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Assessment and Planning of Decarbonization Research and Training at UTRGV

During the one-year project, we identified research areas that align with Fossil Energy and Carbon Management (FECM) mission goals and assessed our university's current research capability and resources. In addition, we determined the resources needed to support FECM-related research and development (R&D) at our minority-serving institution, University of Texas Rio Grande Valley (UTRGV) in to increase our competitiveness for future funding opportunities in this area. We also gathered information on the current academic courses, programs and curriculum at UTRGV that aligns with FECM goals and described additional needs pertaining to student training.

54 ENVIRONMENTAL SCIENCES

Nonlinear Visco-Elastic Response of Composites via Micro-Mechanical Models

Micro-mechanical models for a study of nonlinear visco-elastic response of composite laminae are developed and their performance compared. A single integral constitutive law proposed by Schapery and subsequently generalized to multi-axial states of stress is utilized in the study for the matrix material. This is used in conjunction with a computationally facile scheme in which hereditary strains are computed using a recursive relation suggested by Henriksen. Composite response is studied using two competing micro-models, viz. a simplified Square Cell Model (SSCM) and a Finite Element based self-consistent Cylindrical Model (FECM). The algorithm is developed assuming that the material response computations are carried out in a module attached to a general purpose finite element program used for composite structural analysis. It is shown that the SSCM as used in investigations of material nonlinearity can involve significant errors in the prediction of transverse Young's modulus and shear modulus. The errors in the elastic strains thus predicted are of the same order of magnitude as the creep strains accruing due to visco-elasticity. The FECM on the other hand does appear to perform better both in the prediction of elastic constants and the study of creep response.

Gates, Thomas S.

Carbon Management Projects (CONNECT) Database and Explorer

Overview The Carbon Management Projects (CONNECT) Toolkit is an online exploratory visualization tool developed by the U.S. Department of Energy's (DOE) Office of Fossil Energy and Carbon Management (FECM) with support from other federal agencies such as the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Transportation (DOT). It provides a single point of access to authoritative information on federal agency investment in a portfolio of research, development, and demonstration (RD&D) projects that have been publicly announced to advance technologies for point source carbon capture, carbon dioxide removal, transport, storage, and conversion, collectively referred to as carbon management. The RD&D programs covered in this tool are authorized by annual congressional appropriations ("Base Program") and the 2021 Infrastructure Investment and Jobs Act (IIJA). The tool also incorporates public information on other federal initiatives, such as the Regional Clean Hydrogen Hubs, and public information released by other government agencies, such as the Environmental Protection Agency's (EPA) and Primacy States’ Underground Injection Control Class VI permits and EPA’s facility level greenhouse gas (GHG) emissions. Developed in a geographic information system, the tool organizes carbon management projects into five groups based on the primary technology that a project aims to advance, each visually represented as a digital layer ("carbon management project layer"). Only federally funded projects are included, which can be awarded projects that are completed or ongoing, or projects that have been selected but are currently under negotiation. Project information can be viewed in the map or in the attribute table below it when turned on. In the map view, each project is displayed at either its host site (for field work), where available, or its performer site (project lead's location, further explained in the table below). Host sites and performer sites are represented in distinct icons. Several reference layers offer additional public information on infrastructural and natural resource environment for carbon management. These reference layers, combined with multiple geographical basemaps, enable users to visualize the carbon management project layers in context. Carbon management project information will be updated monthly based on feedback and information availability. Carbon management project layers Point Source Carbon Capture (PSC) This layer contains DOE-funded projects focused on capturing carbon dioxide (CO2) from power plants or industrial facilities. Carbon Dioxide Removal (CDR) This layer contains DOE-funded projects focused on capturing CO2 from the atmosphere, including direct air capture (DAC) and DAC hubs, direct ocean capture, enhanced mineralization, and biomass carbon removal and storage. For projects with multiple host sites, each of the sites are displayed individually with the project cost and cost sharing information representing the total for the entire project. Carbon Transport This layer contains DOE- and DOT-funded projects focused on CO2 transport. The Transport Research and Development sublayer contains projects that do not involve physical infrastructure; the Proposed Transport Corridor sublayer contains projects for which either a route for the transport infrastructure has been proposed or a general area for the transport infrastructure has been identified. Carbon Storage This layer contains DOE-funded key projects focused on CO2 storage. For projects with multiple field-work sites, each of the sites are displayed individually on the map with the project cost and cost sharing information representing the overall total for the entire project. Carbon Conversion This layer contains DOE-funded projects focused on converting CO2 into economically valuable products. Reference layers The following layers provide additional information in the geographic proximity of carbon management projects. Users should reference the original sources for more details (weblinks provided below and in pop-up windows on the map). Regional Clean Hydrogen Hub and Facility These layers illustrate the approximate areas of the Regional Clean Hydrogen Hubs announced by DOE's Office of Clean Energy Demonstrations (OCED) and the approximate locations of individual facilities that constitute the hubs (see "Where are the H2Hubs located?" on the webpage linked above). EPA Facility Level GHG Emissions (direct emitter) This layer shows direct CO2 emissions from stationary sources in 2022, using data extracted from EPA's Facility Level Information on GreenHouse gases Tool (FLIGHT). Captured and injected CO2 are not deducted from direct emitters’ total emissions. Contact EPA for additional details. Underground Injection Control Class VI permit/permit application This layer shows the locations of CO2 injection wells that are granted or in the process of applying for an Underground Injection Control Class VI permit by EPA or a Primacy State (currently Louisiana, North Dakota, and Wyoming). The URLs for the permits or permit applications are provided in the pop-up windows associated with the well locations. Contact EPA for additional details. Carbon Storage Resource This layer contains information on prospective CO2 storage resources in saline formations and oil and gas reservoirs provided by the National Carbon Sequestration Database and Geographic Information System (NATCARB) spatial database. Contact NETL for additional details. Existing CO2 pipeline This layer shows active CO2 pipelines based on information digitized from the map issued by the Pipeline and Hazardous Materials Safety Administration (PHMSA). Contact PHMSA for additional details.

Carbon Conversion

FECM/NETL CO2 Saline Storage Cost Model CO2_S_COM 2024 (v4)

The U.S. Department of Energy's (DOE) Office of Fossil Energy and Carbon Management (FECM), in collaboration with the National Energy Technology Laboratory (NETL), has developed the FECM/NETL CO2 Saline Storage Cost Model (CO2_S_COM). This Excel-based tool provides a comprehensive framework for estimating the costs and breakeven prices associated with storing carbon dioxide (CO2) in deep saline formations. Designed from the perspective of a CO2 storage site owner, the CO2_S_COM incorporates four integrated modules—project management, financial analysis, activity cost estimation, and geological evaluation—to deliver fast, robust and actionable insights for screening project finances.

CO2 storage

Direct Air Capture Recovery of Energy for CCUS Partnership (DAC RECO 2 UP) Final Technical Report

The “Direct Air Capture Recovery of Energy for CCUS Partnership (DAC RECO 2 UP)” project employs a team approach and supports the U.S. Department of Energy Office of Fossil Energy and Carbon Management’s (DOE-FECM) goal to decrease the cost of capture through the testing of existing direct air capture (DAC) materials in integrated field units that produce a concentrated carbon dioxide (CO 2 ) stream of at least 95% purity. Solid-amine CO 2 adsorption-desorption contactor technology, proven in the laboratory, is undergoing high-fidelity design/validation. Recoverable energy is readily available from a large number of commercial locations where DAC can be deployed; therefore, advancing the fidelity of energy recovery to directly reduce the cost of DAC is a key project objective. In addition, many commercial facilities have low-concentration CO 2 vents that are uneconomical to treat alone but could provide more efficient mass and thermal transport to DAC systems with integrated energy recovery and flexible CO 2 treatment capabilities. Technology scale-up leverages past research and occurs in a commercially relevant environment at the National Carbon Capture Center. Prescreening techno-economic analysis, risk assessments, and life cycle analysis are being performed by experienced team members. Results of the project will address critical technical barriers that, when solved, will improve the capital and operating costs of DAC while validating commercial relevance of cost and product quality/need.

54 ENVIRONMENTAL SCIENCES

FECM/NETL CO 2 Saline Storage Cost Model (2024): User’s Manual

The U.S. Department of Energy's (DOE) Office of Fossil Energy and Carbon Management (FECM), in collaboration with the National Energy Technology Laboratory (NETL), has developed the FECM/NETL CO 2 Saline Storage Cost Model (CO2_S_COM). This Excel-based tool provides a comprehensive framework for estimating the costs and breakeven prices associated with storing carbon dioxide (CO 2 ) in deep saline formations. Designed from the perspective of a CO 2 storage site owner, the CO2_S_COM incorporates four integrated modules—project management, financial analysis, activity cost estimation, and geological evaluation—to deliver fast, robust, and actionable insights for evaluating project finances. This is the user's manual for CO2_S_COM. The model may be accessed at this link: FECM/NETL CO2 Saline Storage Cost Model CO2_S_COM 2024 (v4) - Submissions - EDX

54 ENVIRONMENTAL SCIENCES

Preliminary Screening Techno-Economic Analysis of Industrial SOFC/SOEC and Reversible SOC Integration

National Energy Technology Laboratory (NETL) provides system-level process, cost, and market analyses on solid oxide cell (SOC) based technologies. Specifically, techno-economic analyses (TEA), market assessments, and other technology evaluations serve to guide the U.S. Department of Energy (DOE) Office of Fossil Energy and Carbon Management (FECM) Reversible Solid Oxide Fuel Cell (R-SOFC) Program technology goals and objectives. These studies are key to describing how the technologies contribute to improving domestic energy infrastructure in a clean, efficient manner. This effort seeks to elucidate the potential integration opportunities between reversible SOCs and industrial systems which would aid in SOC commercialization and deployment. These preliminary screening-level results show what opportunities exist for power generating SOFCs, hydrogen producing SOECs, and point-source carbon capture. Improvements can be seen through changes in cost of electricity, cost of hydrogen, and cost of carbon capture.

reversible SOC

REPACT tool: A Screening Model for Repurposing Natural Gas Pipelines

Presentation on Reuse of Existing Pipelines for Adapted Carbon Dioxide Transport (REPACT) Tool for the January 2025 FECM interagency CO2 Transport topic team Meeting. The tool enables the user to determine whether a pipeline that was originally deployed for natural gas transport can be reused for carbon dioxide (CO2) transport.

carbon dioxide (CO2)

CMCSCFCB—Critical Minerals in Coaly Strata of the Cherokee-Forest City Basin

This report summarizes results of CMCSCFCB—Critical Minerals in Coaly Strata of the Cherokee-Forest City Basin, a multiyear and multidisciplinary study funded through DE-FOA-0002364 as part of the Department of Energy Office of Fossil Energy and Carbon Management (FECM) Carbon Ore, Rare Earth and Critical Minerals (CORE-CM) Initiative for U.S. Basins. Our working group of state and tribal agencies collected data and made interpretations included herein. It also surveyed the regional potential for critical mineral/material production.

01 COAL, LIGNITE, AND PEAT

"Mining" for Critical Minerals: Critical Minerals from Fossil Energy Waste Byproducts

NETL researcher Mengling Stuckman is an invited speaker for the panel discussion session of "Mining for Critical Minerals" at the Marcellus Shale Coalition event, "Shale 2.0: Learn the Facts about Upstream, Midstream and Downstream". Recent studies from DOE have shown that produced water and drill cuttings from the development of unconventional shale in Appalachia has a significant source of valuable critical minerals and will support bolstering America's supply chain security, putting Pennsylvania in a unique position to capitalize. The panel discussion facilitates obtaining an overview of pipeline capacity needs, downstream users for natural gas and effectively educating and engaging the public relevant to the Marcellus Shale community. The event also offers opportunities for local oil and gas industries, water and waste management companies to work with NETL and participate in FECM’s Critical Mineral program. Industrial feedbacks and participation as outcomes of this invited talk will accelerate the technology and knowledge transfer for the DOE’s Critical Mineral program and for DOE’s mission to unleash American Energy and lead in energy innovation.

critical minerals

Direct Air Capture Case Studies: Sorbent System (Rev. 1)

In 2022, the National Energy Technology Laboratory published a techno-economic assessment (TEA) examining the performance and cost of a generic solid sorbent-based direct air capture (DAC) system, “Direct Air Capture Case Studies: Sorbent System”. Revision 1 of this report builds on the previous effort by updating assumptions to reflect the evolving industry and recent developments in the DAC research and development (R&D) portfolio. Revision 1 of the report also expands the case list to examine a variety of sorbent DAC system configurations. The objective of this series is to present transparent and independent TEAs that can serve as a guideline for sorbent DAC TEA development and highlight potential avenues for cost reductions that can inform R&D. The sorbent considered is not reflective of any one material type; rather, it represents an approximate average of reported material performance in the literature. The base cases presented in this series do not represent optimized systems due to the nascence of the technology and lack of publicly available information. The base cases serve as a reference for informative sensitivity analyses.

54 ENVIRONMENTAL SCIENCES