Results for “F-O-Se”

Materials Data on SeOF2 by Materials Project

SeOF2 crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four SeOF2 clusters. Se4+ is bonded in a distorted trigonal non-coplanar geometry to one O2- and two F1- atoms. The Se–O bond length is 1.63 Å. There is one shorter (1.77 Å) and one longer (1.79 Å) Se–F bond length. O2- is bonded in a single-bond geometry to one Se4+ atom. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Se4+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Se4+ atom.