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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2020

MODIS Detector Differences Using Deep Convective Clouds and Desert Targets

An accurate on-orbit characterization of the Moderate Resolution Imaging Spectroradiometer (MODIS) sensors onboard the Terra and Aqua satellites is essential to satisfy the requirements from the scientific community for high-quality operational and research products. In this study, NASA’s C6.1 L1B data are utilized to assess the stability of the calibrated top of atmosphere reflectance retrieved from individual detectors within a spectral band over deep convective clouds (DCCs) and desert sites. The results from these invariant Earth targets show detector-to-detector (D2D) differences in the L1B reflectance products for select MODIS reflective solar bands. For Aqua MODIS, the D2D differences have no significant change over time for the bands studied. However, the D2D differences exhibit an increase in magnitude over time for Terra MODIS bands 1, 3-7, and 26, which can induce noticeable striping and higher uncertainties in the downstream data products. The D2D stability assessment results over DCCs are consistent with those observed over desert sites. In addition, the view-angle dependence of the D2D differences is investigated by separating the frames along scan into five zones. The D2D assessment is performed for each of the five zones, and the results will further benefit any improvements in the calibration of a detector-dependent response versus scan angle that can be considered for future MODIS Level 1B Collections.

MODIS↗

NASA NTRS2020

Assessment of SNPP VIIRS RSB detector-to-detector differences using deep convective clouds and deserts

An accurate on-orbit characterization of the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership satellite is essential to satisfy the requirements from NOAA, NASA, and the general research community for high-quality operational and research products. NASA’s Land Science Investigator-led Processing System (LSIPS) sensor data records (SDRs) are utilized to assess the stability of the calibrated top of atmosphere reflectance over the deep convective clouds (DCCs) and over the Libya-4desert site. The results from DCCs and desert show detector-to-detector (D2D) reflectance differences in the VIIRS reflective solar bands, 10 moderate-resolution bands (M-bands, M1to M5, M7 to M11), and three imagery resolution bands (I-bands, I1-I3). More importantly, the D2D differences exhibit an increase in magnitude over time for bands M1 to M5 and I1to I2, which induces noticeable striping and higher uncertainties in the downstream data products. The largest D2D difference is observed in bands M1 and M2, with magnitudes greater than1.8% in trends among the 16 detectors and standard deviations less than 0.12% over time. TheD2D stability assessment results over DCCs are consistent with those observed over the Libya-4desert site. To improve the quality of the calibrated SDR reflectance data, NASA’s VIIRS characterization support team has improved the calibration algorithm to incorporate corrections based on these DCC measurements to mitigate the striping (detector differences) observed in the current version of the SDR. These improvements are planned to be included in the next mission reprocessing of the LSIPS land products.

SNPP VIIRS↗

NASA NTRS1976

Spectroscopic studies and analysis of the laser states of Nd/3+/ in YVO4

Polarized absorption and dye-laser excited fluorescence spectra of Nd/3+/ in the Y(3+) site of yttrium orthovanadate at 85 and 300 K are presented and analyzed. The absence of allowed transitions and the unusual concentration of line strength into one transition in pi polarization within a given line group is shown by the Judd-Ofelt theory to be a consequence of the D2d symmetry of the site and ion placements in the unit cell. An energy level scheme giving level positions, level identities, and observed transitions is presented. The principal laser line in this group at about 10640.9 A was found to be predominately pi polarized and to have a cross section of 30 x 10 to the 19th/sq cm, which is 4.6 times larger than the laser transition of Nd/3+/ in YAG.

Pappas Yaney, P.↗

NASA NTRS1992

Interconversion of diborane(4) isomers

Highly correlated electronic structure computations using many-body perturbation theory and coupled-cluster gradient techniques are used to study the reaction pathway that links the two forms (C2u and D2d) of diborane(4). The results obtained indicate that a low-energy pathway exists for interconversion of the two low-lying isomers of diborane(4). The proposed mechanism consists of a single concerted but nonsynchronous rotation of the BH2 groups. The pathway first follows an idealized reaction coordinate which preserves C2 symmetry, but then bifurcates at a branch point, leading to two equivalent transition states which lack nontrivial elements of symmetry.

Stanton, John F.↗

NASA NTRS1994

The Successive H2O Binding Energies for Fe(H2O)n(+)

The binding energy, computed using density functional theory (DFT), are in good agreement with experiment. The bonding is electrostatic (charge-dipole) in origin for all systems. The structures are therefore determined mostly by metal-ligand and ligand-ligand repulsion. The computed structure for FeH2O(+) is C(2v) where sp hybridization is important in reducing the Fe-H2O repulsion. Fe(H2O)2(+) has D2d symmetry where sdo hybridization is the primary factor leading to the linear O-Fe-O geometry. The bonding in Fe(H2O)3(+) and Fe(H2O)4(+) are very complex because ligand-ligand and metal-ligand repulsion, both for the in-plane and out-of-plane water lone-pair orbitals, are important.

Ricca, Alessandra↗

NASA NTRS2014

The Experimental Regional Ensemble Forecast System (ExREF): Its Use in NWS Forecast Operations and Preliminary Verification

The Experimental Regional Ensemble Forecast (ExREF) system is a tool for the development and testing of new Numerical Weather Prediction (NWP) methodologies. ExREF is run in near‐realtime by the Global Systems Division (GSD) of the NOAA Earth System Research Laboratory (ESRL) and its products are made available through a website, an ftp site, and via the Unidata Local Data Manager (LDM). The ExREF domain covers most of North America and has 9‐km horizontal grid spacing. The ensemble has eight members, all employing WRF‐ARW. The ensemble uses a variety of initial conditions from LAPS and the Global Forecasting System (GFS) and multiple boundary conditions from the GFS ensemble. Additionally, a diversity of physical parameterizations is used to increase ensemble spread and to account for the uncertainty in forecasting extreme precipitation events. ExREF has been a component of the Hydrometeorology Testbed (HMT) NWP suite in the 2012‐2013 and 2013‐2014 winters. A smaller domain covering just the West Coast was created to minimize band‐width consumption for the NWS. This smaller domain has and is being distributed to the National Weather Service (NWS) Weather Forecast Office and California Nevada River Forecast Center in Sacramento, California, where it is ingested into the Advanced Weather Interactive Processing System (AWIPS I and II) to provide guidance on the forecasting of extreme precipitation events. This paper will review the cooperative effort employed by NOAA ESRL, NASA SPoRT (Short‐term Prediction Research and Transition Center), and the NWS to facilitate the ingest and display of ExREF data utilizing the AWIPS I and II D2D and GFE (Graphical Software Editor) software. Within GFE is a very useful verification software package called BoiVer that allows the NWS to utilize the River Forecast Center's 4 km gridded QPE to compare with all operational NWP models 6‐hr QPF along with the ExREF mean 6‐hr QPF so the forecasters can build confidence in the use of the ExREF in preparing their rainfall forecasts. Preliminary results will be presented.

Reynolds, David↗