Materials Data on CrCuN6Cl5 by Materials Project
Cr(N2Cl)3CuCl2 crystallizes in the cubic Pn-3m space group. The structure is three-dimensional and consists of four copper chloride molecules and one Cr(N2Cl)3 framework. In the Cr(N2Cl)3 framework, Cr6+ is bonded in a hexagonal planar geometry to six equivalent N+0.33- atoms. All Cr–N bond lengths are 1.83 Å. N+0.33- is bonded in a distorted single-bond geometry to one Cr6+ and two equivalent Cl1- atoms. Both N–Cl bond lengths are 2.27 Å. Cl1- is bonded in a distorted rectangular see-saw-like geometry to four equivalent N+0.33- atoms.
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