Materials Data on CsBiO3 by Materials Project
CsBiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Cs1+ is bonded to twelve equivalent O2- atoms to form CsO12 cuboctahedra that share corners with twelve equivalent CsO12 cuboctahedra, faces with six equivalent CsO12 cuboctahedra, and faces with eight equivalent BiO6 octahedra. All Cs–O bond lengths are 3.12 Å. Bi5+ is bonded to six equivalent O2- atoms to form BiO6 octahedra that share corners with six equivalent BiO6 octahedra and faces with eight equivalent CsO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Bi–O bond lengths are 2.21 Å. O2- is bonded to four equivalent Cs1+ and two equivalent Bi5+ atoms to form a mixture of distorted edge, face, and corner-sharing OCs4Bi2 octahedra. The corner-sharing octahedra tilt angles range from 0–60°.