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TiCr2Re crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiCr2Re ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Cr atoms. Both Ti–Cr bond lengths are 2.73 Å. Cr is bonded in a linear geometry to one Ti and one Re atom. The Cr–Re bond length is 2.29 Å. Re is bonded in a linear geometry to two equivalent Cr atoms.
TiCrRe2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiCrRe2 ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Re atoms. Both Ti–Re bond lengths are 2.21 Å. Cr is bonded in a linear geometry to two equivalent Re atoms. Both Cr–Re bond lengths are 2.63 Å. Re is bonded in a linear geometry to one Ti and one Cr atom.