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Materials Data on WF6 by Materials Project
WF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tungsten hexafluoride molecules. W6+ is bonded in an octahedral geometry to six F1- atoms. All W–F bond lengths are 1.88 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one W6+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one W6+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one W6+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one W6+ atom.
Materials Data on WF5 by Materials Project
WF5 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of one WF5 ribbon oriented in the (1, 0, 1) direction. there are two inequivalent W5+ sites. In the first W5+ site, W5+ is bonded to six F1- atoms to form corner-sharing WF6 octahedra. The corner-sharing octahedral tilt angles are 27°. There are a spread of W–F bond distances ranging from 1.89–2.06 Å. In the second W5+ site, W5+ is bonded to six F1- atoms to form corner-sharing WF6 octahedra. The corner-sharing octahedral tilt angles are 27°. There are a spread of W–F bond distances ranging from 1.89–2.06 Å. There are ten inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two W5+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two W5+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the seventh F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the eighth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the ninth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the tenth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom.
Materials Data on WF5 by Materials Project
WF5 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two WF5 sheets oriented in the (0, 0, 1) direction. W5+ is bonded to eight F1- atoms to form a mixture of edge and corner-sharing WF8 hexagonal bipyramids. There are a spread of W–F bond distances ranging from 1.91–2.21 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two equivalent W5+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the third F1- site, F1- is bonded in a distorted linear geometry to two equivalent W5+ atoms.
Materials Data on WF5 by Materials Project
WF5 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two WF5 ribbons oriented in the (0, 0, 1) direction. W5+ is bonded to six F1- atoms to form corner-sharing WF6 octahedra. The corner-sharing octahedral tilt angles are 30°. There are a spread of W–F bond distances ranging from 1.88–2.06 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the fifth F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent W5+ atoms.