Theoretical aspects of metal-electrolyte interfaces Final report
Skin surface electrode and electrochemical cell characteristics for human bioelectric response determinations
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Skin surface electrode and electrochemical cell characteristics for human bioelectric response determinations
Future NASA missions require high specific energy battery technologies, greater than 400 Wh/kg. Current NASA missions are using "state-of-the-art" (SOA) Li-ion batteries (LIB), which consist of a metal oxide cathode, a graphite anode and an organic electrolyte. NASA Glenn Research Center is currently studying the physical and electrochemical properties of the anode-electrolyte interface for ionic liquid based Li-air batteries. The voltage-time profiles for Pyr13FSI and Pyr14TFSI ionic liquids electrolytes studies on symmetric cells show low over-potentials and no dendritic lithium morphology. Cyclic voltammetry measurements indicate that these ionic liquids have a wide electrochemical window. As a continuation of this work, sp2 carbon cathode and these low flammability electrolytes were paired and the physical and electrochemical properties were studied in a Li-air battery system under an oxygen environment.
Vapor diffusion type fuel cell electrode presents a nonwetting barrier to the liquid feedstocks so they may contact the electrolyte only in the vapor state. Thus, it effects feedstock mixing with the electrolyte at the electrolyte/catalyst interface but prevents feedstock decomposition and catalyst poisoning from liquid mingling.