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Anisotropic magnetism of polymorphic ErAl 3

ErAl 3 can form in either a trigonal (α) or cubic (β) polymorph and this paper investigates the physical properties of these polymorphs through characterizations of single crystals grown in an aluminum flux. Here, we demonstrate that polymorph selection can be achieved based on the nominal composition of the crystal growth. Magnetic measurements confirm that both β-ErAl 3 and α-ErAl 3 order antiferromagnetically at low temperatures. β-ErAl 3 undergoes antiferromagnetic ordering at a Néel temperature T N = 5.1 K, and the transition is suppressed continually with applied field. α-ErAl 3 displays more complex behavior, with successive magnetic transitions at T N = 5.7 K and T 2 = 4.6 K for zero field, where heat capacity and dilatometry measurements evidence that these transitions are second and first order, respectively. Under magnetic field, strong anisotropy is revealed in α-ErAl 3 , with several steplike metamagnetic transitions observed below T 2 for H ∥ c. These transitions produce sequential magnetization plateaus near one-half of the apparent saturation magnetization. The electrical resistivity of α-ErAl 3 is strongly coupled to its magnetism. At T = 2 K, we observe a positive magnetoresistance reaching 60%, with distinct anomalies at the metamagnetic transitions. The results are summarized in H-T phase diagrams that demonstrate complex magnetic behavior for α-ErAl 3 , suggesting an important role of competing interactions in this metallic system that possesses characteristics of Ising physics.

36 MATERIALS SCIENCE↗

Materials Data on ErAl by Materials Project

ErAl crystallizes in the orthorhombic Pbcm space group. The structure is three-dimensional. there are two inequivalent Er sites. In the first Er site, Er is bonded in a 2-coordinate geometry to eight Al atoms. There are a spread of Er–Al bond distances ranging from 3.06–3.37 Å. In the second Er site, Er is bonded in a 6-coordinate geometry to eight Al atoms. There are a spread of Er–Al bond distances ranging from 3.03–3.54 Å. There are two inequivalent Al sites. In the first Al site, Al is bonded to eight Er and four Al atoms to form a mixture of distorted edge, corner, and face-sharing AlEr8Al4 cuboctahedra. There are two shorter (2.73 Å) and two longer (2.79 Å) Al–Al bond lengths. In the second Al site, Al is bonded in a 10-coordinate geometry to eight Er and two equivalent Al atoms.

36 MATERIALS SCIENCE↗

Next Generation Thermal Protection System for Outer Planet Probes and Orbiter

Saturn Probe and Ice Giant Orbiter along with in-situ Probe Missions continue to be very high priority mis-sions. A result of the advocacy by OPAG and other Analysis Groups, the 3D Woven, Dual-Layer HEEET thermal protection system, mature at TRL 6, has closed the TPS gap for extreme environment missions. A mid density follow on to DL HEEET, developed to meet earth entry requirements, is a Single Layer vari-ant of the 3D woven TPS, which provides a mass effi-cient single layer 3D Mid-Density TPS (3MDCP) that has been baselined as the heatshield for MSR EEV. Continued development of 3MDCP will elevate it to TRL 6 by 2025. Conformal-PICA (C-PICA) devel-opment was pursued to establish a more efficient and robust alternate to PICA, and it is at TRL 4+. Our rationale for the next generation of TPS de-velopment is based on the on the missions needs of the next decade Outer Planet missions that are unique and more demanding than any other destinations. Taking advantage of the recent planned development of sev-eral materials, the next generation of TPS offers a much more mass efficient option for small, medium, and large class Outer Planet missions. Saturn Probes: While mission designers are gen-erally interested in shallow entry to maintain the g-load during entry around 50g, the heat-load for shallow entry can range between (100 kJ/cm2 – 300 kJ/cm2), two orders of magnitude higher than Venus or Sample Return missions. TPS must not only offer protection but must be mass efficient to perform reasonable sci-ence. TPS mass can quickly become 50% or more of the mass of the entire entry system. Recent analysis performed shows Saturn Probe missions could signifi-cantly benefit from the single layer HEEET (SL-HEEET/3MDCP). A DL-HEEET based heatshield mass could be ~ (40% -50%), SL-HEEET can provide additional (30% - 50%) mass savings. At the same time, C-PICA can provide (30% - 50%) mass savings on the backshell. The combined mass savings can be significant enough to carry an additional probe, if de-sired. Ice Giant Aerocapture Missions: Aerocapture mission architectures can provide significant ad-vantage over traditional propulsive insertion missions in multiple ways. 1) Reduced trip time ~ (4- 6) years (30% -40%), 2) Enables placing the orbiter, probe, and lander, all together and 3) Allows for greater science mass (probes and landers) due to mass efficiency. The delivery of a probe from orbit makes it easier and eliminates mission design constraints by HEEET for direct entry [4] of probes and allows for more targeted in-situ science once the Orbiter is able to collect data. In the past 20 years, progress made in GN&C for lift-guided entry missions (MSL, Orion EFT1, Mars 2020) and the expertise in blunt body aerodynamics at large scale (~ 5m) has led the EDL community to conclude that aerocapture is a “go do” engineering activity. An aerocapture mission that will deplete the excess energy of a fast arrival mission will require a mass efficient TPS that can handle extreme heat-load, ~ (100 kJ/cm2 – 500 kJ/cm2). Hence TPS, feasibility as well as mass efficiency requires assessment. Utilizing the recent developments, a comprehensive, bounding analysis was done to establish the potential for SOA (HEEET) system as well as emerging new TPS such as SL-HEEET and C-PICA. In this proposed poster, we will outline the process by which we establish bounding aerocapture trajecto-ries for hyperbolic excess velocities ranging from 27 km/s to 35 km/s, for low L/D (~ 0.4) configurations and determine conservative/bounding estimate of aer-othermal environment by using a combination of CFD simulations and stagnation point heating estimates [7]. This engineering approach allows us to assess the TPS need vs. TPS capability and determine the applicability of existing TPS. Once an applicable suite of TPS is determined, the TPS thickness and mass are comput-ed. We show that the TPS mass fraction can be as low as 5% to as high as 20%, depending on the use of ad-vanced TPS, while HEEET is sufficient but will require 50% of the entry mass.

E Venkatapathy↗

Data-driven Modeling for Grid Edge IBRs: A Digital Twin Perspective of User-Defined Models

Recent events in Odessa have brought attention to the challenges associated with the interaction between Inverter- Based Resources (IBRs) and the transmission and distribution system. The NERC event diagnosis report has highlighted sev- eral issues, emphasizing the need for continuous performance monitoring of these IBRs by system operators. Key areas of concern include the mismatch of control and protection perfor- mance of IBRs between the original equipment manufacturer (OEM)-provided models and field measurements. The inability to replicate the realistic response can result in incorrect reliability and resilience studies. In this paper, we developed an approach on how to emulate the behavior of an IBR using measurement data obtained for system operators to utilize in real-time and long- term planning. Two experiments are conducted in the phasor domain and electromagnetic transients (EMT) domain to emulate the behavior for grid forming and grid following inverters under various operating conditions and the effectiveness of the proposed model is demonstrated in terms of accuracy and ease of utilizing user-defined models (UDMs)

Mahapatra, Kaveri [BATTELLE (PACIFIC NW LAB)]↗

Escalation: How Much is Enough?

Determining the escalation percentage to an estimate is often the subject of fierce debate. Cost increases are determined by dynamic relati onships between many factors, including acts of nature, interest rate s, oil prices, global commodity markets, wars, wage rates, and the ov erall health of the economy, as well as supply and demand for the required goods or services. How much escalation is enough? Are the recen t price increases temporary aberrations, or will they continue to pla gue us? This paper examines historical escalation rates, as well as i ndications of trends. Various analysis methods -- Monte Carlo simulations, neural networks, trend impact analysis, and the Delphi method -- are examined in an attempt to determine future trends.

Butts, Glenn↗

Implementing the Mars Science Laboratory Terminal Descent Sensor Field Test Campaign

The Mars Science Laboratory (MSL) will deliver a 900 kg rover to the surface of Mars in August 2012. MSL will utilize a new pulse-Doppler landing radar, the Terminal Descent Sensor (TDS). The TDS employs six narrow-beam antennas to provide unprecedented slant range and velocity performance at Mars to enable soft touchdown of the MSL rover using a unique sky crane Entry, De-scent, and Landing (EDL) technique. Prior to use on MSL, the TDS was put through a rigorous verification and validation (V&V) process. A key element of this V&V was operating the TDS over a series of field tests, using flight-like profiles expected during the descent and landing of MSL over Mars-like terrain on Earth. Limits of TDS performance were characterized with additional testing meant to stress operational modes outside of the expected EDL flight profiles. The flight envelope over which the TDS must operate on Mars encompasses such a large range of altitudes and velocities that a variety of venues were neces-sary to cover the test space. These venues included an F/A-18 high performance aircraft, a Eurocopter AS350 AStar helicopter and 100-meter tall Echo Towers at the China Lake Naval Air Warfare Center. Testing was carried out over a five year period from July 2006 to June 2011. TDS performance was shown, in gen-eral, to be excellent over all venues. This paper describes the planning, design, and implementation of the field test campaign plus results and lessons learned.

Mars Science Laboratory (MSL)↗

The Lunar Atmosphere and Dust Environment Explorer (LADEE): Initial Science Results

On September 6, 2013, a near-perfect launch of the first Minotaur V rocket successfully carried NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE) into a high-eccentricity geocentric orbit. LADEE arrived at the Moon on October 6, 2013, dur-ing the government shutdown. The spacecraft impact-ed the lunar surface on April 18, 2014, following a completely successful mission. LADEE's science objectives were twofold: (1) De-termine the composition and variability of the lunar atmosphere; (2) Characterize the lunar exospheric dust environment, and its variability. The LADEE science payload consisted of the Lunar Dust Experiment (LDEX), which sensed dust impacts in situ, for parti-cles between 100 nm and 5 micrometers; a neutral mass spectrometer (NMS), which sampled lunar exo-spheric gases in situ, over the 2-150 Dalton mass range; an ultraviolet/visible spectrometer (UVS) ac-quired spectra of atmospheric emissions and scattered light from tenuous dust, spanning a 250-800 nm wave-length range. UVS also performed dust extinction measurements via a separate solar viewer optic. The following are preliminary results for the lunar exosphere: (1) The helium exosphere of the Moon, first observed during Apollo, is clearly dominated by the delivery of solar wind He++. (2) Neon 20 is clearly seen as an important constituent of the exosphere. (3) Argon 40, also observed during Apollo and arising from interior outgassing, exhibits variations related to surface temperature-driven condensation and release, and is also enhanced over specific selenographic longi-tudes. (4) The sodium abundance varies with both lu-nar phase and with meteoroid influx, implicating both solar wind sputtering and impact vaporization process-es. (5) Potassium was also routinely monitored and exhibits some of the same properties as sodium. (6) Other candidate species were seen by both NMS and UVS, and await confirmation. Dust measurements have revealed a persistent "shroud" of small dust particles between 0.7 and sev-eral micrometers in size, present over the pre-dawn and morning sector of the Moon. This tenuous dust exosphere, with densities of approximately 10(exp -5) m(exp -3), appears to be sustained by the ejecta of micrometeoroid impacts.

lunar atmosphere↗

Clast Selection and Metallographic Cooling Rates: Initial Results on Type 1A and 2A Mesosiderites

We initiated a comprehensive study on selected clasts and metal of mesosiderites using SEM, electron microprobe and the complete suite of noble gases. Here we report initial results on the petrography of selected clasts and metallographic cooling rates using the central Ni method used in sev-eral publications. We focus on the approach of selecting grains in least recrystallized mesosiderites. Hence, especially (lithic) clasts in type 1A, 1B, 2A and 2B are the first choice. They provide highest primitive-ness and least annealing/metamorphism. All grains selected should be in close proximity to each other. Lithic clasts in mesosiderites are of high interest be-cause of their igneous texture and similarity to eucrites and howardite petrography. We find pyrox-enes (px) and plagioclase (plag) attached to each other which implies a common formation history. It will be interesting to see differences and similarities in their noble gas inventory (CRE ages, trapped components and closure temperature). In addition, we will investi-gate variations of the lithic clasts toward similar grains in the thick sections which are not igneous. Plag grains are the best bases for noble gas measurements con-cerning He to Ar and Ar-Ar dating since it delivers im-portant target elements. We focus on plag grains in close contact to olivine (olv) / px grains to assess weth-er both grains show noble gas patterns being similar or different. Phosphate grains are suitable for Kr and Xe measurements since they yield REE abundances (tar-get elements).

Mesosiderites↗

Enabling International Data Relay at Mars

The most commonly used mode of communications be-tween Earth and a Mars surface mission is ultra-high fre-quency (UHF) radio relay via a Mars orbiter. There are four orbiters and two surface rovers operating at Mars and by October there should be five orbiters and three landers or rovers. There has been some collaboration between ESA’s Mars Express orbiter and NASA’s rovers, but 2016 is when Mars relay becomes fully international. In October, ESA will deliver the ExoMars Trace Gas Orbiter (TGO) and En-try, Descent, and Landing (EDL) Demonstrator Module (EDM) lander to Mars. The ExoMars program includes both ESA and ROSCOSMOS, with NASA participation (the Electra UHF transceiver on TGO). NASA orbiters will pro-vide relay for EDM and future ESA Mars landers and rov-ers. TGO will provide relay for NASA's current and future surface assets (as Mars Express will continue to do). Inter-national collaboration is enabled in several steps. At the in-struction of the space agencies, the Mars mission projects negotiate and write a “Service Agreement.” This describes at a high level how a new Mars orbiter would operate with its corresponding surface missions or how a new surface mis-sion would operate with its corresponding orbiters. It in-cludes the roles of the different projects, how the new mis-sion would communicate with existing or planned missions, the general flow of data and commands, and the capabilities or requirements of the new mission. After completing the Service Agreement, the projects write Interface Control Doc-uments (ICDs), each of which describes data and command flow in greater detail and quantitative aspects of the relay link and operations timeline between an orbiter and a cor-responding lander/rover. Interfaces and operations are test-ed before a new mission arrives at Mars. Once at Mars, a new orbiter performs some “practice” relay contacts with its partners. For a new lander (e.g. EDM), relay operations gen-erally begin before atmospheric entry at Mars, with record-ing of the UHF relay signal from the lander (including open-loop wide-bandwidth recording) as it enters and traverses Mars’s atmosphere and lands on its surface. After Mars EDL or orbit injection, each relay contact is negotiat-ed and scheduled using the Mars Relay Operations Service (MaROS). This paper describes the international approach to develop inter-agency agreements, inter-project interfaces, and specifics of how MaROS is used in actual relay opera-tions between international partners.

Winton, Alistair J.↗

Deep nonparametric estimation of operators between infinite dimensional spaces

Learning operators between infinitely dimensional spaces is an important learning task arising in machine learning, imaging science, mathematical modeling and simulations, etc. This paper studies the nonparametric estimation of Lipschitz operators using deep neural networks. Non-asymptotic upper bounds are derived for the generalization error of the empirical risk minimizer over a properly chosen network class. Under the assumption that the target operator exhibits a low dimensional structure, our error bounds decay as the training sample size increases, with an attractive fast rate depending on the intrinsic dimension in our estimation. Our assumptions cover most scenarios in real applications and our results give rise to fast rates by exploiting low dimensional structures of data in operator estimation. We also investigate the influence of network structures (e.g., network width, depth, and sparsity) on the generalization error of the neural network estimator and propose a general suggestion on the choice of network structures to maximize the learning efficiency quantitatively.

97 MATHEMATICS AND COMPUTING↗