Results for “Eu(FeP3)4”

Materials Data on Eu(FeP3)4 by Materials Project

EuFe4P12 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Eu2+ is bonded to twelve equivalent P1- atoms to form EuP12 cuboctahedra that share faces with eight equivalent FeP6 octahedra. All Eu–P bond lengths are 3.00 Å. Fe+2.50+ is bonded to six equivalent P1- atoms to form FeP6 octahedra that share corners with six equivalent FeP6 octahedra and faces with two equivalent EuP12 cuboctahedra. The corner-sharing octahedral tilt angles are 60°. All Fe–P bond lengths are 2.25 Å. P1- is bonded in a distorted bent 120 degrees geometry to one Eu2+, two equivalent Fe+2.50+, and two equivalent P1- atoms. There are one shorter (2.29 Å) and one longer (2.35 Å) P–P bond lengths.