Materials Data on P4PtF12 by Materials Project
Pt(PF3)4 is Tungsten structured and crystallizes in the cubic I-43m space group. The structure is zero-dimensional and consists of two platinum, tetrakis(phosphorus trifluoride)- molecules. Pt2- is bonded in a tetrahedral geometry to four equivalent P+3.50+ atoms. All Pt–P bond lengths are 2.26 Å. P+3.50+ is bonded in a 3-coordinate geometry to one Pt2- and three equivalent F1- atoms. All P–F bond lengths are 1.58 Å. F1- is bonded in a single-bond geometry to one P+3.50+ atom.
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