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Materials Data on Cs(AsRh)2 by Materials Project

Cs(RhAs)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Cs is bonded in a body-centered cubic geometry to eight equivalent As atoms. All Cs–As bond lengths are 3.73 Å. Rh is bonded to four equivalent As atoms to form a mixture of corner and edge-sharing RhAs4 tetrahedra. All Rh–As bond lengths are 2.45 Å. As is bonded in a 8-coordinate geometry to four equivalent Cs and four equivalent Rh atoms.

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