SEARCH · Engineering Papers
Results for “Entropy change”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
ENTROPY CHANGES IN NONEQUILIBRIUM FLOWS
Two-system model of nonequilibrium expanding and compressing dissociated gas flows, for determining entropy changes
Diurnal movements of cotton leaves expressed as thermodynamic work and entropy changes
It is pointed out that some important agricultural crops show heliotropic leaf movements. In these species, the proclivity of leaves to orient either perpendicularly or parallel or in some combination of these positions with respect to the sun is controlled by the leaf turgor and the availability of water. Such an orientational response is particularly noticeable for cotton. Schutt et al. (1985) have detailed leaf trajectories using three angles. The present investigation applies the three-angle representation to leaf trajectory mapping and to the calculation of the phase angle 'gamma' between the individual leaf normals and the solar direction. Using gamma, the thermodynamic work and entropy functions are evaluated and used to distinguish between the behavior of water-stressed and well watered cotton canopies.
Calculation of the thermoneutral potential of NiCd and NiH2 cells
The thermoneutral potential of a nickel cadmium or nickel hydrogen cell is the potential at which the cell charge or discharge process puts out zero heat, and thus is the potential corresponding to the enthalpy change of the charge/discharge reaction, delta H. A relatively straightforward method for obtaining the thermoneutral potential E(sub tn), is based on the measured potential and temperature derivative of the cell reactions, which are related to the free energy change delta G, and entropy change delta S, respectively. Particularly in the nickel hydrogen cell, the pressure of hydrogen can often vary over an order of magnitude or more during the course of a charge or discharge. In a nickel cadmium cell, although significant changes in oxygen pressure can occur during charge or discharge, since oxygen does not enter into the charge/discharge reaction, these pressure changes are related to the heat generated from oxygen evolution and recombination. However, the entropy changes due to changes in hydrogen pressure relative to the 1 atm standard state must be included to apply this method to the nickel hydrogen cell.
Complex magnetic ground state driving a large rotating magnetocaloric effect in Tb 3 Ni at low temperature
The rotating magnetocaloric effect (RMCE) offers a promising alternative to conventional magnetocaloric configurations by taking advantage of magnetic anisotropy to simplify device architecture and enhance refrigeration efficiency. In this study, the RMCE in a high-quality single crystal of Tb 3 Ni is investigated, a compound previously shown to exhibit significant magnetocaloric behavior along its easy axis of magnetization. By measuring the magnetization and corresponding entropy change along the three principal crystallographic axes using a discontinuous measurement protocol, we verify the anisotropic magnetic properties and derive the RMCE from rotations between hard ( a, b ) and easy ( c ) axes of magnetization. Our results show a maximum value for the rotating entropy change of 19.5 J kg −1 K −1 for µ 0 H = 7 T around 60 K, within the critical temperature window for industrial gas liquefaction applications. Neutron diffraction and magnetic Pair-Distribution Function (mPDF) analysis reveal that the origin of this large anisotropic response lies in a partially ordered incommensurate spin-density wave phase and persistent short-range ferromagnetic (FM) correlations. These complex magnetic states enable the release of a substantial amount of magnetic entropy when the field is applied along the easy c-axis, effectively driving the large RMCE. Comparison with other RMCE materials confirms Tb 3 Ni as one of the most promising candidates in this temperature regime, offering both a large magnetic entropy change and a wide operating window.
Effects of carbon substitution on magnetic properties and magnetocaloric effects in Mn 65-x Ga 17 C 18+x compounds
This study involved the tuning of the magnetic, magnetocaloric, and room-temperature structural properties of Mn 65-x Ga 17 C 18+x (0 ≤ x ≤ 4) compounds prepared using a high-energy ball milling (HEBM) technique. This study indicates that the crystal structure of all the compounds can be described as an anti-perovskite cubic structure with the Pm-3m space group and the crystal cell volume decreases with increasing carbon concentration. The system shows a first-order structural phase transition at a temperature T=T M between two cubic phases having different magnetic structures. The phases are characterized by antiferromagnetic (AFM) and ferromagnetic (FM) -like behavior at low (T < T M ) and high (T M > T) temperature regions, respectively. A suppression of the AFM phase was observed with increasing C concentration. The temperature-induced first-order transitions (FOTs) were found to possess a small thermal hysteresis in the magnetization (~2-3 K) in an applied magnetic field of H = 50 kOe. Magnetic entropy changes estimated from isothermal magnetization curves indicate that the largest value of the magnetic entropy change of |ΔS M | = 2.1 J kg -1 K -1 for x = 4 with ΔH = 50 kOe, with a relative cooling power (RCP) of ~190 J kg -1 . Furthermore, high-energy ball milling (HEBM), a scalable technique, has been demonstrated as a viable method to synthesize magnetocaloric materials with substantial RCP values.
Rare-Earth Garnets and Perovskites for Space-Based ADR Cooling at High T and Low H
Future NASA satellite detector systems must be cooled to the 0.1 K temperature range to meet the stringent energy resolution and sensitivity requirements demanded by mid-term astronomy missions. The development of adiabatic demagnetization refrigeration (ADR) materials that can efficiently cool from the passive radiative cooling limit of approx. 30 K down to sub-Kelvin under low magnetic fields (H less than or equal to 3 T) would represent a significant improvement in space-based cooling technology. Governed by these engineering goals, our efforts have focused on quantifying the change in magnetic entropy of rare-earth garnets and perovskites. Various compositions within the gadolinium gallium iron garnet solid solution series (GGIG, Gd3Ga(5-x)Fe(x)O12, 0.00 less than or equal to X less than or equal to 5.00) and gadolinium aluminum perovskite (GAP, GdAlO3) have been synthesized via an organometallic complex approach and confirmed with powder x-ray diffraction. The magnetization of the GGIG and GAP materials has been measured as a function of composition (0.00 less than or equal to X less than or equal to 5.00), temperature (2 K less than or equal to T less than or equal to 30 K) and applied magnetic field (0 T less than or equal to H less than or equal to 3 T). The magnetic entropy change (DeltaS(sub mag)) between 0 T and 3 T was determined from the magnetization data. In the GGIG system, DeltaS(sub mag) was compositionally dependent; Fe(sup 3+) additions up to X less than or equal to 2.44 increased DeltaS(sub mag) at T > 5 K. For GAP, DeltaS(sub mag) was similar to that of GGIG, X = 0.00, both in terms of magnitude and temperature dependence at T > 10 K. However, the DeltaS(sub mag) of GAP at T < 10 K was less than the endmember GGIG composition, X = 0.00, and exhibited maximum approx. 5 K.
Wave generation in a sunspot
In this paper we analyze the generation of waves in a sunspot by extending Stein's hydrodynamic approach to the turbulent medium permeated by a strong uniform magnetic field oriented parallel to the gravity. For wave sources appropriate to the sunspot, we consider magnetic perturbations and entropy changes as well as turbulent convection. To describe the anisotropy imposed by the sunspot, we use a one-dimensional correlation function relating the turbulent eddies separated along the symmetry axis of the spot. This treatment yields several interesting possibilities for wave generation in a sunspot. First, it is demonstrated that the entropy change and magnetic perturbation can lead to a relative enhancement of acoustic wave emission. Second, the energy flux of Alfven waves may be comparable to that of acoustic waves in sunspots. Third, the anisotropy of the sunspot dynamics can lead to wave energy spectrum in a form which may explain the origin of umbral atmospheric oscillations.
Application of radial-equilibrium condition to axial-flow turbomachine design including consideration of change of entropy with radius downstream of blade row
Explore the source record for details and available documents.
A combined experimental and machine learning exploration of Ti 2-x Zr x MnCrFeNi high entropy Laves hydrides
A series of high entropy AB 2 -type Ti 2-x Zr x MnCrFeNi alloys (x = 0.6, 0.7, 0.8, 0.9, 1.0, 1.1 and 1.2) were synthesized to investigate their potential for hydrogen storage and chemical compression. The influence of the Ti/Zr ratio was explored in terms of structural, microstructural and thermodynamic properties. The storage capacity together with the reaction enthalpy and entropy changes of the synthesized high entropy alloys were compared to predictions from Machine Learning (ML) to investigate changes in these properties across the explored composition space. The results revealed that a decreasing Zr content consistently lowered the hydride formation enthalpy and increased the plateau pressure from 8 to >90 bar H 2 at 25 °C, in good agreement with ML predictions. Selected compositions (x = 1.0 and 1.2) demonstrated reversible hydrogen storage capability over 150 cycles, with capacities of 1.34–1.40 wt % H 2 and remarkable reaction kinetics (<4 min) at ambient temperature. These experimental and computational findings highlight the potential of this Laves-HEA system as tuneable, stable, and cost-effective materials suitable for long-term operations in stationary hydrogen storage and compression applications.
Sonic boom analysis for high altitude flight at high Mach number
Numerical programs are presented which take into account the nonlinear effects of high Mach number, the entropy change across the shock, the entropy and enthalpy variations in the atmospheric layer and the gravitational effect. Extension of the programs for the axisymmetric problems to handle nonaxisymmetric terms is described. The asymmetry can be caused by the geometry of the body, the lift and also the fact that the variations in the atmospheric layer are two-dimensional. Numerical results demonstrating the influences of these effects and comparison with existing approximate theories are presented.
Nonlinear sonic boom analysis including the asymmetric effects
A numerical program is developed which takes into account the nonlinear effects of high Mach number, the entropy change across the shock, the entropy and enthalpy variations in the atmospheric layer and the gravitational effect. The program differs from the existing ones by accounting for non-axisymmetric terms. The asymmetry can be caused by the geometry of the body, the lift and also the fact that the variations in the atmospheric layer are two-dimensional. Numerical results demonstrate that the influence of these asymmetric effects tends to lower the pressure signature.
Sonic boom analysis for high-altitude flight at high Mach number
Numerical programs for the computation of the flow field from the airplane at the flight altitude to the ground are presented. They take into account the nonlinear effects of high Mach number, the entropy change across the shock, the entropy and enthalpy variations in the atmospheric layer, and the gravitational effect. Extension of the programs for the axisymmetric problems to handle nonaxisymmetric terms is described. The asymmetry can be caused by the geometry of the body and the lift, and also by the fact that the variations in the atmospheric layer are two-dimensional. Numerical results for ground level signatures of several configurations at various flight conditions are presented and compared with existing approximate theories to demonstrate the influences of these nonlinear effects.
Revisiting the First, Second and Combined Laws of Thermodynamics
The present study revisits the first, second, and combined laws of thermodynamics by introducing partial internal energy in the first law, entropy production and partial entropy in entropy change, and partial volume in the context of work exchange. These developments yield a more rigorous and internally consistent thermodynamic framework, within which chemical potential is defined as the partial derivative of internal energy with respect to composition at constant entropy and volume, and is related to partial internal energy, partial entropy, and partial volume.
Shock heating of the solar wind plasma
The role played by shocks in heating solar-wind plasma is investigated using data on 413 shocks which were identified from the plasma and magnetic-field data collected between 1973 and 1982 by Pioneer and Voyager spacecraft. It is found that the average shock strength increased with the heliocentric distance outside 1 AU, reaching a maximum near 5 AU, after which the shock strength decreased with the distance; the entropy of the solar wind protons also reached a maximum at 5 AU. An MHD simulation model in which shock heating is the only heating mechanism available was used to calculate the entropy changes for the November 1977 event. The calculated entropy agreed well with the value calculated from observational data, suggesting that shocks are chiefly responsible for heating solar wind plasma between 1 and 15 AU.
Magnetocaloric effect in Mn-rich Heusler-derived alloys for room temperature-based applications
Magnetic refrigeration-based technologies rely on the magnetocaloric properties of materials and are crucial for improving energy efficiency and for supporting clean environments. However, materials possessing significant magnetocaloric properties that can be used for room temperature-based applications are still lacking. Heusler alloys (such as Mn–Ni–Ga) show giant magnetocaloric effects, which can be further improved by tuning their composition. Herein, we optimized the ratio of Ni to Ga to achieve an alloy with unique magnetocaloric properties. Here, the alloy demonstrated a substantial magnetocaloric effect, attributed to its narrow temperature range for structural and magnetic phase transitions (near room temperature with minimal hysteresis). Structural phase changes were also observed through high-resolution transmission electron microscopy. Optimum entropy changes, calculated from isothermal magnetization curves (4 Tesla magnetic field), were found to be 24.50 J kg −1 K −1 , which is higher than that of state-of-the-art alloys. Experimental demonstration of the magnetocaloric effect (refrigeration cycle) was also carried out using a thermal imaging camera. Furthermore, first-principles calculations were conducted to validate the experimental findings, specifically focusing on the compositional effects on the structural transitions and magnetic properties of the investigated MNG alloys.
Molecular microenvironments: Solvent interactions with nucleic acid bases and ions
The possibility of reconstructing plausible sequences of events in prebiotic molecular evolution is limited by the lack of fossil remains. However, with hindsight, one goal of molecular evolution was obvious: the development of molecular systems that became constituents of living systems. By understanding the interactions among molecules that are likely to have been present in the prebiotic environment, and that could have served as components in protobiotic molecular systems, plausible evolutionary sequences can be suggested. When stable aggregations of molecules form, a net decrease in free energy is observed in the system. Such changes occur when solvent molecules interact among themselves, as well as when they interact with organic species. A significant decrease in free energy, in systems of solvent and organic molecules, is due to entropy changes in the solvent. Entropy-driven interactioins played a major role in the organization of prebiotic systems, and understanding the energetics of them is essential to understanding molecular evolution.
Propulsion over a wide Mach number range
Criteria is presented to assess the relative merits of different propulsion systems. Previous references focus mainly on subsonic or low supersonic flight speeds. The main focus here is on a higher range, from low supersonic to orbital velocities. Air breathing propulsion systems for hypersonic flight persent the engine designer with circumstances that differ in important fundamental ways from those encountered in engines designed for operation at subsonic or low supersonic speeds. This analysis highlights the importance of various features of hypersonic engine design. Since the performance of hypersonic engines are energy limited, unlike low speed engines which are stagnation pressure limited, the efficient use of the energy of the fuel used is critical to minimize the take-off fuel mass fraction of the vehicle. Furthermore, since the required energy increase of a vehicle per incremental speed change increases with speed, the engine must be designed to operate efficiently at high speed. An analysis of engine performance in terms of entropy changes of the flow passing through the engine allows comparison of various engine designs as well as a convenient method to determine the effect of individual engine component efficiencies on overall engine performance.