Materials Data on CsCoN by Materials Project
CoNCs crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Cs1+ is bonded in a distorted bent 120 degrees geometry to two equivalent N3- atoms. There are one shorter (3.13 Å) and one longer (3.14 Å) Cs–N bond lengths. Co2+ is bonded in a distorted T-shaped geometry to three equivalent N3- atoms. There is two shorter (1.80 Å) and one longer (1.92 Å) Co–N bond length. N3- is bonded in a 3-coordinate geometry to two equivalent Cs1+ and three equivalent Co2+ atoms.
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