Materials Data on AgSbC2N2(ClF3)2 by Materials Project
AgC2SbN2(ClF3)2 crystallizes in the monoclinic P2/c space group. The structure is one-dimensional and consists of two AgC2SbN2(ClF3)2 ribbons oriented in the (0, 1, 0) direction. Ag1+ is bonded in a square co-planar geometry to two equivalent N3- and two equivalent F1- atoms. Both Ag–N bond lengths are 2.09 Å. Both Ag–F bond lengths are 2.82 Å. C4+ is bonded in a linear geometry to one N3- and one Cl1- atom. The C–N bond length is 1.17 Å. The C–Cl bond length is 1.60 Å. Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is four shorter (1.92 Å) and two longer (1.94 Å) Sb–F bond length. N3- is bonded in a distorted linear geometry to one Ag1+ and one C4+ atom. Cl1- is bonded in a distorted single-bond geometry to one C4+ atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Ag1+ and one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.