3D CoSe@C Aerogel as a Host for Dendrite-Free Lithium-Metal Anode and Efficient Sulfur Cathode in Li–S Full Cells
Abstract not provided.
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Results for “CoSe”
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Materials Data on CoSe by Materials Project
CoSe is lead oxide structured and crystallizes in the tetragonal P4/nmm space group. The structure is two-dimensional and consists of one CoSe sheet oriented in the (0, 0, 1) direction. Co2+ is bonded to four equivalent Se2- atoms to form a mixture of edge and corner-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.31 Å. Se2- is bonded in a 4-coordinate geometry to four equivalent Co2+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on CoSe by Materials Project
CoSe is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Co2+ is bonded to six equivalent Se2- atoms to form a mixture of corner, edge, and face-sharing CoSe6 octahedra. The corner-sharing octahedral tilt angles are 50°. All Co–Se bond lengths are 2.46 Å. Se2- is bonded in a 6-coordinate geometry to six equivalent Co2+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on Rb(CoSe)2 by Materials Project
Rb(CoSe)2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rb1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All Rb–Se bond lengths are 3.52 Å. Co+1.50+ is bonded to four equivalent Se2- atoms to form a mixture of edge and corner-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.36 Å. Se2- is bonded in a 8-coordinate geometry to four equivalent Rb1+ and four equivalent Co+1.50+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on Cs(CoSe)2 by Materials Project
Cs(CoSe)2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Cs1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All Cs–Se bond lengths are 3.64 Å. Co+1.50+ is bonded to four equivalent Se2- atoms to form a mixture of edge and corner-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.36 Å. Se2- is bonded in a 8-coordinate geometry to four equivalent Cs1+ and four equivalent Co+1.50+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on KTl(CoSe)4 by Materials Project
KTl(CoSe)4 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. K1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All K–Se bond lengths are 3.41 Å. Co+1.50+ is bonded to four Se2- atoms to form a mixture of edge and corner-sharing CoSe4 tetrahedra. There are two shorter (2.34 Å) and two longer (2.35 Å) Co–Se bond lengths. Tl1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All Tl–Se bond lengths are 3.42 Å. There are two inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a 4-coordinate geometry to four equivalent Co+1.50+ and four equivalent Tl1+ atoms. In the second Se2- site, Se2- is bonded in a 8-coordinate geometry to four equivalent K1+ and four equivalent Co+1.50+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on KTl4(CoSe)10 by Materials Project
KTl4(CoSe)10 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. K1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All K–Se bond lengths are 3.40 Å. There are three inequivalent Co+1.50+ sites. In the first Co+1.50+ site, Co+1.50+ is bonded to four Se2- atoms to form a mixture of corner and edge-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.34 Å. In the second Co+1.50+ site, Co+1.50+ is bonded to four equivalent Se2- atoms to form a mixture of corner and edge-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.33 Å. In the third Co+1.50+ site, Co+1.50+ is bonded to four equivalent Se2- atoms to form a mixture of corner and edge-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.33 Å. There are two inequivalent Tl1+ sites. In the first Tl1+ site, Tl1+ is bonded in a body-centered cubic geometry to eight Se2- atoms. There are four shorter (3.40 Å) and four longer (3.41 Å) Tl–Se bond lengths. In the second Tl1+ site, Tl1+ is bonded in a body-centered cubic geometry to eight Se2- atoms. All Tl–Se bond lengths are 3.41 Å. There are four inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a 4-coordinate geometry to four equivalent Co+1.50+ and four equivalent Tl1+ atoms. In the second Se2- site, Se2- is bonded in a 4-coordinate geometry to four equivalent Co+1.50+ and four equivalent Tl1+ atoms. In the third Se2- site, Se2- is bonded in a 8-coordinate geometry to four equivalent K1+ and four equivalent Co+1.50+ atoms. In the fourth Se2- site, Se2- is bonded in a 4-coordinate geometry to four equivalent Co+1.50+ and four equivalent Tl1+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on CoSeS by Materials Project
CoSeS is pyrite-derived structured and crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Co4+ is bonded to three equivalent Se2- and three equivalent S2- atoms to form corner-sharing CoSe3S3 octahedra. The corner-sharing octahedral tilt angles are 63°. All Co–Se bond lengths are 2.40 Å. All Co–S bond lengths are 2.31 Å. Se2- is bonded in a 4-coordinate geometry to three equivalent Co4+ and one S2- atom. The Se–S bond length is 2.39 Å. S2- is bonded in a 4-coordinate geometry to three equivalent Co4+ and one Se2- atom.
36 MATERIALS SCIENCE↗
Materials Data on Tl(CoSe)2 by Materials Project
TlCo2Se2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Co+1.50+ is bonded to four equivalent Se2- atoms to form a mixture of corner and edge-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.34 Å. Tl1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All Tl–Se bond lengths are 3.44 Å. Se2- is bonded in a 4-coordinate geometry to four equivalent Co+1.50+ and four equivalent Tl1+ atoms.
36 MATERIALS SCIENCE↗
Materials Data on K(CoSe)2 by Materials Project
KCo2Se2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. K1+ is bonded in a body-centered cubic geometry to eight equivalent Se2- atoms. All K–Se bond lengths are 3.41 Å. Co+1.50+ is bonded to four equivalent Se2- atoms to form a mixture of edge and corner-sharing CoSe4 tetrahedra. All Co–Se bond lengths are 2.35 Å. Se2- is bonded in a 8-coordinate geometry to four equivalent K1+ and four equivalent Co+1.50+ atoms.
36 MATERIALS SCIENCE↗
Correction: Emergence of two distinct phase transitions in monolayer CoSe 2 on graphene
Following publication of the original article, the author identified an error in Graphical Abstract and updated Acknowledgment section. In Graphical abstract, there is a type on the unit E B (eV) which has been updated with this correction.
Rhee, Tae Gyu↗
Emergence of two distinct phase transitions in monolayer CoSe2 on graphene
Abstract Dimensional modifications play a crucial role in various applications, especially in the context of device miniaturization, giving rise to novel quantum phenomena. The many-body dynamics induced by dimensional modifications, including electron-electron, electron-phonon, electron-magnon and electron-plasmon coupling, are known to significantly affect the atomic and electronic properties of the materials. By reducing the dimensionality of orthorhombic CoSe 2 and forming heterostructure with bilayer graphene using molecular beam epitaxy, we unveil the emergence of two types of phase transitions through angle-resolved photoemission spectroscopy and scanning tunneling microscopy measurements. We disclose that the 2 × 1 superstructure is associated with charge density wave induced by Fermi surface nesting, characterized by a transition temperature of 340 K. Additionally, another phase transition at temperature of 160 K based on temperature dependent gap evolution are observed with renormalized electronic structure induced by electron-boson coupling. These discoveries of the electronic and atomic modifications, influenced by electron-electron and electron-boson interactions, underscore that many-body physics play significant roles in understanding low-dimensional properties of non-van der Waals Co-chalcogenides and related heterostructures. Graphical Abstract
36 MATERIALS SCIENCE↗
A transformer of closely spaced pulsed waveforms
Passive circuit, using diodes, transistors, and magnetic cores, transforms the voltage of repetitive positive or negative pulses. It combines a pulse transformer with switching devices to effect a resonant flux reset and can transform various pulsed waveforms that have a nonzero average value and are relatively cosely spaced in time.
Niedra, J.↗
Optical fibers and components experiment (A0138-7)
Fiber optics permanent damages induced by ionizing radiation after a long exposure in space and after laboratory tests were examined. Irradiation tests performed with radioactive sources (Sr90 - Y90) were validataed, computer coses used for the fluence and dose profile were verified. The performance of fiber optics waveguides in a low altitude orbit, and the origin of transmission losses in the material were dtermined. High sensitivity to ionizing radiations, however, may be a restriction for optic fiber use on satellites. Irradiation tests on these components using neutrons, gamma rays, and X-rays are carried out. Radiation damage on opticao materials, however, is strongly linked to the test conditions.
Bourrieau, J.↗
Ignition and ignition propagation in solid propellant motors.
Solid propellant ignition and ignition propagation for rocket exhaust and hypergolic-type igniters
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