Materials Data on EuVO2 by Materials Project
EuVO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Eu2+ is bonded to six equivalent O2- atoms to form edge-sharing EuO6 octahedra. There are four shorter (2.47 Å) and two longer (2.52 Å) Eu–O bond lengths. V2+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All V–O bond lengths are 2.14 Å. O2- is bonded to three equivalent Eu2+ and two equivalent V2+ atoms to form a mixture of distorted edge and corner-sharing OEu3V2 square pyramids.
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