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Materials Data on Cs(PRu)2 by Materials Project

Cs(RuP)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Cs1+ is bonded in a body-centered cubic geometry to eight equivalent P3- atoms. All Cs–P bond lengths are 3.75 Å. Ru+2.50+ is bonded to four equivalent P3- atoms to form a mixture of edge and corner-sharing RuP4 tetrahedra. All Ru–P bond lengths are 2.32 Å. P3- is bonded in a 8-coordinate geometry to four equivalent Cs1+ and four equivalent Ru+2.50+ atoms.

36 MATERIALS SCIENCE↗