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DOE OSTI2020

Materials Data on TeRhCl by Materials Project

RhTeCl is Calaverite-derived structured and crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of two RhTeCl sheets oriented in the (1, 0, 0) direction. Rh3+ is bonded to three equivalent Te2- and three equivalent Cl1- atoms to form edge-sharing RhTe3Cl3 octahedra. There are two shorter (2.58 Å) and one longer (2.59 Å) Rh–Te bond lengths. There are one shorter (2.54 Å) and two longer (2.59 Å) Rh–Cl bond lengths. Te2- is bonded in a 3-coordinate geometry to three equivalent Rh3+ atoms. Cl1- is bonded in a 3-coordinate geometry to three equivalent Rh3+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on Te6RhCl3 by Materials Project

RhTe6Cl3 crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of six RhTe6Cl3 clusters. Rh3+ is bonded in an octahedral geometry to six equivalent Te atoms. All Rh–Te bond lengths are 2.70 Å. Te is bonded in a 2-coordinate geometry to one Rh3+ and one Cl1- atom. The Te–Cl bond length is 2.81 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Te atoms.

36 MATERIALS SCIENCE↗