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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Eu(SiRh)2 by Materials Project

EuRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Eu2+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Eu–Si bond lengths are 3.20 Å. Rh3+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing RhSi4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Eu2+, four equivalent Rh3+, and one Si4- atom. The Si–Si bond length is 2.62 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on EuSi3Rh by Materials Project

EuRhSi3 crystallizes in the tetragonal I4mm space group. The structure is three-dimensional. Eu is bonded in a 4-coordinate geometry to four equivalent Rh and twelve Si atoms. All Eu–Rh bond lengths are 3.36 Å. There are a spread of Eu–Si bond distances ranging from 3.11–3.37 Å. Rh is bonded in a 5-coordinate geometry to four equivalent Eu and five Si atoms. There are four shorter (2.38 Å) and one longer (2.39 Å) Rh–Si bond lengths. There are two inequivalent Si sites. In the first Si site, Si is bonded in a distorted single-bond geometry to four equivalent Eu, one Rh, and four equivalent Si atoms. All Si–Si bond lengths are 2.59 Å. In the second Si site, Si is bonded in a distorted bent 120 degrees geometry to four equivalent Eu, two equivalent Rh, and two equivalent Si atoms.

36 MATERIALS SCIENCE↗