Results for “Cs-Li-S-V”

Materials Data on Cs2LiVS4 by Materials Project

Cs2LiVS4 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Cs1+ is bonded in a 8-coordinate geometry to eight equivalent S2- atoms. There are a spread of Cs–S bond distances ranging from 3.60–3.94 Å. Li1+ is bonded to four equivalent S2- atoms to form distorted LiS4 tetrahedra that share edges with two equivalent VS4 tetrahedra. All Li–S bond lengths are 2.44 Å. V5+ is bonded to four equivalent S2- atoms to form VS4 tetrahedra that share edges with two equivalent LiS4 tetrahedra. All V–S bond lengths are 2.16 Å. S2- is bonded in a 2-coordinate geometry to four equivalent Cs1+, one Li1+, and one V5+ atom.