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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on EuNi5 by Materials Project

EuNi5 crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. Eu is bonded in a 6-coordinate geometry to eighteen Ni atoms. There are six shorter (2.89 Å) and twelve longer (3.17 Å) Eu–Ni bond lengths. There are two inequivalent Ni sites. In the first Ni site, Ni is bonded in a 12-coordinate geometry to three equivalent Eu and six equivalent Ni atoms. All Ni–Ni bond lengths are 2.42 Å. In the second Ni site, Ni is bonded to four equivalent Eu and eight Ni atoms to form a mixture of corner, edge, and face-sharing NiEu4Ni8 cuboctahedra. All Ni–Ni bond lengths are 2.50 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on EuNi3 by Materials Project

EuNi3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Eu is bonded to twelve equivalent Ni atoms to form EuNi12 cuboctahedra that share corners with twelve equivalent EuNi12 cuboctahedra, edges with twenty-four equivalent NiEu4Ni8 cuboctahedra, faces with six equivalent EuNi12 cuboctahedra, and faces with twelve equivalent NiEu4Ni8 cuboctahedra. All Eu–Ni bond lengths are 2.75 Å. Ni is bonded to four equivalent Eu and eight equivalent Ni atoms to form distorted NiEu4Ni8 cuboctahedra that share corners with twelve equivalent NiEu4Ni8 cuboctahedra, edges with eight equivalent EuNi12 cuboctahedra, edges with sixteen equivalent NiEu4Ni8 cuboctahedra, faces with four equivalent EuNi12 cuboctahedra, and faces with fourteen equivalent NiEu4Ni8 cuboctahedra. All Ni–Ni bond lengths are 2.75 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Eu2Ni17 by Materials Project

Eu2Ni17 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Eu sites. In the first Eu site, Eu is bonded in a 12-coordinate geometry to eighteen Ni atoms. There are a spread of Eu–Ni bond distances ranging from 2.95–3.24 Å. In the second Eu site, Eu is bonded in a 8-coordinate geometry to twenty Ni atoms. There are a spread of Eu–Ni bond distances ranging from 2.90–3.16 Å. There are eight inequivalent Ni sites. In the first Ni site, Ni is bonded in a 2-coordinate geometry to one Eu and thirteen Ni atoms. There are a spread of Ni–Ni bond distances ranging from 2.35–2.72 Å. In the second Ni site, Ni is bonded to two equivalent Eu and ten Ni atoms to form NiEu2Ni10 cuboctahedra that share corners with fourteen NiEu2Ni10 cuboctahedra, edges with six NiEu3Ni9 cuboctahedra, and faces with ten NiEu2Ni10 cuboctahedra. There are four shorter (2.40 Å) and four longer (2.41 Å) Ni–Ni bond lengths. In the third Ni site, Ni is bonded to two equivalent Eu and ten Ni atoms to form NiEu2Ni10 cuboctahedra that share corners with fourteen NiEu2Ni10 cuboctahedra, edges with six NiEu3Ni9 cuboctahedra, and faces with ten NiEu2Ni10 cuboctahedra. All Ni–Ni bond lengths are 2.40 Å. In the fourth Ni site, Ni is bonded in a 12-coordinate geometry to two Eu and ten Ni atoms. There are a spread of Ni–Ni bond distances ranging from 2.40–2.60 Å. In the fifth Ni site, Ni is bonded in a 12-coordinate geometry to two Eu and ten Ni atoms. There are a spread of Ni–Ni bond distances ranging from 2.41–2.60 Å. In the sixth Ni site, Ni is bonded in a 12-coordinate geometry to two Eu and ten Ni atoms. There are two shorter (2.48 Å) and two longer (2.60 Å) Ni–Ni bond lengths. In the seventh Ni site, Ni is bonded to three Eu and nine Ni atoms to form a mixture of edge, face, and corner-sharing NiEu3Ni9 cuboctahedra. There are one shorter (2.43 Å) and one longer (2.44 Å) Ni–Ni bond lengths. In the eighth Ni site, Ni is bonded to three Eu and nine Ni atoms to form a mixture of edge, face, and corner-sharing NiEu3Ni9 cuboctahedra.

36 MATERIALS SCIENCE↗