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Ti2RhCu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ti2RhCu ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to one Rh and one Cu atom. The Ti–Rh bond length is 2.19 Å. The Ti–Cu bond length is 2.58 Å. Rh is bonded in a linear geometry to two equivalent Ti atoms. Cu is bonded in a linear geometry to two equivalent Ti atoms.
TiRh2Cu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiRh2Cu ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Rh atoms. Both Ti–Rh bond lengths are 2.03 Å. Rh is bonded in a linear geometry to one Ti and one Cu atom. The Rh–Cu bond length is 2.46 Å. Cu is bonded in a linear geometry to two equivalent Rh atoms.