Materials Data on Cs3BrO by Materials Project
Cs3OBr crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Cs1+ is bonded in a 2-coordinate geometry to two equivalent O2- and two equivalent Br1- atoms. Both Cs–O bond lengths are 2.84 Å. Both Cs–Br bond lengths are 4.03 Å. O2- is bonded to six equivalent Cs1+ atoms to form face-sharing OCs6 octahedra. Br1- is bonded in a distorted hexagonal planar geometry to six equivalent Cs1+ atoms.
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