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Materials Data on Cu3(SnO3)4 by Materials Project

Cu3(SnO3)4 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Cu+2.67+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Cu–O bond lengths are 1.90 Å. Sn4+ is bonded to six equivalent O2- atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Sn–O bond lengths are 2.09 Å. O2- is bonded in a trigonal planar geometry to one Cu+2.67+ and two equivalent Sn4+ atoms.

36 MATERIALS SCIENCE↗