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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Eu(NO3)3 by Materials Project

Eu(NO3)3 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Eu(NO3)3 sheet oriented in the (0, 0, 1) direction. Eu3+ is bonded in a 10-coordinate geometry to ten O2- atoms. There are a spread of Eu–O bond distances ranging from 2.46–2.67 Å. There are three inequivalent N5+ sites. In the first N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.25–1.28 Å. In the second N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.26 Å) and one longer (1.27 Å) N–O bond length. In the third N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.25 Å) and one longer (1.30 Å) N–O bond length. There are nine inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Eu3+ and one N5+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Eu3+ and one N5+ atom. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom. In the fifth O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom. In the sixth O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom. In the seventh O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom. In the eighth O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom. In the ninth O2- site, O2- is bonded in a distorted single-bond geometry to one Eu3+ and one N5+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on EuN3O14 by Materials Project

EuN3O14 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of two EuN3O14 ribbons oriented in the (1, 0, 0) direction. Eu is bonded in a 7-coordinate geometry to nine O atoms. There are a spread of Eu–O bond distances ranging from 2.46–3.18 Å. There are three inequivalent N sites. In the first N site, N is bonded in a trigonal planar geometry to three O atoms. There is one shorter (1.22 Å) and two longer (1.29 Å) N–O bond length. In the second N site, N is bonded in a trigonal planar geometry to three O atoms. There is one shorter (1.22 Å) and two longer (1.29 Å) N–O bond length. In the third N site, N is bonded in a trigonal planar geometry to three O atoms. There are a spread of N–O bond distances ranging from 1.22–1.30 Å. There are fourteen inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one O atom. The O–O bond length is 1.28 Å. In the second O site, O is bonded in a bent 120 degrees geometry to two O atoms. The O–O bond length is 1.29 Å. In the third O site, O is bonded in a distorted L-shaped geometry to one Eu and one N atom. In the fourth O site, O is bonded in a distorted L-shaped geometry to one Eu and one N atom. In the fifth O site, O is bonded in a single-bond geometry to one N atom. In the sixth O site, O is bonded in a distorted water-like geometry to one Eu and one N atom. In the seventh O site, O is bonded in a distorted L-shaped geometry to one Eu and one N atom. In the eighth O site, O is bonded in a single-bond geometry to one N atom. In the ninth O site, O is bonded in a distorted L-shaped geometry to one Eu and one N atom. In the tenth O site, O is bonded in a distorted L-shaped geometry to one Eu and one N atom. In the eleventh O site, O is bonded in a single-bond geometry to one N atom. In the twelfth O site, O is bonded in a bent 120 degrees geometry to one Eu and one O atom. The O–O bond length is 1.24 Å. In the thirteenth O site, O is bonded in a bent 150 degrees geometry to one Eu and one O atom. In the fourteenth O site, O is bonded in a distorted bent 120 degrees geometry to one Eu and one O atom.

36 MATERIALS SCIENCE↗