Materials Data on Cu2SbO5 by Materials Project
CuO2CuSbO3 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one copper(ii) hydroxide molecule and one CuSbO3 cluster. In the CuSbO3 cluster, Cu+2.50+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.69 Å) and one longer (1.75 Å) Cu–O bond length. Sb5+ is bonded in a water-like geometry to two O2- atoms. There is one shorter (1.84 Å) and one longer (1.98 Å) Sb–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Sb5+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Cu+2.50+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one Cu+2.50+ and one Sb5+ atom.