Ignition of metals with ClF sub 3 and ClF sub 5 for use as spacecraft chemical heaters
Chemical heat source combined with metals ignition properties considered for spacecraft heating during Mars nighttime landing
Rhein, R. A.↗
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Low cost monocrystalline silicon sheet fabrication for solar cells by advanced ingot technology
The continuous liquid feed (CLF) Czochralski furnace and the enhanced I.D. slicing technology for the low-cost production of monocrystalline silicon sheets for solar cells are discussed. The incorporation of the CLF system is shown to improve ingot production rate significantly. As demonstrated in actual runs, higher than average solidification rates (75 to 100 mm/hr for 150 mm 1-0-0 crystals) can be achieved, when the system approaches steady-state conditions. The design characteristics of the CLF furnace are detailed, noting that it is capable of precise control of dopant impurity incorporation in the axial direction of the crystal. The crystal add-on cost is computed to be $11.88/sq m, considering a projected 1986 25-slice per cm conversion factor with an 86% crystal growth yield.
Fiegl, G. F.↗
Spectroscopy of Chlorosyl Fluoride, FClO
FClO has been proposed as an intermediate in reactions involving ClF, Cl2O, and ClF3O, and it has been suggested as a molecule of atmospheric interest. It has been prepared in situ by the hydrolysis of ClF3. The pure rotational spectrum of FClO has been studied by conventional millimeter wave techniques and by microwave Fourier transform spectroscopy. Selected transitions were searched for using predictions based on an analysis of the nu(sub 1) band. FClO is an asymmetric prolate top, kappa = -0.8950 for F(35)ClO, with a rather small dipole component of 0.093 (4) D along the a-axis and a larger one of 1.93 (5) D along the b-axis. Transitions with 0 <= J <= 54 and 0 <= K(sub a) <= 18 were observed. Cl hyperfine splitting was generally observable throughout the spectrum with F-19 spin-rotation splitting observable as well in the microwave region. Structural parameters, harmonic force constants, and nuclear magnetic shielding parameters were derived and will be compared with data of related molecules, such as ClF3, ClF, FClO2, and FClO3. High resolution infrared spectra were taken in the regions of the FCl stretching mode and bending mode around 600 and 310/cm, respectively. A preliminary analysis indicates that the FCl stretch, near 596.86/cm for F(35)ClO, is in resonance with the dark overtone of delta near 617/cm. A brief progress report will be given.
Mueller, Holger S. P.↗
The Solar System Beyond Neptune
The aim of this research is to study the objects in the Kuiper Belt, in order to understand the nature of its origin and the evolutionary processes which have affected the Kuiper Belt. Particular science objectives include: 1) the determination of the sky-plane surface density of Kuiper Belt Objects (KBOs); 2) the determination of the slope of the cumulative luminosity function (CLF); 3) the determination of the KBO size distribution; 4) the isolation of bright KBOs from which physical measurements can be secured using existing 10-meter diameter class telescopes; 5) physical measurements of bright KBOs designed to assess their composition. Major results obtained under the grant include: 1) The determination of the surface density of KBOs (objects per square degree of sky) as a function of apparent red magnitude in the range 21 less than MR less than 24.8. 2) The discovery of a new dynamical class in the Kuiper Belt, exemplified by 1996 TL66. 3) Physical observations of two bright KBOs were secured using the Keck 10-meter telescope and an infrared imager/spectrometer; 4) In support of public interest in the Kuiper Belt, we wrote a popular article for Scientific American magazine and we developed a "Kuiper Belt Home Page" on the world-wide web.
Jewitt, David↗