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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on RbEu3F10 by Materials Project

RbEu3F10 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to sixteen F1- atoms to form distorted edge-sharing RbF16 tetrahedra. There are four shorter (2.89 Å) and twelve longer (3.33 Å) Rb–F bond lengths. Eu3+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are four shorter (2.30 Å) and four longer (2.44 Å) Eu–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded to one Rb1+ and three equivalent Eu3+ atoms to form a mixture of distorted edge and corner-sharing FRbEu3 tetrahedra. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Rb1+ and two equivalent Eu3+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Rb2EuF5 by Materials Project

Rb2EuF5 crystallizes in the orthorhombic Pna2_1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.84–3.11 Å. In the second Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.86–3.20 Å. Eu3+ is bonded to seven F1- atoms to form distorted edge-sharing EuF7 pentagonal bipyramids. There are a spread of Eu–F bond distances ranging from 2.26–2.45 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+ and two equivalent Eu3+ atoms. In the second F1- site, F1- is bonded in a 5-coordinate geometry to four Rb1+ and one Eu3+ atom. In the third F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+ and two equivalent Eu3+ atoms. In the fourth F1- site, F1- is bonded in a 5-coordinate geometry to four Rb1+ and one Eu3+ atom. In the fifth F1- site, F1- is bonded in a 1-coordinate geometry to four Rb1+ and one Eu3+ atom.

36 MATERIALS SCIENCE↗