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Materials Data on EuTl3 by Materials Project

EuTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Eu is bonded to twelve equivalent Tl atoms to form EuTl12 cuboctahedra that share corners with twelve equivalent EuTl12 cuboctahedra, edges with twenty-four equivalent TlEu4Tl8 cuboctahedra, faces with six equivalent EuTl12 cuboctahedra, and faces with twelve equivalent TlEu4Tl8 cuboctahedra. All Eu–Tl bond lengths are 3.50 Å. Tl is bonded to four equivalent Eu and eight equivalent Tl atoms to form distorted TlEu4Tl8 cuboctahedra that share corners with twelve equivalent TlEu4Tl8 cuboctahedra, edges with eight equivalent EuTl12 cuboctahedra, edges with sixteen equivalent TlEu4Tl8 cuboctahedra, faces with four equivalent EuTl12 cuboctahedra, and faces with fourteen equivalent TlEu4Tl8 cuboctahedra. All Tl–Tl bond lengths are 3.50 Å.

36 MATERIALS SCIENCE↗

Materials Data on EuTl3 by Materials Project

EuTl3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Eu is bonded to twelve Tl atoms to form a mixture of corner and face-sharing EuTl12 cuboctahedra. There are a spread of Eu–Tl bond distances ranging from 3.44–3.64 Å. There are two inequivalent Tl sites. In the first Tl site, Tl is bonded in a 4-coordinate geometry to four equivalent Eu atoms. In the second Tl site, Tl is bonded in a 4-coordinate geometry to four equivalent Eu atoms.

36 MATERIALS SCIENCE↗