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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Aqueous solution of [EMIM][OAc]: Property formulations for use in air conditioning equipment design

Liquid desiccant air conditioning (LDAC) is a promising alternative to vapor compression refrigeration based space cooling and dehumidification for the reduction of energy consumption and the improvement of indoor air quality. However, its use in the air conditioning market is still very limited due to its high installation cost, intensive carryover, and high cost of operation and maintenance associated to the corrosion of the current desiccant liquids. Substitutes for the traditional desiccant liquids with better properties and no corrosion are highly needed. Ionic liquids, which are salts comprised of organic cations and inorganic anions or organic anions, have high thermal stability, negligible or no vapor pressure, varied solubility in water, low or no corrosion to metals, and low driving temperatures to achieve dew point temperatures. All of those characteristics make them as perfect substitutes for traditional desiccant liquids. Up to date, a very few research groups investigated ILs as potential alternatives to traditional desiccant liquids for LDAC. The study aimed to identify the ionic liquids as ideal desiccant liquids to achieve better cost-effectiveness and higher system performance of LDAC. There were 13 different ionic liquids (IL) identified and screened for the most promising candidate. 1-Ethyl-3-methylimidazolium acetate, [EMIM][OAc], was selected as an ideal candidate for the capable of the most adsorption and desorption. The study was mainly focused on the development of calculation models for the thermo-physical properties of the aqueous solution of [EMIM][OAc] to represent the property data needed for use as the desiccant liquid in sorption-based air conditioning equipment. It aims to provide convenient methods for use in the design and model of the sorption-based air conditioning. Finally, the calculation models for the following thermo-physical properties of the aqueous solution of [EMIM][OAc] were proposed and presented in the study: the vapor pressures, specific heat capacity, density, and dynamic viscosity at various temperatures and concentrations.

1-Ethyl-3-methylimidazolium acetate↗
DOE OSTI2020

Analysis of Space-Conditioning Loads in Commercial Buildings

Space conditioning end-uses, which include heating, cooling, and ventilation, represent a significant fraction of commercial building energy use, with a wide variety of heating and cooling technology options available in the market. In the interest of improving the overall efficiency of heating, ventilation and air-conditioning (HVAC) technologies, governments, utilities and private sector entities have implemented a variety of market transformation policies that aim to influence consumer purchase decisions. To evaluate the costs and benefits of such programs, analysts typically postulate a hypothetical default equipment choice, and compare it to one that provides comparable service with lower energy and/or power use. The corresponding reduced operating cost provides a benefit that offsets the potential higher cost of improved efficiency. Typically, life-cycle cost or cash-flow analyses are used to quantify the net economic benefit. These analyses require the capability to assess how a given equipment design would perform across a broad range of characteristics, both of the building and of the local weather. While these assessments can be performed using customized building simulations, it is generally not practical to develop and validate detailed building simulation code to cover all the potential variations of equipment design and installation. An alternative, and somewhat simpler, approach is to solely use detailed building simulations to generate time series of heating and cooling loads in commercial buildings. These loads can then be used as input to more detailed, stand-alone engineering models that simulate HVAC system performance under different equipment designs. This approach was used to evaluate a range of high-efficiency commercial packaged air conditioner design options for the Department of Energy’s Appliance and Equipment Standards Program (DOE-EERE 2015). While there may be some loss of precision relative to full simulation, the accuracy of this approach is sufficient for practical applications of cost-benefit analysis. This report describes the development of a database of commercial building heating and cooling loads, generated using the EnergyPlus software package, a whole building energy use model supported by the Department of Energy (DOE-EERE 2020a). EnergyPlus takes as input a set of configuration files that describe the building itself (size, zoning, envelope characteristics, etc.) and the various systems within it (HVAC, lighting, water heating, etc.). This analysis uses a publicly available collection of commercial reference buildings (CRB), comprised of sixteen building types and three vintages (DOE-EERE 2020b; Deru et al 2011). Each building is simulated in eighteen different locations, covering a wide range of climatic conditions. The prototype building description files assign the type of HVAC equipment used, and capacities across climate zones.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Mitigation for Removal of Building 01-103 in the Area 1 Subdock, Nevada National Security Site, Nye County, Nevada

Building 01-103, the Drill Bit Repair Building was originally recorded as SHPO Resource No. B18848 in 2020 during an architectural survey of the Area 1 Subdock (Collins et al. 2022). It was recommended individually eligible for listing in the NRHP under Criteria A and C and contributing to the significance of the Area 1 Subdock Historic District. The SHPO concurred with these determinations in a letter dated April 29, 2022 (Reed 2022). The Drill Bit Repair Building retains all seven aspects of integrity. The location, materials, workmanship, feeling, and association have not changed since its original construction. The design was modified slightly in 1996 with the addition of a removable and non-destructive chain-link fence. Nearby buildings 01-101 and 01-102 were removed (Collins and Menocal 2020) but the other buildings and storage yards remain. Therefore, the integrity of setting has been changed, but not to the degree that the building no longer conveys its significance (see Figures 4 and 5 for comparison). Building 01-103 was constructed in 1985 to coincide with the relocation of the Area 3 Subdock to Area 1. The design for the new Subdock provided a centralized cluster of buildings surrounded by two large storage yards. The buildings included administrative and engineering office space, warehouses, a radiograph building, and Building 01-103 as the drill bit maintenance and repair building, among others. The Drill Bit Repair Building was critical to the success of underground nuclear testing and is eligible under Criterion A for its contribution to broad patterns of history by maintaining specially designed equipment for underground nuclear testing at the NNSS. It is also eligible under Criterion C as it is the only recorded example of a facility built specifically for the maintenance of big-hole drill bits on the NNSS. As it retains both significance and integrity, it remains individually eligible under Criteria A and C. In addition to its individual significance, the Drill Bit Repair Building also contributes to the significance of the Area 1 Subdock Historic District as a representative of a big-hole drilling support facility necessary for underground nuclear testing. The building and the equipment therein were designed specifically for testing at the NNSS, where much of the early technology and methods for big-hole drilling were developed. Its removal will result in not only the demolition of a contributing element but also a change in the physical features of the district’s setting that contribute to its historic significance. The change in setting will diminish the district’s integrity. However, the district still contains numerous examples of other buildings constructed for the purpose of supporting big-hole drilling and remains eligible under Criteria A and C.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Key factors in designing a robust biorefinery feedstock preprocessing system

One essential prerequisite for achieving design throughput and product conversion yield of cellulosic biofuel in commercial operation is a robust biomass feedstock preprocessing system. Such a system will reliably and steadily supply consistent quality feedstock to the conversion reactor. Pioneer cellulosic biofuel plants have encountered many feedstock handling challenges which lead to lengthy startup and difficulties in meeting plant nameplate production rate. Most of the biomass material handling challenges are caused by: (1) variability in biomass properties especially for herbaceous materials such as corn stover, (2) inadequate integrated testing of equipment, (3) not using the appropriate equipment or equipment design for the job, (4) mismatching of equipment capacity and turn down ratio, (5) lack of integrated control for the whole feedstock preprocessing system, and (6) inadequate surge capacity. This presentation will discuss the feedstock preprocessing challenges, identify key areas from equipment design and operation to process integration requiring optimization or further development to achieve robust integrated biomass feedstock preprocessing systems.

09 BIOMASS FUELS↗
DOE OSTI2021

Seismic isolation: A pathway to standardized advanced nuclear reactors

Standardizing advanced nuclear reactors is a pathway to substantially reducing their overnight capital cost and achieving parity with other power sources, including renewables and fossil fuels. The seismic load case has thwarted standardization of nuclear power plants because site-specific seismic hazard and local near-surface geology has triggered soil-structure-interaction analysis, design, equipment qualification, regulatory review, and licensing, ensuring that each build is different. To achieve standardized or site-independent certified advanced reactor designs, the impact of the seismic load case on the engineering and construction cost and time must be substantially mitigated. Seismic isolation is a mature technology that has been used for more than 30 years in non-nuclear sectors to substantially reduce earthquake demands in buildings and other infrastructure. In this paper, seismic isolation is used to enable standardization of advanced reactor designs, aimed at the complete re-use of a site-independent, certified design and repeated procurement of safety-class equipment. A pathway to standardized designs using seismic isolation is demonstrated for two fundamentally different advanced reactors: a molten salt reactor and a high temperature gas reactor. Each reactor building is equipped with three specialized pieces of safety-class equipment, namely, a reactor vessel, a steam generator, and a control rod drive mechanism housing that is attached to the reactor head. Analysis is performed per ASCE and ASME standards to design the buildings and the equipment for two base conditions: conventional (fixed base) and base isolated. The impact of the seismic load case is characterized for the reinforced concrete walls in the buildings and for the equipment, measured using vessel wall thickness and horizontal accelerations. Here the analysis results show that the fixed-base buildings, designed for a site of low seismic hazard (peak ground acceleration, PGA = 0.15 g) could be constructed at a site of much greater seismic hazard (PGA = 0.7 g) if seismic base isolation is employed. Importantly, the scope of the site-specific analysis, design, and qualification would be limited to the seismic isolators and the isolated substructure, drastically reducing plant-specific engineering, review, and licensing, and time to construction start. Regulatory challenges and opportunities with standardized reactor designs are identified.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2021

Design Considerations for the Field Use of International Nuclear Safeguards Technology

The process of developing and deploying safeguards technology should be carried out in such a way that it supports the International Atomic Energy Agency’s (IAEA’s) international safeguards verification mission, while also being efficient in terms of both cost and time. This process, however, may be hindered by a general lack of nuclear facility operating experience among the scientists or engineers designing safeguards technology, or the inability to interact with the IAEA inspector end user. As a result, equipment designers may have difficulty understanding inspector needs and the limitations of using safeguards technology in the field, often leading to inefficiencies (in the form of increased cost and time spent) in the safeguards technology design process. Here, to mitigate this knowledge gap, the Y-12 National Security Complex in Oak Ridge, Tennessee, has developed design considerations that should be incorporated into safeguards technologies, focusing on non-destructive assay equipment. Timelines for integration of these considerations into the design process are also discussed.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2019

Fracture Mechanics Analysis of Isotope Fuel Impact Tester, Milli-Watt, Multi-Hundred Watt and GPHS Outer Catch-Tube Subassembly Design

The Isotope Fuel Impact Tester (IFIT) at PF-4 is a specialized set of equipment designed for simulating high-speed impact of experimental parts. The IFIT is an inert gas launcher designed to impact 238 PuO 2 heat source assemblies, fuel encapsulation materials, structural materials, and subassemblies of radioisotope thermoelectric generators (RTGs). TA-55 management desires to re-use outer catch tube (OCT) of the milli-watt (MW), multi-hundred watt (MHW) and general purpose heat source (GPHS) designs and thus requires a technical evaluation of potential life cycles to failure. This report provides a fitness-for-service (FFS) assessment using fracture mechanics techniques based on the state-of-stress developed with the aid of a computational finite element model (FEM) of the IFIT. Importantly, the report describes the different material options for the OCT; H-11 vacuum-arc re-melted (VAR) and H-13 VAR for a given heat treatment resulting in a Rockwell-C hardness of 42, and an additional option of 4340 alloy steel with a range of heat treatment resulting in Rockwell-C hardness of 40 to 44.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

Feasibilities of a Coal-Biomass to Liquids Plant in Southern West Virginia

This project has generated comprehensive and realistic results of feasibilities for a coal-biomass to liquids (CBTL) plant in southern West Virginia; and evaluated the sensitivity of the analyses to various anticipated scenarios and parametric uncertainties. Specifically the project has addressed economic feasibility, technical feasibility, market feasibility, and financial feasibility. In the economic feasibility study, a multi-objective siting model was developed and was then used to identify and rank the suitable facility sites. Spatial models were also developed to assess the biomass and coal feedstock availabilities and economics. Environmental impact analysis was conducted mainly to assess life cycle analysis and greenhouse gas emission. Uncertainty and sensitivity analysis were also investigated in this study. Sensitivity analyses on required selling price (RSP) and greenhouse gas (GHG) emissions of CBTL fuels were conducted according to feedstock availability and price, biomass to coal mix ratio, conversion rate, internal rate of return (IRR), capital cost, operational and maintenance cost. The study of siting and capacity showed that feedstock mixed ratio limited the CBTL production. The price of coal had a more dominant effect on RSP than that of biomass. Different mix ratios in the feedstock and conversion rates led to RSP ranging from $104.3 - $157.9/bbl. LCA results indicated that GHG emissions ranged from 80.62 kg CO 2 eq to 101.46 kg CO2 eq/1,000 MJ of liquid fuel at various biomass to coal mix ratios and conversion rates if carbon capture and storage (CCS) was applied. Most of water and fossil energy were consumed in conversion process. Compared to petroleum-derived-liquid fuels, the reduction in GHG emissions could be between -2.7% and 16.2% with CBTL substitution. As for the technical study, three approaches of coal and biomass to liquids, direct, indirect and hybrid, were considered in the analysis. The process models including conceptual design, process modeling and process validation were developed and validated for different cases. Equipment design and capital costs were investigated on capital coast estimation and economical model validation. Material and energy balances and techno-economic analysis on base case were conducted for evaluation of projects. Also, sensitives studies of direct and indirect approaches were both used to evaluate the CBTL plant economic performance. In this study, techno-economic analysis were conducted in Aspen Process Economic Analyzer (APEA) environment for indirect, direct, and hybrid CBTL plants with CCS based on high fidelity process models developed in Aspen Plus and Excel. The process thermal efficiency ranges from 45% to 67%. The break-even oil price ranges from $86.1 to $100.6 per barrel for small scale (10000 bbl/day) CBTL plants and from $65.3 to $80.5 per barrel for large scale (50000 bbl/day) CBTL plants. Increasing biomass/coal ratio from 8/92 to 20/80 would increase the break-even oil price of indirect CBTL plant by $3/bbl and decrease the break-even oil price of direct CBTL plant by about $1/bbl. The order of carbon capture penalty is direct > indirect > hybrid. The order of capital investment is hybrid (with or without shale gas utilization) > direct (without shale gas utilization) > indirect > direct (with shale gas utilization). The order of thermal efficiency is direct > hybrid > indirect. The order of break-even oil price is hybrid (without shale gas utilization) > direct (without shale gas utilization) > hybrid (with shale gas utilization) > indirect > direct (with shale gas utilization).

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2024

Improved biomass feedstock materials handling and feeding engineering data sets, design methods, and modeling/simulation tools

Forest Concepts led a project to develop a set of tools which enable feedstock handing equipment designers to better understand and model the flowability of bulk particulate biomass materials. The work products included improved flowability mathematical models, data sets used to populate the models, and two new laboratory devices – a biomass-scale true cubical triaxial tester and a biomass-scale gas pycnometer. This work was funded in part by the US Department of Energy under contact DE-EE0008254.

09 BIOMASS FUELS↗
DOE OSTI2015

Leaning the tank closure process at the Savannah River Site - 15515

The Savannah River Site liquid waste system consists of multiple facilities that safely receive and store legacy radioactive waste prior to treatment and disposition. The liquid radioactive waste is stored in large underground tanks. The waste inventory currently stored in these tanks is a complex mixture of insoluble metal hydroxide solids and soluble salt supernate. The high-level (radioactive) portion of the waste is vitrified into a glass waste form, while the low-level waste is immobilized into a cementitious grout waste form called salt-stone. Once the waste is retrieved and processed, the tanks are closed. The closure process includes; waste removal, characterizing residuals, isolating the tank systems, and stabilizing the tank with tailored grout formulations. The core of Lean is to eliminate waste or non-value added steps from processes to maximize customer value. From the perspective of the customer, 'value' is defined as any action or process for which a customer would willingly pay. In this case our product is to safely and efficiently remove waste from the underground storage tanks and demonstrate operational closure to the State of South Carolina. Savannah River Remediation (SRR) initiated the use of the Lean process in late 2013 and identified the Tank Closure process as one of the targeted areas to improve. The first step in the Lean process is to 'map' out the value stream and identify areas where non-value added steps are present and then prioritize Rapid Improvement Events (RIE). Based on this mapping process, there were a number of areas that SRR determined warranted further evaluation for improvements, including; standard equipment design, characterization, standard work packages, regulatory documentation, tank characterization, structural evaluations, engineering documentation and equipment re-use. This paper focuses on the application of the Lean process at SRR and more specifically, effective application to the Tank Closure Process. This paper discusses the value stream mapping process for Tank Closures, as well as, summarizes the RIEs and demonstrate the realized benefits. Benefits can come in a variety of forms, from schedule compression to decreased costs. Through the Lean process we have been able to identify close to $10 M in savings over the life cycle of the tank closure process and a 4 year schedule compression. Cost and schedule savings are used to accomplish further risk reduction efforts. In addition to hard benefits, there are also soft benefits. These soft benefits are a result of the process itself and help drive improved efficiencies through better communication with key stakeholders, such as regulators and customers. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Scaleup and Site-Specific Engineering Design for Global Thermostat Direct Air Capture Technology

The overall goal of the project is completion of an initial design of a commercial-scale, Carbon Capture, Utilization, and Storage Direct Air Capture (CCUS-DAC) plant design at three different sites that captures a net of at least 100,000 tonnes per year (TPY) carbon dioxide (CO 2 ) from the atmosphere and considers compression and conditioning of the captured CO 2 for purpose of pipeline transportation to different geological formation sites for deep well injection and underground storage. In addition to the leading system consisting of a scaled-up Global Thermostat DAC unit, overall plant design includes a combined Heat and Power (CHP) unit integrated with a conventional liquid amine-based carbon capture system (90% capture) and compression facilities. These are considered balance of plant (BOP) systems and are required to provide low carbon-intensity steam and power to the DAC process. A second approach involving provision of DAC units modified to directly capture emissions from the CHP unit was initially assessed as an alternative and it was determined to be less mature than considered approach and not included in the scaled-up plant design efforts. Three geographically diverse continental United States locations were selected to better understand the effect of local/regional ambient conditions on scaled-up DAC system performance and project costs: Bucks, Alabama (hot wet climate), Odessa, Texas (dry hot climate), and Goose Creek, Illinois (mid continental climate). The team focused on initial engineering design activities, including the development of project design criteria, initiation of site-specific studies and investigations, completion of DAC system process and equipment design, and definition of balance of plant (BOP) engineering. The purpose of the activities were to develop Technoeconomic Analysis (TEA), Life-Cycle Analysis (LCA), and Environmental, Health, and Safety (EH&S) analysis, and Business Case Analysis (BCA) to validate that the project engineering and scale-up plans of the DAC systems, at each of the three distinct case studies considered, are technically, economically, and environmentally feasible for commercial-scale operation.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2018

Testing and Deployment of Remote Systems to Remove Highly Radioactive Soil at Hanford's 324 Building - 18043

U.S. Department of Energy (DOE) contractor CH2M HILL Plateau Remediation Company (CHPRC) is in the process of procuring, testing and deploying remotely operated tools to safely remove highly contaminated soil from beneath the 324 Building on the Hanford Site in southeastern Washington State. The 324 Building operated for more than 40 years, completing a variety of high-dose engineering development and demonstration activities inside six hot cells that shielded the workers from the highly radioactive materials. Activities to decommission, decontaminate and demolish the facility began in 2008. In 2010, soil contamination was found in the soil under one of the hot cells, and building deactivation was paused to evaluate the soil contamination. Sampling efforts, using borehole technology, revealed significant under-building contamination with dose rates measuring has high as 130 Sv/hr (13,000 R/hr). The highly-contaminated soil has to be removed before traditional open air deactivation activities can continue. CHPRC completed proof of concept testing and built a full-scale test facility to demonstrate the effectiveness of three primary tools that will accomplish the floor and soil removal. The tools include a commercially available concrete saw, and a commercially available excavator arm that have been modified to operate remotely in the high-radiation environment within the hot-cell. In order to reduce the wear on the hot-cell overhead cranes, a remote operated rail and cart system has been designed to transport soil and debris out of the hot-cell to an airlock area where the waste will be separated, according to its level of radioactivity. A camera and light system has been designed to provide visual and audio coverage of the hot-cell area that will allow the operations to proceed from remote control stations. This paper will describe the primary remote operated equipment designed for the project and the challenges and processes for developing, testing and deploying the equipment necessary to excavate the soil from below the 324 Building. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Development and Bench-Scale Testing of a Novel Biphasic Solvent-Enabled Absorption Process for Post-Combustion Carbon Capture (Final Technical Report)

A new class of biphasic solvents was developed, and the concept of the enabled carbon dioxide (CO 2 ) absorption process was tested for post-combustion carbon capture in our previous lab-scale research. The primary goals of this project were to advance the development of the novel biphasic CO 2 absorption process (BiCAP) and validate its technical advantages by testing the integrated technology at a 40 kWe bench-scale with actual coal-derived flue gas in a power plant environment. The project was led by the University of Illinois at Urban-Champaign (UIUC), and Trimeric Corporation served as a sub-awardee providing support in basic design and techno-economic studies. To achieve the project goals and objectives, solvent management studies, process modeling and optimization, bench-scale equipment design, construction and testing, and technical, economic and environmental assessments have been conducted. The two top-performing biphasic solvents developed in our previous research were used in this project. Biphasic solvent emissions and control were investigated in the laboratory. The emissions of the biphasic solvents from the absorber were comparable to or lower than the reference 30 wt% monoethanolamine (MEA) solution, while they could be more effectively removed in the water wash column. Lab-scale testing of solvent degradation reclamation has revealed that vacuum distillation was feasible for biphasic solvent reclamation. Aspen Plus models were used to optimize the BiCAP, and a CO 2 stripping configuration introducing a secondary cold solvent feed to the stripper was identified to be the most energy efficient. A 40 kWe bench-scale, integrated BiCAP system was successfully designed, fabricated, and installed at the UIUC’s Abbott Power Plant. Parametric testing with synthetic flue gas has demonstrated that the two biphasic solvents required a more than 40% lower heat duty for CO 2 desorption as compared to the reference MEA tested on the same bench-scale skid. Slipstream testing with actual coal flue gas for a total of 31 days in two test campaigns has further demonstrated stable operation of the bench-scale skid. During the first campaign targeting 90% CO 2 removal, the heat duty averaged at 2,183 MJ/tonne of CO 2 captured and during the second campaign targeting 95% removal, the heat duty averaged at 2,450 MJ/tonne of CO 2 captured. A techno-economic analysis has revealed that for integration of the BiCAP into a 650-MWe pulverized coal-fired power plant, the parasitic power loss was reduced by ~20%, and the cost of CO 2 capture was reduced by ~21% ($36.3/tonne on a December 2018 dollar basis) compared to the U.S. Department of Energy (DOE)’s baseline Case B12B. As progression from this bench-scale development effort, a new project “Engineering-Scale Testing of the Biphasic Solvent Based CO 2 Absorption Capture Technology at a Covanta Waste-to-Energy Facility” was awarded by the DOE, launched in February 2023, to allow the team to further test the technology and demonstrate its technical and economic advantages at a pilot scale.

20 FOSSIL-FUELED POWER PLANTS↗