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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Designing Graceful Degradation into Complex Systems: The Interaction Between Causes of Degradation and the Association with Degradation Prevention and Recovery

System resilience is critical to safety in air traffic control. An important element of maintaining resilience is the ability of systems to degrade gracefully. Of the available graceful degradation research, a majority of studies have focused primarily on technological causes of degradation only, limiting an ecologically valid understanding of the causes of degradation in air traffic control, and the preventative and mitigative strategies that enable graceful degradation. The current study aimed to address this research gap by investigating causes of degradation in air traffic control across the broad categories of technology, the environment, and the human operator, and the potential interactions between these causes. 12 retired controllers participated in semi-structured interviews focused on previous experience of causes of degradation and mitigation strategies. Findings provide an understanding of causation of degradation in air traffic control, and the prevention and mitigation strategies that moderate the relationship between cause and system effect. Findings confirmed that causes appear to interact to create compound, multiple effects on overall system performance. Findings also revealed prevention and mitigation strategies utilized to moderate the effect of the cause on the system. In order to gain an ecologically valid understanding of the causes of degradation, and effective prevention or mitigation strategies, causes from multiple categories, and the interactions between them, must be identified. Findings have implications for designers of future air traffic control systems to ensure the ability of the system to gracefully degrade, as well as risk assessment and system validation processes.

human performance↗
NASA NTRS2018

Designing Graceful Degradation into Complex Systems: Identification of Causes of Degradation, Interactions, and Mitigation of Degradation in Air Traffic Control

System resilience is critical to safety in air traffic control. An important element of maintaining resilience is the ability of systems to degrade gracefully. Of the available graceful degradation research, a majority of studies have focused primarily on technological causes of degradation only, limiting an ecologically valid understanding of the causes of degradation in air traffic control, and the preventative and mitigative strategies that enable graceful degradation. The current study aimed to address this research gap by investigating causes of degradation in air traffic control across the broad categories of technology, the environment, and the human operator, and the potential interactions between these causes. 12 retired controllers participated in semi-structured interviews focused on previous experience of causes of degradation and mitigation strategies. Findings provide an understanding of causation of degradation in air traffic control, and the prevention and mitigation strategies that moderate the relationship between cause and system effect. Findings confirmed that causes appear to interact to create compound, multiple effects on overall system performance. Findings also revealed prevention and mitigation strategies utilized to moderate the effect of the cause on the system. In order to gain an ecologically valid understanding of the causes of degradation, and effective prevention or mitigation strategies, causes from multiple categories, and the interactions between them, must be identified. Findings have implications for designers of future air traffic control systems to ensure the ability of the system to gracefully degrade, as well as risk assessment and system validation processes.

human performance↗
NASA NTRS2018

Designing Graceful Degradation into Complex Systems: The Interaction Between Causes of Degradation and the Association with Degradation Prevention and Recovery

System resilience is critical to safety in air traffic control. An important element of maintaining resilience is the ability of systems to degrade gracefully. Of the available graceful degradation research, a majority of studies have focused primarily on technological causes of degradation only, limiting an ecologically valid understanding of the causes of degradation in air traffic control, and the preventative and mitigative strategies that enable graceful degradation. The current study aimed to address this research gap by investigating causes of degradation in air traffic control (ATC) across the broad categories of technology, the environment, and the human operator, and the potential interactions between these causes. 12 retired controllers (ATCOs - Air Traffic Control Officers) participated in semi-structured interviews focused on previous experience of causes of degradation and mitigation strategies. Findings provide an understanding of causation of degradation in air traffic control, and the prevention and mitigation strategies that moderate the relationship between cause and system effect. Findings confirmed that causes appear to interact to create compound, multiple effects on overall system performance. Findings also revealed prevention and mitigation strategies utilized to moderate the effect of the cause on the system. In order to gain an ecologically valid understanding of the causes of degradation, and effective prevention or mitigation strategies, causes from multiple categories, and the interactions between them, must be identified. Findings have implications for designers of future air traffic control systems to ensure the ability of the system to gracefully degrade, as well as risk assessment and system validation processes.

Graceful Degradation↗
NASA NTRS1990

Possible atmospheric lifetimes and chemical reaction mechanisms for selected HCFCs, HFCs, CH3CCl3, and their degradation products against dissolution and/or degradation in seawater and cloudwater

For a wide variety of atmospheric species including CO2, HNO3, and SO2, dissolution in seawater or cloudwater followed by hydrolysis or chemical reaction represents a primary pathway for removal from the atmosphere. In order to determine if this mechanism can also remove significant amounts of atmospheric chlorofluorocarbons (HCFC's), fluorocarbons (HFC's), and their degradation products, an investigation was undertaken as part of the Alternative Fluorocarbons Environmental Acceptability Study (AFEAS). In this investigation, the rates at which CHCl2CF3 (HCFC-123), CCl2FCH3 (HCFC-141b), CClF2CH3 (HCFC-142b), CHClF2 (HCFC-22), CHClFCF3 (HCFC-124) CH2FCF3 (HFC-134a) CHF2CH3 (HFC-152a), CHF2CF3 (HFC-125), and CH3CCl3 can be dissolved in the oceans and in cloudwater were estimated from the species' thermodynamic and chemical properties using simple mathematical formulations to simulate the transfer of gases from the atmosphere to the ocean or cloudwater. The ability of cloudwater and rainwater to remove gas phase degradation products of these compounds was also considered as was the aqueous phase chemistry of the degradation products. The results of this investigation are described.

Wine, P. H.↗
NASA NTRS1999

On the Oxidative Degradation of Nadic End-Capped Polyimides: Synthesis and Characterization of Model Compounds for End-Cap Degradation Products - 3

The oxidative degradation of PMR (for polymerization of monomeric reactants) polyimides at elevated temperatures was followed by cross-polarized magic angle spinning (CP-MAS) NMR. Labeling of selected sites in the polymers with C-13 allowed for direct observation of the transformations arising from oxidation processes. The formation of several degradation products has been proposed to be occurring in the cross-links derived from the nadic end caps on oxidation. Model compounds have been synthesized and characterized by CPMAS NMR with both normal and delayed decoupling to distinguish between protonated and unprotonated carbons. Comparison of these spectra to predicted chemical shifts of proposed products for the aged polymer provides further insight to degradation occurring in the cross-linked moieties.

Meador, Mary Ann B.↗
NASA NTRS1996

Effects of Material Degradation on the Structural Integrity of Composite Materials: Experimental Investigation and Modeling of High Temperature Degradation Mechanisms

It has previously been demonstrated that simple coupled reaction-diffusion models can approximate the aging behavior of PMR-15 resin subjected to different oxidative environments. Based on empirically observed phenomena, a model coupling chemical reactions, both thermal and oxidative, with diffusion of oxygen into the material bulk should allow simulation of the aging process. Through preliminary modeling techniques such as this it has become apparent that accurate analytical models cannot be created until the phenomena which cause the aging of these materials are quantified. An experimental program is currently underway to quantify all of the reaction/diffusion related mechanisms involved. The following contains a summary of the experimental data which has been collected through thermogravimetric analyses of neat PMR-15 resin, along with analytical predictions from models based on the empirical data. Thermogravimetric analyses were carried out in a number of different environments - nitrogen, air and oxygen. The nitrogen provides data for the purely thermal degradation mechanisms while those in air provide data for the coupled oxidative-thermal process. The intent here is to effectively subtract the nitrogen atmosphere data (assumed to represent only thermal reactions) from the air and oxygen atmosphere data to back-figure the purely oxidative reactions. Once purely oxidative (concentration dependent) reactions have been quantified it should then be possible to quantify the diffusion of oxygen into the material bulk.

Cunningham, Ronan A.↗
NASA NTRS2021

Mapping the Extent of Mangrove Ecosystem Degradation by Integrating an Ecological Conceptual Model with Satellite Data

Anthropogenic and natural disturbances can cause degradation of ecosystems, reducing their capacity to sustain biodiversity and provide ecosystem services. Understanding the extent of ecosystem degradation is critical for estimating risks to ecosystems, yet there are few existing methods to map degradation at the ecosystem scale and none using freely available satellite data for mangrove ecosystems. In this study, we developed a quantitative classification model of mangrove ecosystem degradation using freely available earth observation data. Crucially, a conceptual model of mangrove ecosystem degradation was established to identify suitable remote sensing variables that support the quantitative classification model, bridging the gap between satellite-derived variables and ecosystem degradation with explicit ecological links. We applied our degradation model to two case-studies, the mangroves of Rakhine State, Myanmar, which are severely threatened by anthropogenic disturbances, and Shark River within the Everglades National Park, USA, which is periodically disturbed by severe tropical storms. Our model suggested that 40% (597 km2) of the extent of mangroves in Rakhine showed evidence of degradation. In the Everglades, the model suggested that the extent of degraded mangrove forest increased from 5.1% to 97.4% following the Category 4 Hurricane Irma in 2017. Quantitative accuracy assessments indicated the model achieved overall accuracies of 77.6% and 79.1% for the Rakhine and the Everglades, respectively. We highlight that using an ecological conceptual model as the basis for building quantitative classification models to estimate the extent of ecosystem degradation ensures the ecological relevance of the classification models. Our developed method enables researchers to move beyond only mapping ecosystem distribution to condition and degradation as well. These results can help support ecosystem risk assessments, natural capital accounting, and restoration planning and provide quantitative estimates of ecosystem degradation for new global biodiversity targets.

Calvin K. F. Lee↗
NASA NTRSDate not supplied

Comprehensive Analysis of Thirty Years of Land Change in Georgia: Forest Degradation, Land-Use Patterns, and Drivers

In this talk, we present results from a study, funded by the NASA Land-Cover and Land-Use Change program, of thirty years of environmental change in the country of Georgia. The country, a former Soviet Union Republic, has experienced more political, economic and social change in the last 30 years than most countries. But the environmental implications of these extreme events remain largely unknown – the region is understudied, no national forest inventory has been completed in 20 years, and previous research in the area conducted by the authors were not successful. The latter statement is because of forest degradation. After the collapse of the Soviet Union, much of the forestry infrastructure broke down and people resorted to chopping down individual trees. The result was in many parts of the country a reduction in forest biomass but not to the point of a change in land cover. This type of forest degradation, which was either gradual over decades or abrupt, could not be readily identified using the methods and data at our disposal at the time. In the recent study, we had full access to the Landsat archive in combination with computing power. By using monitoring methods that are based on time series analysis, we were able to capture and identify the gradual processes driven by small scale activities that are so characteristic of the post-Soviet Georgian landscape. We developed an approach (“CCDC-SMA”) that combines time series analysis and spectral mixture analysis running on Google Earth Engine for monitoring abrupt and gradual forest degradation. By using this approach, we found that forest degradation was significantly larger than the area estimate of deforestation; 3,541 ± 556 km2 (11% of the forest area in 1987) compared to 158 ± 98 km2 from 1987 to 2020. The prevailing narrative is that legal and illegal cutting of trees for fuelwood is primarily responsible for this process. Yet, since independence from the Soviet Union in 1991, the country has undergone rapid socioeconomic and institutional changes which have not been explored as drivers of forest change. To further our understanding of the underlying causes, we combined forest disturbance estimates, Georgian statistical data, and historical institutional change data to examine socioeconomic drivers of forest degradation. We found that higher winter temperature and drought were associated with higher degradation at the regional scale, while major institutional changes and drought were associated with higher forest degradation at the national level. Access to natural gas, the major energy alternative to fuelwood, had no significant association with degradation. Our results challenge the narrative that poverty and a lack of alternative energy infrastructure drive forest degradation and suggest that government policies banning household fuelwood cutting, including the new Forest Code of 2020, may not reduce forest degradation. Given these results, improved data on wood harvesting and more research on the commercial drivers of degradation and their links to economic and political reforms is needed to better inform forest policy in the region, especially given ongoing risks from climate change.

Pontus Olofsson↗
NASA NTRS2011

Method for Impeding Degradation of Porous Silicon Structures

This invention relates to surface modification of porosified silicon (pSi) structures with poly(alkylene) glycols for the purpose of controlled degradation of the silicon matrix and tailored release of encapsulated substances for biomedical applications. The pSi structures are currently used in diverse biomedical applications including bio-molecular screening, optical bio-sensoring, and drug delivery by means of injectable/orally administered carriers and implantable devices. The size of the pores and the surface chemistry of the pSi structure can be controlled during the microfabrication process and thereafter. A fine regulation of the degradation kinetics of mesoporous silicon structures is of fundamental importance. Polyethylene glycols (PEGs) represent the major category of surface modifying agents used in classical drug delivery systems and in pharmaceutical dosage forms. PEGylation enables avoidance of RES uptake, thus prolonging circulation time of intravenously injectable nanovectors. PEG molecules demonstrate little toxicity and immunogenicity, and are cleared from the body through the urine (molecular weight, MW less than 30 kDa) or in the feces (MW greater than 30kDa). The invention focuses on the possibility of finely tuning the degradation kinetics of the pSi nanovectors and other structures through surface conjugation of PEGs with various backbone lengths/MWs. To prove the concept, pSi nanovectors were covalently conjugated to seven PEGs with MW from 245 to 5,000 Da and their degradation kinetics in physiologically relevant media (phosphate buffer saline, PBS pH7.4, and fetal bovine serum) was assessed by the elemental analysis of the Si using inductive coupled plasma atomic emission spectroscopy (ICP-AES). The conjugation of the PEG with lowest MW to the nanovectors surface did not induce any change in the degradation kinetics in serum, but inhibited degradation and consequently the release of orthosilicic acid into buffer. When PEGs with the longer chains were evaluated, Si mass loss from the nanovectors was slowed down, and the PEGylated structures were almost fully degraded within 18 24 hours in serum and within 48 hours in PBS. The most dramatic effect was observed for high MW PEGs 3,400 and 5,000 Da, which prominently inhibited the degradation of the systems, with complete degradation achieved only after four days. For these PEGs, during the early stages of the degradation, there was a lag period of little or no Si mass loss from the nanovector. The obtained profiles were in agreement with the erosion of the nanovector surface as observed by scanning electron microscopy.

Vilentchouk, Biana Godin↗
NASA NTRS2023

Exploring Natural and Social Drivers of Forest Degradation in Post-Soviet Georgia

The Caucasus Mountains harbor high concentrations of endemic species and provide an abundance of ecosystem services yet are significantly understudied compared to other ecosystems in Eurasia. In the country of Georgia, at the heart of the Caucasus region, forest degradation has been the largest land change process over the last thirty years. The prevailing narrative is that legal and illegal cutting of trees for fuelwood is primarily responsible for this process. Yet, since independence from the Soviet Union in 1991, the country has undergone rapid socioeconomic and institutional changes which have not been explored as drivers of forest change. We combine newly available land-cover change estimates, Georgian statistical data, and historical institutional change data to examine socioeconomic drivers of forest degradation. Our analysis controls for concurrent changes in climate that would affect degradation and examines variation at the regional (state) level from 2011 to 2019, as well as at the national level from 1987 to 2019. We find that higher winter temperature and drought are associated with higher degradation at the regional scale, while major institutional changes and drought are associated with higher forest degradation at the national level. Access to natural gas, the major energy alternative to fuelwood, had no significant association with degradation. Our results challenge the narrative that poverty and a lack of alternative energy infrastructure drive forest degradation and suggest that government policies banning household fuelwood cutting, including the new Forest Code of 2020, may not reduce forest degradation. Given these results, improved data on wood harvesting and more research on the commercial drivers of degradation and their links to economic and political reforms is needed to better inform forest policy in the region, especially given ongoing risks from climate change.

Institutions↗
NASA NTRS1988

Antimisting kerosene: Low temperature degradation and blending

The inline filtration characteristics of freshly blended and degraded antimisting fuels (AMK) at low temperature are examined. A needle valve degrader was modified to include partial recirculation of degraded fuel and heat addition in the bypass loop. A pressure drop across the needle valve of up to 4,000 psi was used. The pressure drop across a 325 mesh filter screen placed inline with the degrader and directly downstream of the needle valve was measured as a function of time for different values of pressure drop across the needle valve. A volume flux of 1 gpm/sq in was employed based on the frontal area of the screen. It was found that, at ambient temperatures, freshly blended AMK fuel could be degraded using a single pass degradation at 4,000 psi pressure drop across the needle valve to give acceptable filterability performance. At fuel temperatures below -20 C, degradation becomes increasingly difficult and a single pass technique results in unacceptable filtration performance. Recirculation of a fraction of the degraded fuel and heat addition in the bypass loop improved low temperature degradation performance. The problem is addressed of blending the AMK additive with Jet A at various base fuel temperatures.

Yavrouian, A.↗
NASA NTRS1993

Characterization of atrial natriuretic peptide degradation by cell-surface peptidase activity on endothelial cells

Atrial natriuretic peptide (ANP) is a fluid-regulating peptide hormone that promotes vasorelaxation, natriuresis, and diuresis. The mechanisms for the release of ANP and for its clearance from the circulation play important roles in modulating its biological effects. Recently, we have reported that the cell surface of an endothelial cell line, CPA47, could degrade 125I-ANP in the presence of EDTA. In this study, we have characterized this degradation of 125I-ANP. The kinetics of ANP degradation by the surface of CPA47 cells were first order, with a Km of 320 +/- 60 nM and Vmax of 35 +/- 14 pmol of ANP degraded/10 min/10(5) cells at pH 7.4. ANP is degraded by the surface of CPA47 cells over a broad pH range from 7.0-8.5. Potato carboxypeptidase inhibitor and bestatin inhibited 125I-ANP degradation, suggesting that this degradative activity on the surface of CPA47 cells has exopeptidase characteristics. The selectivity of CPA47 cell-surface degradation of ANP was demonstrated when 125I-ANP degradation was inhibited in the presence of neuropeptide Y and angiotensin I and II but not bradykinin, bombesin, endothelin-1, or substance P. The C-terminal amino acids phe26 and tyr28 were deduced to be important for ANP interaction with the cell-surface peptidase(s) based on comparison of the IC50 of various ANP analogues and other natriuretic peptides for the inhibition of ANP degradation. These data suggest that a newly characterized divalent cation-independent exopeptidase(s) that selectively recognizes ANP and some other vasoactive peptides exists on the surface of endothelial cells.

NASA Discipline Regulatory Physiology↗
NASA NTRS2018

MODIS Solar Diffuser Degradation Determination and Its Spectral Dependency

This study presents a modeling approach to improve solar diffuser (SD) degradation determination from SD stability monitor (SDSM) measurements. The MODIS instrument uses a SDto calibrate its reflective solar bands (RSBs) on-orbit. Due to the imperfectly designed SDSM sun view screen, the SD reflectance tracked by SDSM has large noise. The SDSM measurements noise is spectrally coherent and can be minimized by normalizing measurements to the least degradeddetector 9 (936 nm). In this study, a SD degradation model is used to determine the SDdegradation's wavelength dependency and the detector 9 degradation is estimated by the model solution.The results show the SD degradations measured at 6 SDSM detectors (554 _ 936 nm) have stable relationships, where the degradation is inversely proportion to 1/wavelength^4. The model estimated SD degradation at SDSM detector 9 wavelength (936 nm) is ~0.9% from 2002 to 2018.Based on the SD degradation model solution, the SD degradation at short/mid wave bands are estimated to improve short/mid wave bands calibration. The model can also be used to improve interpolating SD degradation at SDSM detectors to RSB wavelengths. Compared to linear interpolation, bands 9 and 10 show the largest differences of up to 0.3 and 0.4% respectively. These differences directly impact the calibration coefficients of these bands.

radiometric calibration↗
NASA NTRS2021

S-NPP VIIRS Solar Diffuser Degradation at the View Direction of the Rotating Telescope Assembly

S-NPP VIIRS has been on-orbit for more than nine years since it was launched on October28th,2011. The VIIRS reflective solar bands (RSBs) are calibrated on-orbit primarily by an onboard solar diffuser (SD). The SD on-orbit degradation is tracked by an onboard SD stability monitor(SDSM). The VIIRS RSBs view the SD through a rotating telescope assembly (RTA). The RTA views the SD from a direction that is quite different from that of the SDSM. It has been shown that the SD degrades non-uniformly with respect to the incident and outgoing directions, especially at the short wavelengths. Thus, the SDSM calibration cannot provide an accurate SD degradation estimation for the view direction of the RTA, resulting in long-term drifts in the calibration coefficients derived from the SD and SDSM calibration. S-NPP VIIRS has been scheduled to view the Moon approximately monthly since its launch. The lunar observations can provide accurate long-term trends for the RSB calibration coefficients since the lunar surface reflectance is quite stable. By comparing the SD and lunar calibration results, we can obtain the SD degradation differences at the view directions of the SDSM and RTA and derive the SD degradation at the view direction of the RTA. Moreover, we can also derive the SD degradation in the short-wave infrared (SWIR) spectral range, wherein the SDSM cannot track the SD degradation. In this paper, we will derive the SD degradation for the view direction of the RTA from the SD, SDSM, and lunar calibrations from the visible to SWIR spectral range. We will also simulate the SD degradation with analytical models and compare their performances.

SNPP VIIRS↗
NASA NTRS2016

Impacts of the Angular Dependence of the Solar Diffuser BRDF Degradation Factor on the SNPP VIIRS Reflective Solar Band On-Orbit Radiometric Calibration

Using an onboard sunlit solar diffuser (SD) as the primary radiance source, the visible infrared imaging radiometer suite (VIIRS) on the Suomi National Polar-orbiting Partnership satellite regularly performs radiometric calibration of its reflective solar bands (RSBs). The SD bidirectional reflectance distribution function (BRDF) value decreases over time. A numerical degradation factor is used to quantify the degradation and is determined by an onboard SD stability monitor (SDSM), which observes the sun and the sunlit SD at almost the same time. We had shown previously that the BRDF degradation factor was angle-dependent. Consequently, due to that the SDSM and the RSB view the SD at very different angles relative to both the solar and the SD surface normal vectors, directly applying the BRDF degradation factor determined by the SDSM to the VIIRS RSB calibration can result in large systematic errors. We develop a phenomenological model to calculate the BRDF degradation factor for the RSB SD view from the degradation factor for the SDSM SD view. Using the yearly undulations observed in the VIIRS detector gains for the M1-M4 bands calculated with the SD BRDF degradation factor for the SDSM SD view and the difference between the VIIRS detector gains calculated from the SD and the lunar observations, we obtain the model parameter values and thus establish the relation between the BRDF degradation factors for the RSB and the SDSM SD view directions.

Lei, Ning↗
NASA NTRS2017

Towards Designing Graceful Degradation into Trajectory Based Operations: A Human-Systems Integration Approach

One of the most fundamental changes to the air traffic management system in NextGen is the concept of trajectory based operations (TBO). With the introduction of such change, system safety and resilience is a critical concern, in particular, the ability of systems to gracefully degrade. In order to design graceful degradation into a TBO envrionment, knowledge of the potential causes of degradation, and appropriate solutions, is required. In addition, previous research has predominantly explored the technological contribution to graceful degradation, frequently neglecting to consider the role of the human operator, specifically, air traffic controllers (ATCOs). This is out of step with real-world operations, and potentially limits an ecologically valid understanding of achieving graceful degradation in an air traffic control (ATC) environment. The following literature review aims to identify and summarize the literature to date on the potential causes of degradation in ATC and the solutions that may be applied within a TBO context, with a specific focus on the contribution of the air traffic controller. A framework of graceful degradation, developed from the literature, is presented. It is argued that in order to achieve graceful degradation within TBO, a human-system integration approach must be applied.

human-system integration↗