Materials Data on RbNdF4 by Materials Project
RbNdF4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 7-coordinate geometry to seven F1- atoms. There are a spread of Rb–F bond distances ranging from 2.75–2.90 Å. Nd3+ is bonded in a 9-coordinate geometry to nine F1- atoms. There are a spread of Nd–F bond distances ranging from 2.31–2.55 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded to two equivalent Rb1+ and two equivalent Nd3+ atoms to form distorted FRb2Nd2 tetrahedra that share corners with ten FRb2Nd2 tetrahedra and an edgeedge with one FRbNd3 tetrahedra. In the second F1- site, F1- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Nd3+ atoms. In the third F1- site, F1- is bonded to one Rb1+ and three equivalent Nd3+ atoms to form FRbNd3 tetrahedra that share corners with eight FRb2Nd2 tetrahedra and edges with three FRbNd3 tetrahedra. In the fourth F1- site, F1- is bonded in a 1-coordinate geometry to four equivalent Rb1+ and one Nd3+ atom.