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V2WCr crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two V2WCr ribbons oriented in the (1, 0, 0) direction. V is bonded in a distorted linear geometry to one W and one Cr atom. The V–W bond length is 2.18 Å. The V–Cr bond length is 2.85 Å. W is bonded in a linear geometry to two equivalent V atoms. Cr is bonded in a linear geometry to two equivalent V atoms.
VW2Cr crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two VW2Cr ribbons oriented in the (1, 0, 0) direction. V is bonded in a linear geometry to two equivalent W atoms. Both V–W bond lengths are 2.16 Å. W is bonded in a linear geometry to one V and one Cr atom. The W–Cr bond length is 2.60 Å. Cr is bonded in a linear geometry to two equivalent W atoms.
VWCr2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two VWCr2 ribbons oriented in the (0, 1, 0) direction. V is bonded in a linear geometry to two equivalent Cr atoms. Both V–Cr bond lengths are 2.73 Å. W is bonded in a linear geometry to two equivalent Cr atoms. Both W–Cr bond lengths are 2.79 Å. Cr is bonded in a linear geometry to one V and one W atom.