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Materials Data on EuU3 by Materials Project

U3Eu is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. U is bonded to eight equivalent U and four equivalent Eu atoms to form UEu4U8 cuboctahedra that share corners with twelve equivalent UEu4U8 cuboctahedra, edges with eight equivalent EuU12 cuboctahedra, edges with sixteen equivalent UEu4U8 cuboctahedra, faces with four equivalent EuU12 cuboctahedra, and faces with fourteen equivalent UEu4U8 cuboctahedra. All U–U bond lengths are 3.18 Å. All U–Eu bond lengths are 3.18 Å. Eu is bonded to twelve equivalent U atoms to form EuU12 cuboctahedra that share corners with twelve equivalent EuU12 cuboctahedra, edges with twenty-four equivalent UEu4U8 cuboctahedra, faces with six equivalent EuU12 cuboctahedra, and faces with twelve equivalent UEu4U8 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on Eu3U by Materials Project

UEu3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. U is bonded in a distorted body-centered cubic geometry to fourteen Eu atoms. There are eight shorter (3.82 Å) and six longer (4.41 Å) U–Eu bond lengths. There are two inequivalent Eu sites. In the first Eu site, Eu is bonded in a distorted body-centered cubic geometry to four equivalent U and four equivalent Eu atoms. All Eu–Eu bond lengths are 3.82 Å. In the second Eu site, Eu is bonded in a 8-coordinate geometry to six equivalent U and eight equivalent Eu atoms.

36 MATERIALS SCIENCE↗