fuel cell electric buses (FCEBs) from different manufacturers operating in fleets located in both cold and hot climates. The purpose of this report is to present the results from Central Contra Costa Transit Authority (County Connection) deployment of four BEBs in Concord, California. NREL's evaluation of the BEBs at County Connection was funded by OST-R.

33 ADVANCED PROPULSION SYSTEMS↗

King County Metro Battery Electric Bus Demonstration: Preliminary Project Results

The U.S. Federal Transit Administration (FTA) funds a variety of research projects that support the commercialization of zero-emission bus technology. To evaluate projects funded through these programs, FTA has enlisted the help of the National Renewable Energy Laboratory (NREL) to conduct third-party evaluations of the technologies deployed under the FTA programs. NREL works with the selected agencies to evaluate the performance of the zero-emission buses compared to baseline conventional buses in similar service. The evaluation effort will advance the knowledge base of zero-emission technologies in transit bus applications and provide 'lessons learned' to aid other fleets in incrementally introducing next generation zero-emission buses into their operations. This report provides preliminary performance evaluation results from a demonstration of three zero-emission battery electric buses at King County Metro in King County, Washington. NREL developed this preliminary results report to quickly disseminate evaluation results to stakeholders. Detailed evaluation results will be published in future reports.

25 ENERGY STORAGE↗

County Connection Battery Electric Bus Demonstration: Preliminary Project Results

The U.S. Federal Transit Administration (FTA) funds a variety of research projects that support the commercialization of zero-emission bus technology. To evaluate projects funded through these programs, FTA has enlisted the help of the National Renewable Energy Laboratory (NREL) to conduct third-party evaluations of the technologies deployed under the FTA programs. NREL works with the selected agencies to evaluate the performance of the zero-emission buses compared to baseline conventional buses in similar service. The evaluation effort will advance the knowledge base of zero-emission technologies in transit bus applications and provide 'lessons learned' to aid other fleets in incrementally introducing next generation zero-emission buses into their operations. This report provides preliminary performance evaluation results from a demonstration of four all-electric trolley-replica buses and two electric vehicle charging stations at County Connection in the San Francisco Bay Area. NREL developed this preliminary results report to quickly disseminate evaluation results to stakeholders. Detailed evaluation results will be published in future reports.

25 ENERGY STORAGE↗

MO-E-9A-01: Risk Based Quality Management: TG100 In Action

One of the goals of quality management in radiation therapy is to gain high confidence that patients will receive the prescribed treatment correctly. To accomplish these goals professional societies such as the American Association of Physicists in Medicine (AAPM) has published many quality assurance (QA), quality control (QC), and quality management (QM) guidance documents. In general, the recommendations provided in these documents have emphasized on performing device-specific QA at the expense of process flow and protection of the patient against catastrophic errors. Analyses of radiation therapy incidents find that they are most often caused by flaws in the overall therapy process, from initial consult through final treatment, than by isolated hardware or computer failures detectable by traditional physics QA. This challenge is shared by many intrinsically hazardous industries. Risk assessment tools and analysis techniques have been developed to define, identify, and eliminate known and/or potential failures, problems, or errors, from a system, process and/or service before they reach the customer. These include, but are not limited to, process mapping, failure modes and effects analysis (FMEA), fault tree analysis (FTA), and establishment of a quality management program that best avoids the faults and risks that have been identified in the overall process. These tools can be easily adapted to radiation therapy practices because of their simplicity and effectiveness to provide efficient ways to enhance the safety and quality of treatment processes. Task group 100 (TG100) of AAPM has developed a risk-based quality management program that uses these tools. This session will be devoted to a discussion of these tools and how these tools can be used in a given radiotherapy clinic to develop a risk based QM program. Learning Objectives: Learn how to design a process map for a radiotherapy process. Learn how to perform a FMEA analysis for a given process. Learn what Fault tree analysis is all about. Learn how to design a quality management program based upon the information obtained from process mapping, FMEA and FTA.

60 APPLIED LIFE SCIENCES↗

Field expedient stool collection methods for gut microbiome analysis in deployed military environments

ABSTRACT Field expedient devices and protocols for the collection, storage, and shipment of stool samples in deployed settings are needed for the advancement of microbiome research in military health. Relevant assessments include the evaluation of microbiome signatures associated with susceptibility to travelers’ diarrhea and recovery of gut function following infection. However, inherent biases in microbial measurements due to preservatives and sampling methods are unclear and should be assessed for an accurate evaluation of the microbiome. We performed shotgun metagenomic sequencing and compared the microbiome composition in paired fecal samples collected using Flinters Technology Associates (FTA) cards and OMNIgene (OG) Gut tubes, prior to and during international travel, from 49 adult participants, 39 of whom remained asymptomatic and 10 experienced travelers’ diarrhea. Higher concentrations of nucleic acid and sequencing libraries were observed in OG samples. A majority of genera (82.9%) were detected with both methods, and detections of genera limited to one collection method were not highly prevalent across samples and were present in extremely low relative abundances (<0.01%). Differences in beta diversity were largely explained by inter-individuality of microbiome composition, followed by the effect of collection method and timepoint-disease states. Differential abundance analysis indicated that Corynebacterium and Blautia were consistently higher in abundance across all groups with FTA and OG collection, respectively. The observed differences in microbiome composition between methods suggest the need for consistent and standardized protocols within a study. Overall, the data presented here could help guide the future design of fecal microbiome study protocols in field and military deployment settings. IMPORTANCE The assessment of field-deployable methods for fecal sample collection and storage is required to reliably capture samples collected in remote and austere locations. This study describes a comparative metagenomics analysis between samples collected by two different commercially available methods in a military-deployed setting. The results presented here are foundational for the future design of fecal microbiome study protocols in an operational context.

field study↗

American Fuel Cell Bus Project Evaluation. Second Report

This report presents results of the American Fuel Cell Bus (AFCB) Project, a demonstration of fuel cell electric buses operating in the Coachella Valley area of California. The prototype AFCB was developed as part of the Federal Transit Administration's (FTA's) National Fuel Cell Bus Program. Through the non-profit consortia CALSTART, a team led by SunLine Transit Agency and BAE Systems developed a new fuel cell electric bus for demonstration. SunLine added two more AFCBs to its fleet in 2014 and another in 2015. FTA and the AFCB project team are collaborating with the U.S. Department of Energy (DOE) and DOE's National Renewable Energy Laboratory to evaluate the buses in revenue service. This report summarizes the performance results for the buses through June 2015.

30 DIRECT ENERGY CONVERSION↗

American Fuel Cell Bus Project Evaluation: Third Report

This report presents results of the American Fuel Cell Bus (AFCB) Project, a demonstration of fuel cell electric buses operating in the Coachella Valley area of California. The prototype AFCB, which was developed as part of the Federal Transit Administration's (FTA) National Fuel Cell Bus Program, was delivered to SunLine in November 2011 and was put in revenue service in mid-December 2011. Two new AFCBs with an upgraded design were delivered in June/July of 2014 and a third new AFCB was delivered in February 2015. FTA and the AFCB project team are collaborating with the U.S. Department of Energy (DOE) and DOE's National Renewable Energy Laboratory to evaluate the buses in revenue service. This report covers the performance of the AFCBs from July 2015 through December 2016.

33 ADVANCED PROPULSION SYSTEMS↗

Hydrogen Fuel Cell Electric Bus (FCEB) Evaluations in US Public Transit Service

The National Renewable Energy Laboratory (NREL) is a Department of Energy (DOE) national laboratory focused on renewable energy and energy efficiency. NREL has evaluated alternative fuel and advanced propulsion transit buses for DOE and the U.S. Department of Transportation's Federal Transit Administration (FTA). These evaluations are focused on determining the status of fuel cell systems and the corresponding infrastructure in transit applications to help DOE and FTA assess the progress toward technology readiness. For the last 19 years NREL has evaluated FCEBs in service around the United States and in Canada. The results of these evaluations have been published in numerous reports that compare FCEB performance to conventional technology as well as document the implementation experience and lessons learned by the transit agencies and their demonstration teams. Currently, 70 fuel cell buses are in active service in the US and 66 FCEBs are in development. NREL is evaluating a subset of the active FCEBs that includes three transit agencies demonstrating 25 fuel cell electric buses in California. One bus has exceeded 35,000 hours in service and 12 have exceeded 25,000 hours. Fuel economy for the current generation of FCEBs has improved 35% over the previous generation and is double that of conventional buses. Maintenance cost for FCEBs is equivalent to diesel and BEBs. The most up-to-date performance results will be presented, including fuel economy, availability, reliability, and operational costs.

bus↗

Data requirements for improving the Quantitative Risk Assessment of liquid hydrogen storage systems

Quantitative Risk Assessment (QRA) supports the development of risk-informed safety codes and standards which are employed to enable the safe deployment of hydrogen technologies essential to decarbonize the transportation sector. System reliability data is a necessary input for rigorous QRA. Here, the lack of reliability data for bulk liquid hydrogen (LH 2 ) storage systems located on site at fueling stations limits the use of QRAs. In turn, this hinders the ability to develop the necessary safety codes and standards that enable worldwide deployment of these stations. Through a QRA-based analysis of a LH 2 storage system, this work focuses on identifying relevant scenario and probability data currently available and ascertaining future data collection requirements regarding risks specific to liquid hydrogen releases. The work developed consists of the analysis of a general bulk LH 2 storage system design located at a hydrogen fueling station. Failure Mode and Effect Analysis (FMEA) and traditional QRA modeling tools such as Event Sequence Diagrams (ESD) and Fault Tree Analysis (FTA) are employed to identify, rank, and model risk scenarios related to the release of LH 2 . Based on this analysis, scenario and reliability data needs to add LH 2 -related components to QRA are identified with the purpose of improving the future safety and risk assessment of these systems.

08 HYDROGEN↗

Secondary corundum‐bearing assemblages in Allende Ca,Al‐rich inclusions: Mineralogy, petrology, oxygen, and aluminum–magnesium isotope systematics

Here, we report on the mineralogy, petrology, oxygen, and aluminum–magnesium isotopic systematics of the secondary corundum-bearing assemblages in type B CAIs 3529Z and 3529G and fluffy type A (FTA) CAI ALH-2 from Allende (CV > 3.6). In 3529Z and 3529G, 2–5 μm-sized euhedral-to-subhedral corundum grains associate with secondary alumoåkermanite [(Ca,Na) 2 AlSi 2 O 7 ], grossular, spinel, grossite, celsian, kushiroite, and wadalite. In ALH-2, 2–5 μm-sized euhedral-to-subhedral corundum grains associate with secondary grossular, nepheline, spinel, and kushiroite. In 3529Z and 3529G, corundum and associated secondary grossite, spinel, alumoåkermanite, grossular, and kushiroite have similar 16 O-poor compositions (Δ 17 O = −2.2 ± 1.5‰); primary spinel is 16 O-rich (Δ 17 O ~ −23‰); Al,Ti-diopside shows a range of Δ 17 O (from ~ −24‰ to ~ −15‰); anorthite and melilite are 16 O-depleted to various degrees (−6.5‰ ≤ Δ 17 O ≤ −4.5‰ and Δ 17 O = −2.7 ± 0.8‰, respectively). In ALH-2, corundum shows a range of Δ 17 O, from ~ −9‰ to ~ −1‰; primary hibonite and spinel are 16 O-rich (Δ 17 O ~ −23‰); melilite and perovskite are 16 O-poor (Δ 17 O = −2.6 ± 1.5‰ and −3.1 ± 1.3‰, respectively). On the Al-Mg isotope diagram ( 26 Mg* versus 27 Al/ 24 Mg), primary Al,Ti-diopside, hibonite, melilite, and spinel in the Allende CAIs studied along the canonical isochron with inferred initial 26 Al/ 27 Al ratio [( 26 Al/ 27 Al) 0 ] of ~5 × 10 −5 . All secondary minerals have resolved excesses of 26 Mg*: alumoåkermanite, corundum, and grossite plot below the canonical isochron, whereas most spinel analyses plot above it. An internal isochron defined by the coexisting secondary corundum and alumoåkermanite in 3529Z has ( 26 Al/ 27 Al) 0 = (7.5 ± 2.6) × 10 −7 . We conclude that the corundum-bearing assemblages in Allende CAIs resulted from metasomatic alteration of primary melilite and anorthite, ~4–5 Ma after their crystallization. Metasomatic alteration of CAIs in the Allende parent asteroid by an aqueous fluid having Δ 17 O of ~ −3 ± 2‰ modified the O-isotope composition of their primary melilite, anorthite, and Ti-rich pyroxene; O-isotope compositions of primary hibonite, spinel, and low-Ti pyroxene escaped this modification.

Geosciences↗