Materials Data on TlInF6 by Materials Project
TlInF6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Tl3+ is bonded to six equivalent F1- atoms to form TlF6 octahedra that share corners with six equivalent InF6 octahedra. The corner-sharing octahedral tilt angles are 33°. All Tl–F bond lengths are 2.19 Å. In3+ is bonded to six equivalent F1- atoms to form InF6 octahedra that share corners with six equivalent TlF6 octahedra. The corner-sharing octahedral tilt angles are 33°. All In–F bond lengths are 2.11 Å. F1- is bonded in a bent 150 degrees geometry to one Tl3+ and one In3+ atom.
36 MATERIALS SCIENCE↗