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Materials Data on CrRh3 by Materials Project

CrRh3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Cr is bonded to twelve equivalent Rh atoms to form CrRh12 cuboctahedra that share corners with twelve equivalent CrRh12 cuboctahedra, edges with twenty-four equivalent RhCr4Rh8 cuboctahedra, faces with six equivalent CrRh12 cuboctahedra, and faces with twelve equivalent RhCr4Rh8 cuboctahedra. All Cr–Rh bond lengths are 2.69 Å. Rh is bonded to four equivalent Cr and eight equivalent Rh atoms to form distorted RhCr4Rh8 cuboctahedra that share corners with twelve equivalent RhCr4Rh8 cuboctahedra, edges with eight equivalent CrRh12 cuboctahedra, edges with sixteen equivalent RhCr4Rh8 cuboctahedra, faces with four equivalent CrRh12 cuboctahedra, and faces with fourteen equivalent RhCr4Rh8 cuboctahedra. All Rh–Rh bond lengths are 2.69 Å.

36 MATERIALS SCIENCE↗

Materials Data on Cr3Rh by Materials Project

Cr3Rh crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Cr is bonded in a 6-coordinate geometry to two equivalent Cr and four equivalent Rh atoms. Both Cr–Cr bond lengths are 2.32 Å. All Cr–Rh bond lengths are 2.59 Å. Rh is bonded to twelve equivalent Cr atoms to form a mixture of edge and face-sharing RhCr12 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on CrRh by Materials Project

CrRh crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Cr is bonded to six equivalent Rh atoms to form a mixture of distorted face, edge, and corner-sharing CrRh6 cuboctahedra. All Cr–Rh bond lengths are 2.61 Å. Rh is bonded to six equivalent Cr atoms to form a mixture of distorted face, edge, and corner-sharing RhCr6 cuboctahedra.

36 MATERIALS SCIENCE↗