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ZrCo is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Zr is bonded in a body-centered cubic geometry to eight equivalent Co atoms. All Zr–Co bond lengths are 2.77 Å. Co is bonded in a body-centered cubic geometry to eight equivalent Zr atoms.
Co23Zr6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Zr is bonded in a 12-coordinate geometry to twelve Co atoms. There are a spread of Zr–Co bond distances ranging from 2.76–2.91 Å. There are four inequivalent Co sites. In the first Co site, Co is bonded in a distorted q6 geometry to three equivalent Zr and nine Co atoms. There are a spread of Co–Co bond distances ranging from 2.35–2.51 Å. In the second Co site, Co is bonded in a body-centered cubic geometry to eight equivalent Co atoms. All Co–Co bond lengths are 2.41 Å. In the third Co site, Co is bonded to four equivalent Zr and eight Co atoms to form a mixture of face and corner-sharing CoZr4Co8 cuboctahedra. All Co–Co bond lengths are 2.52 Å. In the fourth Co site, Co is bonded in a 10-coordinate geometry to three equivalent Zr and ten Co atoms. All Co–Co bond lengths are 2.79 Å.
Zr3Co crystallizes in the orthorhombic Cmcm space group. The structure is one-dimensional and consists of four Zr3Co ribbons oriented in the (1, 0, 0) direction. there are two inequivalent Zr sites. In the first Zr site, Zr is bonded in a 2-coordinate geometry to two equivalent Co atoms. Both Zr–Co bond lengths are 2.64 Å. In the second Zr site, Zr is bonded in a 2-coordinate geometry to two equivalent Co atoms. Both Zr–Co bond lengths are 2.59 Å. Co is bonded in a 6-coordinate geometry to six Zr atoms.
Zr2Co is Khatyrkite structured and crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Zr is bonded in a 4-coordinate geometry to four equivalent Co atoms. All Zr–Co bond lengths are 2.73 Å. Co is bonded in a 10-coordinate geometry to eight equivalent Zr atoms.
ZrCo2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Zr is bonded in a 12-coordinate geometry to twelve equivalent Co atoms. All Zr–Co bond lengths are 2.86 Å. Co is bonded to six equivalent Zr and six equivalent Co atoms to form a mixture of edge, face, and corner-sharing CoZr6Co6 cuboctahedra. All Co–Co bond lengths are 2.44 Å.
ZrCo3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Zr is bonded to twelve Co atoms to form a mixture of face and corner-sharing ZrCo12 cuboctahedra. There are six shorter (2.69 Å) and six longer (2.70 Å) Zr–Co bond lengths. There are two inequivalent Co sites. In the first Co site, Co is bonded in a 12-coordinate geometry to four equivalent Zr and eight Co atoms. There are a spread of Co–Co bond distances ranging from 2.44–2.93 Å. In the second Co site, Co is bonded in a 12-coordinate geometry to four equivalent Zr and eight equivalent Co atoms.
Zr3Co is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Zr is bonded to eight equivalent Zr and four equivalent Co atoms to form distorted ZrZr8Co4 cuboctahedra that share corners with four equivalent CoZr12 cuboctahedra, corners with fourteen equivalent ZrZr8Co4 cuboctahedra, edges with six equivalent CoZr12 cuboctahedra, edges with twelve equivalent ZrZr8Co4 cuboctahedra, faces with four equivalent CoZr12 cuboctahedra, and faces with sixteen equivalent ZrZr8Co4 cuboctahedra. There are a spread of Zr–Zr bond distances ranging from 2.87–3.19 Å. There are two shorter (2.95 Å) and two longer (3.03 Å) Zr–Co bond lengths. Co is bonded to twelve equivalent Zr atoms to form CoZr12 cuboctahedra that share corners with six equivalent CoZr12 cuboctahedra, corners with twelve equivalent ZrZr8Co4 cuboctahedra, edges with eighteen equivalent ZrZr8Co4 cuboctahedra, faces with eight equivalent CoZr12 cuboctahedra, and faces with twelve equivalent ZrZr8Co4 cuboctahedra.
Zr2Co crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. there are two inequivalent Zr sites. In the first Zr site, Zr is bonded in a 6-coordinate geometry to six equivalent Co atoms. All Zr–Co bond lengths are 2.77 Å. In the second Zr site, Zr is bonded in a 2-coordinate geometry to four equivalent Co atoms. There are two shorter (2.68 Å) and two longer (3.13 Å) Zr–Co bond lengths. Co is bonded in a 9-coordinate geometry to nine Zr atoms.