Materials Data on EuMoO5 by Materials Project
EuMoO5 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Eu is bonded in a 8-coordinate geometry to eight O atoms. There are a spread of Eu–O bond distances ranging from 2.31–2.52 Å. Mo is bonded in a distorted tetrahedral geometry to five O atoms. There are a spread of Mo–O bond distances ranging from 1.77–2.41 Å. There are five inequivalent O sites. In the first O site, O is bonded in a distorted trigonal non-coplanar geometry to two equivalent Eu and one Mo atom. In the second O site, O is bonded in a distorted trigonal planar geometry to two equivalent Eu and one Mo atom. In the third O site, O is bonded in a distorted trigonal planar geometry to two equivalent Eu and one Mo atom. In the fourth O site, O is bonded in a distorted linear geometry to one Eu and one Mo atom. In the fifth O site, O is bonded in a distorted bent 150 degrees geometry to one Eu and one Mo atom.