Materials Data on Cr(BMo)2 by Materials Project
Cr(MoB)2 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Mo2+ is bonded in a distorted hexagonal planar geometry to six equivalent B3- atoms. There are two shorter (2.33 Å) and four longer (2.34 Å) Mo–B bond lengths. Cr2+ is bonded in a square co-planar geometry to four equivalent B3- atoms. All Cr–B bond lengths are 2.35 Å. B3- is bonded in a 9-coordinate geometry to six equivalent Mo2+, two equivalent Cr2+, and one B3- atom. The B–B bond length is 1.88 Å.