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RhCoGa2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two RhCoGa2 ribbons oriented in the (1, 0, 0) direction. Rh is bonded in a linear geometry to two equivalent Ga atoms. Both Rh–Ga bond lengths are 2.36 Å. Co is bonded in a linear geometry to two equivalent Ga atoms. Both Co–Ga bond lengths are 2.38 Å. Ga is bonded in a linear geometry to one Rh and one Co atom.
Rh2CoGa crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Rh2CoGa ribbons oriented in the (1, 0, 0) direction. Rh is bonded in a linear geometry to one Co and one Ga atom. The Rh–Co bond length is 2.22 Å. The Rh–Ga bond length is 2.38 Å. Co is bonded in a linear geometry to two equivalent Rh atoms. Ga is bonded in a linear geometry to two equivalent Rh atoms.