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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Configurations of base-pair complexes in solutions

A theoretical search for the most stable conformations (i.e., stacked or hydrogen bonded) of the base pairs A-U and G-C in water, CCl4, and CHCl3 solutions is presented. The calculations of free energies indicate a significant role of the solvent in determining the conformations of the base-pair complexes. The application of the continuum method yields preferred conformations in good agreement with experiment. Results of the calculations with this method emphasize the importance of both the electrostatic interactions between the two bases in a complex, and the dipolar interaction of the complex with the entire medium. In calculations with the solvation shell method, the last term, i.e., dipolar interaction of the complex with the entire medium, was added. With this modification the prediction of the solvation shell model agrees both with the continuum model and with experiment, i.e., in water the stacked conformation of the bases is preferred.

Egan, J. T.↗
NASA NTRS1976

Proton magnetic relaxation and internal rotations in tetramethylammonium cadmium chloride

Nuclear magnetic resonance (NMR) and relaxation studies of the proton spin-lattice relaxation time (PSLRT) and proton second moment (PSM) are reported. Tetramethylammonium cadmium chloride (TMCC) was selected as a diamagnetic member of the isomorphic series, and hence proton data relate directly to the motion of the tetramethylammonium ion in the absence of paramagnetic ions. In the model adopted, the correlation time for hindered motion of one of the methyl groups differs from that of the other three groups in the low-temperature phase below 104 K. PSLRT and PSM values agree closely with experimental data with this model. Crystallographic phase transitions in TMCC occur at 104 K and 119 K according to the PSLRT measurements. Dipolar interactions between adjacent protons account for the PSLR rates below 104 K.

Tsang, T.↗
NASA NTRS1987

Indirect measurement of N-14 quadrupolar coupling for NH3 intercalated in potassium graphite

A method for indirect measurement of the nuclear quadrupolar coupling was developed and applied to NH3 molecules in the graphite intercalation compound K(NH3)4.3C24, which has a layered structure with alternating carbon and intercalant layers. Three triplets were observed in the H-1 NMR spectra of the compound. The value of the N-14 quadrupolar coupling constant of NH3 (3.7 MHz), determined indirectly from the H-1 NMR spectra, was intermediate between the gas value of 4.1 MHz and the solid-state value of 3.2 MHz. The method was also used to deduce the (H-1)-(H-1) and (N-14)-(H-1) dipolar interactions, the H-1 chemical shifts, and the molecular orientations and motions of NH3.

Tsang, T.↗
NASA NTRS1987

H-1 NMR study of ternary ammonia-alkali metal-graphite intercalation compounds

For the first-stage ternary ammonia-alkali metal-graphite intercalation compounds M(NH3)(x)C24(x of about 4, M = K, Rb, Cs), three sets of triplet H-1 NMR spectral lines have been observed at various temperatures and orientations due to the H-1 - H-1 and N-14 - H-1 dipolar interactions. The structures of these compounds have been inferred as mobile (liquid-like) intercalant layers of planar M(NH3)4 ions in between the carbon layers. For the intercalated ammonia molecules, the potential barrier is about 0.2 eV and the molecular geometry is very close to the free NH3 in gas phase.

Tsang, T.↗
NASA NTRS1985

The interaction of a dipolar thunderstorm with its global electrical environment

The role of the thundercloud in the global electric circuit has been considered by many researchers. Thus, Holzer and Saxon (1952) have constructed a simple model of a bipolar thunderstorm. The global models considered provide insight into the atmospheric electric circuit but are restricted, both by various analytical mathematical representations and by computer size, to a grid of about five degrees in latitude and longitude. A need exists, therefore, for the development of a numerical regional model capable of resolving small-scale phenomena so that their coupling into the global-scale circuit can be examined. The construction of a two-dimensional quasi-static numerical model of atmospheric electricity is discussed. The model provides a basis for the calculation of the global electric field and current distribution produced by a single thunderstorm generator. In connection with the calculations, the thunderstorm was defined by a quasi-static current source function which generates a dipole charge configuration.

Tzur, I.↗
NASA NTRS1965

Generalized keesom potential

Field theoretic approach for generalization of expressions for adiabatic interaction between two rotating dipolar systems

ADIABATIC EQUATION↗
NASA NTRS1974

Analysis of multiple pulse NMR in solids. II

A systematic method, an extension of the average Hamiltonian formalism, is presented for calculating the effects of pulse errors and imperfections in the multiple pulse nuclear magnetic resonance experiments. Application of this method to account for effects of pulse nonidealities such as phase errors, phase transient effects, pulse size errors, and rf inhomogeneity is found to agree with experimental observation, and the results furnish a basis for understanding the complex couplings between the pulse errors and other interactions such as the dipolar and the chemical shift Hamiltonians.

Rhim, W.-K.↗
NASA NTRS1987

Geocoronal structure. II - Inclusion of a magnetic dipolar plasmasphere

Calculations of exospheric quantities (hydrogen atom density, satellite atom fractional density, kinetic temperature, and escape flux) at locations along the earth-sun axis in the noon and midnight directions have been extended to incorporate a plasmasphere characterized by a dipolar shape and an empirical temperature profile. This interaction, evaluated with parameter values corresponding to low-to-moderate solar conditions, results in an increased density at outer geocoronal positions; the effect is not dramatic, though, and the resulting exosphere mimics the evaporative case closely, in spite of the control of trajectory parcel content by charge exchange collisions. A careful discussion of the handling of plasmaspheric charge exchange collisions and solar ionization is included, and the effect on the exospheric kinetic distribution is analyzed in terms of pertinent examples.

Bishop, James↗
NASA NTRS1992

The solar wind interaction with Venus

The Pioneer Venus Orbiter (PVO) mission has played a key role in establishing the nature of the solar wind interaction with Venus. Although earlier probes had determined that Venus presented an obstacle much smaller than the size of earth's magnetosphere to the solar wind, they did not carry out in situ measurements pertaining to solar wind interaction studies at low enough altitudes to determine why. They also did not provide datasets of sufficient duration to study the variability of the interaction of both short (one day) and long (solar cycle) timescales. The first 600 of the nearly 5000 orbits of PVO magnetometer data have been used to determine a very low upper limit on the intrinsic dipolar magnetic moment of Venus. The consequence of that low magnetic moment is that the solar wind interacts directly with the upper atmosphere and ionosphere. Relative to a dipolar field obstacle, the ionospheric obstacle is rather incompressible. A bow shock is observed to stand in front of the nearly Venus-sized ionospheric obstacle at a comparatively steady subsolar altitude of approximately 1.5 R(v) (Venus radii). This shock decelerates the supersonic solar wind plasma so that it can flow around the obstacle. It was found to change its average position in the terminator plane from about 2.4 R(v) to 2.1 R(v) as the solar cycle progressed from the 1978 orbit insertion near solar maximum through the 1986-87 solar minimum, and back again during the latest solar activity increase. Between the bow shock and the ionosphere proper, the slowed solar wind plasma flow diverges near the subsolar point and makes its way across the terminator where it reaccelerates and continues anti-Sunward. The solar wind magnetic field, which is in effect frozen into the flowing plasma, is distorted in this 'magnetosheath' region so that it appears to hang up or drape over the dayside ionosphere before it slips around with the flow. These features of the solar wind interaction are also seen when the obstacle is a dipole magnetic field, but there are two important distinctions. In the wake of the Venus obstacle one finds an induced magnetic tail composed of varying interplanetary fields rather than the constant fields of intrinsic origin. This magnetotail is further seen to be populated by Heavy (0+) ions that are evidently escaping from the planet at significant (approximately 10(exp -25) s(exp -1)) rates. These heavy ions are also observed in the dayside magnetosheath. The interpretation is that ions are produced by both photoionization and solar wind electron impact ionization of the upper neutral atmosphere that extends into the magnetosheath.

Luthmann, J. G.↗
NASA NTRS1990

Average patterns of precipitation and plasma flow in the plasma sheet flux tubes during steady magnetospheric convection

Average patterns of plasma drifts and auroral precipitation in the nightside auroral zone were constructed during a steady magnetospheric convection (SMC) event on February 19, 1978. By comparing these patterns with the measurements in the midtail plasma sheet made by ISEE-1, and using the corresponding magnetic field model, the following features are inferred: (1) the concentration of the earthward convection in the midnight portion of the plasma sheet (convection jet); (2) the depleted plasma energy content of the flux tubes in the convection jet region; and (3) the Region-1 field-aligned currents generated in the midtail plasma sheet. It is argued that these three elements are mutually consistent features appearing in the process of ionosphere-magnetosphere interaction during SMC periods. These configurational characteristics resemble the corresponding features of substorm expansions (enhanced convection and 'dipolarized' magnetic field within the substorm current wedge) and appear to play the same role in regulating the plasma flow in the flux tubes connected to the plasma sheet.

Sergeev, V. A.↗
NASA NTRS1977

The magnetic field of Mercury

The Mariner 10 spacecraft encountered Mercury three times in 1974-1975. The first and third encounters provided detailed observations of a well-developed detached bow shock wave which results from the interaction of the solar wind. The planet possesses a global magnetic field and a modest magnetosphere, which deflects the solar wind. The field is approximately dipolar, with orientation in the same sense as earth, tilted 12 deg from the rotation axis. The magnetic moment corresponds to an undistorted equatorial field intensity of 350 gammas, approximately 1% of earth's. The field, while unequivocally intrinsic to the planet, may be due to remanent magnetization acquired from an extinct dynamo or a primordial magnetic field or due to a presently active dynamo. The latter possibility appears more plausible at present. In any case, the existence of the magnetic field provides very strong evidence of a mature differentiated planetary interior with a large core (core radius about 0.7 Mercury radius) and a record of the history of planetary formation in the magnetization of the crustal rocks.

Ness, N. F.↗
NASA NTRS1983

On the evolution of Saturn's 'Spokes' - Theory

Starting with the assumption that negatively charged micron-sized dust grains may be elevated above Saturn's ring plane by plasma interactions, the subsequent evolution of the system is discussed. The discharge of the fine dust by solar UV radiation produces a cloud of electrons which moves adiabatically in Saturn's dipolar magnetic field. The electron cloud is absorbed by the ring after one bounce, alters the local ring potential significantly, and reduces the local Debye length. As a result, more micron-sized dust particles may be elevated above the ring plane and the spoke grows. This process continues until the electron cloud has dissipated.

Morfill, G. E.↗
NASA NTRS1972

Hyperfine interactions of Fe/2+/ in ilmenite.

Hyperfine interactions at the Fe(2+) sites in ilmenite have been determined by Mossbauer spectroscopy. At 5 K, the internal magnetic field is -43 (plus or minus 3) kOe, and the quadrupole coupling constant is +1.44 (plus or minus 0.01) mm/sec. Theoretical interpretation of the internal magnetic field in terms of dipolar-, orbital-, and core-polarization contributions is shown to depend critically upon the still unknown lattice contribution to the quadrupole coupling constant.

Grant, R. W.↗
NASA NTRS1976

Venera-9 magnetic field measurements in the Venus wake - Evidence for an earth-like interaction

Venera-9 magnetic field measurements in the Venus wake provide additional support for the hypothesis that Venus has an intrinsic planetary field. The observed field is in the direction expected for a northward moment, and is similar to that observed in equivalent locations in the terrestrial magnetosphere, both in its temporal and spatial behavior. In particular, Venera-9 appears to have observed a plasma sheet expansion, field-aligned currents, and tail-field dipolarization.

Russell, C. T.↗