Materials Data on CoP4F12 by Materials Project
CoP4F12 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoP4F12 clusters. Co2+ is bonded in a tetrahedral geometry to four P+2.50+ atoms. There are two shorter (2.13 Å) and two longer (2.15 Å) Co–P bond lengths. There are two inequivalent P+2.50+ sites. In the first P+2.50+ site, P+2.50+ is bonded in a 3-coordinate geometry to one Co2+ and three F1- atoms. All P–F bond lengths are 1.58 Å. In the second P+2.50+ site, P+2.50+ is bonded in a 3-coordinate geometry to one Co2+ and three F1- atoms. There is two shorter (1.58 Å) and one longer (1.59 Å) P–F bond length. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one P+2.50+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one P+2.50+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one P+2.50+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one P+2.50+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one P+2.50+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one P+2.50+ atom.