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ZrRh2Cu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two ZrRh2Cu ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to two equivalent Rh atoms. Both Zr–Rh bond lengths are 2.18 Å. Rh is bonded in a linear geometry to one Zr and one Cu atom. The Rh–Cu bond length is 2.45 Å. Cu is bonded in a linear geometry to two equivalent Rh atoms.
Zr2RhCu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2RhCu ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Rh and one Cu atom. The Zr–Rh bond length is 2.32 Å. The Zr–Cu bond length is 2.72 Å. Rh is bonded in a linear geometry to two equivalent Zr atoms. Cu is bonded in a linear geometry to two equivalent Zr atoms.